chloro-(2,4,6-trichloro-phenylhydrazono)-acetic acid ethyl ester | 53729-07-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chloro-(2,4,6-trichloro-phenylhydrazono)-acetic acid ethyl ester
• 英文别名: Chlor-(2,4,6-trichlor-phenylhydrazono)-essigsaeure-aethylester；ethyl chloroglyoxylate 2-(2,4,6-trichlorophenyl)-hydrazone；Ethyl chloro[2-(2,4,6-trichlorophenyl)hydrazinylidene]acetate；ethyl 2-chloro-2-[(2,4,6-trichlorophenyl)hydrazinylidene]acetate
• CAS: 53729-07-0
• 化学式: C₁₀H₈Cl₄N₂O₂
• 分子量: 329.998
• InChiKey: NDKJJMNJPYSZDC-UHFFFAOYSA-N

物化性质

• 熔点：
  74 °C
• 沸点：
  378.6±52.0 °C(Predicted)
• 密度：
  1.53±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  50.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  chloro-(2,4,6-trichloro-phenylhydrazono)-acetic acid ethyl ester 在 氨 作用下， 生成 amino-(2,4,6-trichloro-phenylhydrazono)-acetic acid ethyl ester
  参考文献：
  名称：

  Chattaway; Lye, Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1932, vol. 135, p. 282,297

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氯 、 溶剂黄146 作用下， 生成 chloro-(2,4,6-trichloro-phenylhydrazono)-acetic acid ethyl ester
  参考文献：
  名称：

  Chattaway; Daldy, Journal of the Chemical Society, 1928, p. 2761,2762

  摘要：

  DOI：

文献信息

• 1'-Formyl-1'-halobenzeneazomethane compounds having herbicidal activity
  申请人：The Upjohn Company

  公开号：US04006132A1

  公开（公告）日：1977-02-01

  Compounds of the formula: ##STR1## WHEREIN R is alkyl of from 1 to 8 carbon atoms, inclusive; alkoxy of from 1 to 8 carbon atoms, inclusive; haloalkoxy of from 1 to 8 carbon atoms, inclusive; cycloalkyl of from 3 to 8 carbon atoms, inclusive; cycloalkoxy of from 3 to 8 carbon atoms, inclusive; or haloalkyl of from 1 to 8 carbon atoms, inclusive; R' is lower-alkyl of from 1 to 8 carbon atoms, inclusive, phenyl, cycloalkyl of from 3 to 8 carbon atoms, inclusive; or X; X is bromine, chlorine, or fluorine; m is an integer 0 through 5, inclusive, and Y is (independently when m is more than 1) halogen, lower-alkyl of from 1 to 4 carbon atoms, inclusive, lower-alkoxy of from 1 to 4 carbon atoms, inclusive, or halolower-alkyl of from 1 to 4 carbon atoms, inclusive; providing however, that m is 2 to 5 whenever R' is X, and that the sum of the carbon atoms in substituents (Y).sub.m is not more than 15.

  该化合物的分子式为：##STR1## 其中，R为1-8个碳原子的烷基、1-8个碳原子的烷氧基、1-8个碳原子的卤代烷氧基、3-8个碳原子的环烷基、3-8个碳原子的环烷氧基或1-8个碳原子的卤代烷基；R'为1-8个碳原子的较低烷基、苯基、3-8个碳原子的环烷基或X；X为溴、氯或氟；m为0-5的整数，Y为（当m大于1时）卤素、1-4个碳原子的较低烷基、1-4个碳原子的较低烷氧基或1-4个碳原子的卤代较低烷基。但是，当R'为X时，m为2-5，并且取代基（Y）的碳原子总数不超过15。
• Chattaway; Daldy, Journal of the Chemical Society, 1928, p. 2761,2762
  作者：Chattaway、Daldy

  DOI：——

  日期：——
• Chattaway; Lye, Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1932, vol. 135, p. 282,297
  作者：Chattaway、Lye

  DOI：——

  日期：——