tri(5-hexen-1-yl)phosphine | 816419-98-4

• 物质功能分类: 化学试剂 - 有机试剂 - 烯烃（环状与无环状）
• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: tri(5-hexen-1-yl)phosphine
• 英文别名: Tri(hex-5-en-1-yl)phosphane；tris(hex-5-enyl)phosphane
• CAS: 816419-98-4
• 化学式: C₁₈H₃₃P
• 分子量: 280.434
• InChiKey: BZUSXVGDTUISLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tri(5-hexen-1-yl)phosphine 在 dimethyl sulfide borane 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH₂)_mCH=CH₂)₃

  摘要：

  Br(CH₂)ₘCH=CH₂与镁粉和PCl₃（0.33当量）的反应得到P((CH₂)ₘ- CH=CH₂)₃（1; m = a, 4; b, 5; c, 6; d, 7; e, 8; f, 9; 52 - 87％）。1a - c, e与PdX₂(COD)（X = Cl, Br）反应得到反式-PdX₂(P((CH₂)ₘCH=CH₂)₃)₂（35 - 92％）。1b - e与PtCl₂在苯中反应主要得到反式-PtCl₂(P((CH₂)ₘCH=CH₂)₃)₂（反-5b-e; 52 - 75％），而与K₂PtCl₄在水中反应主要得到顺式-5b-e（33 - 70％）。1c和H₃B・S(CH₃)₂等量反应得到1：1加合物H₃B・P((CH₂)₆CH=CH₂)₃（85％）。在这些转化中，没有观察到来自C=C键的副产物。

  DOI：

  10.1515/znb-2010-0327
• 作为产物：
  描述：

  6-溴-1-己烯 在 1,1-二溴乙烷 、 magnesium 、 三氯化磷 作用下， 以 四氢呋喃 为溶剂， 反应 3.33h， 以70%的产率得到tri(5-hexen-1-yl)phosphine
  参考文献：
  名称：

  分子陀螺仪：[Fe（CO）（3）]和[Fe（CO）（2）（NO）]（+）转子装在三辐定子中；烯烃易位组装。

  摘要：

  DOI：

  10.1002/anie.200460534

文献信息

• Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3
  作者：Georgette M. Lang、Dirk Skaper、Takanori Shima、Michael Otto、Leyong Wang、John A. Gladysz

  DOI：10.1071/ch15178

  日期：——

  of (BDA)Fe(CO)3 (BDA = benzylideneacetone) and P((CH2)mCH=CH2)3 (1; m = 4, a; 5, b; 6, c; 7, d; 8, e) give the trigonal bipyramidal bis(phosphine) complexes trans-Fe(CO)3(P((CH2)mCH=CH2)3)2 (2a–e) as moderately air-sensitive yellow-orange oils in 60–75 % yields after workup. These and NO+BF4– react to give the cationic iron dicarbonyl nitrosyl complexes trans-[Fe(CO)2(NO)(P((CH2)mCH=CH2)3)2]+BF4– (3a–e;

  （BDA）Fe（CO）3（BDA =亚苄基丙酮）与P（（CH 2）m CH = CH 2）3（1 ; m  = 4，a ; 5，b ; 6，c ; 7，d ; 8，ë）得到三角双锥双（膦）配合物的反式-Fe（CO）3（P（（CH 2）米CH = CH 2）3）2（2A - E）为中度空气敏感的黄色-橙色油后处理的产率为60–75％。这些与否+ BF 4 -的反应，得到阳离子型铁二羰基亚硝酰基配合物的反式- [铁（CO）2（NO）（P（（CH 2）米CH = CH 2）3）2 ] + BF 4 - （图3a - ë ;橙油，88–98％）。用n -Bu 4 N + X –（X = Cl，Br，I或CN）进行进一步取代，得到反式-Fe（CO）（NO）（X）（P（（CH 2）m CH = CH 2）3）2（4a – e - X；红油，73–93％）。详细分析了这些加合物的NMR（1 H，13 C，31
• Long-term stable photoactive composition, such as phosphorescent composition or TTA-photon upconversion composition
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP2851407A1

  公开（公告）日：2015-03-25

  A long-term stable photoactive composition, such as a phosphorescent composition or a TTA-photon upconversion composition, contains at least one compound, which has a triplet state capable of energy transfer via an emissive process or a non-emissive process, and at least one compound capable of reacting with singlet oxygen, wherein the at least one compound capable of reacting with singlet oxygen comprises at least one terminal unsaturated carbon-carbon bond, and wherein the at least one compound capable of reacting with singlet oxygen is contained in the composition in such an amount that the number of terminal unsaturated carbon-carbon bonds is at least 100 times higher in the composition than the number of molecules of all compounds having a triplet state capable of energy transfer via an emissive process or a non-emissive process.

  一种长期稳定的光活性组合物，如磷光组合物或 TTA 光子上转换组合物，包含至少一种化合物，该化合物具有能够通过发射过程或非发射过程进行能量转移的三重态，以及至少一种能够与单线态氧反应的化合物，其中至少一种能够与单线态氧反应的化合物包含至少一个末端不饱和碳-碳键、其中至少一种能与单线态氧反应的化合物在组合物中的含量，使组合物中末端不饱和碳-碳键的数量比所有具有能通过发射过程或非发射过程进行能量转移的三重态的化合物分子数量至少高 100 倍。
• LONG-TERM STABLE PHOTOACTIVE COMPOSITION, SUCH AS PHOSPHORESCENT COMPOSITION OR TTA-PHOTON UPCONVERSION COMPOSITION
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP3049502B1

  公开（公告）日：2020-04-01
• [EN] LONG-TERM STABLE PHOTOACTIVE COMPOSITION, SUCH AS PHOSPHORESCENT COMPOSITION OR TTA-PHOTON UPCONVERSION COMPOSITION<br/>[FR] COMPOSITION PHOTOACTIVE STABLE À LONG-TERME, TELLE QU'UNE COMPOSITION PHOSPHORESCENTE OU UNE COMPOSITION DE CONVERSION ASCENDANTE DE PHOTONS PAR TTA
  申请人：MAX PLANCK GES ZUR FÖRDERUNG DER WISSENSCHAFTEN E V

  公开号：WO2015044129A1

  公开（公告）日：2015-04-02

  A long-term stable photoactive composition, namely a phosphorescent composition or a TTA-photon upconversion composition, contains: a) at least one compound, which has a triplet state capable of energy transfer via an emissive process or a non-emissive process, wherein the at least one compound having a triplet state is i) at least one phosphorescent compound and/ or ii) at least one sensitizer compound being capable of absorbing radiation at a first frequency v1and at least one emissive compound, wherein the at least one sensitizer compound is capable of transferring energy to the at least one emissive compound and wherein the at least one emissive compound, after obtaining energy transferred from the at least one sensitizer compound, is capable of emitting light at a second frequency v2, wherein the following equation is fulfilled: v2>v1, wherein the at least one sensitizer compound is capable of a triplet-triplet energy transfer to the at least one emissive compound and wherein the at least one emissive compound is preferably capable of a triplet-triplet annihilation, and b) at least one compound capable of reacting with singlet oxygen, wherein the at least one compound capable of reacting with singlet oxygen comprises at least one terminal unsaturated carbon-carbon bond and is selected from the group consisting of compounds having anyone of the general formulae (I) to (X).