terphenyl-2,5,2',5'-tetracarboxylic acid | 1365548-77-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: terphenyl-2,5,2',5'-tetracarboxylic acid
• 英文别名: [1,1':4',1"-Terphenyl]-2,2",5,5"-tetracarboxylic acid；2-[4-(2,5-dicarboxyphenyl)phenyl]terephthalic acid
• CAS: 1365548-77-1
• 化学式: C₂₂H₁₄O₈
• 分子量: 406.348
• InChiKey: WQLZLYNBQDKQTC-UHFFFAOYSA-N

物化性质

• 沸点：
  718.7±60.0 °C(Predicted)
• 密度：
  1.504±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  149
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  gadolinium(III) nitrate hexahydrate 、 terphenyl-2,5,2',5'-tetracarboxylic acid 在 硝酸 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 72.0h， 以72%的产率得到
  参考文献：
  名称：

  RETRACTED: Two metal-organic frameworks for selective C2H2/CO2 separation and exert therapeutic effect on postpartum hemorrhage by increasing the prothrombin activity

  摘要：

  In this research, two novel MOFs have been prepared through utilizing two similar organic tetracarboxylic ligands with different functional groups, and their chemical formulae are (H2NMe2)[(Gd (L-1)(H2O)2]center dot 2H(2)O (1, L-1 = [1,184',1 ''-terphenyl]-2,2 '',5,5 ''-tetracarboxylic acid) and [Gd-3(L-2)(2)(HCOO)(H2O)(4)]center dot 6H(2)O (2, L-2 = 2',5'-difluoro-[1,1':4',]''-terphenyl]-2,2 '',5,5 ''-tetracarboxylic acid). The gas sorption measurements reveal that complex 2 could selective adsorb C2H2 from a mixture of C2H2/CO2 around the ambient temperature. In order to generate novel candidates to conduct the treatment of postpartum hemorrhage, the prothrombin time (PT) and fibrinogen (FIB) determination was conducted after compounds treatment. The levels of inflammatory cytokines of TNF-alpha and IL-1 beta on postpartum hemorrhage animal model were evaluated with ELISA detection kit.

  DOI：

  10.1016/j.jssc.2020.121629
• 作为产物：
  描述：

  2-溴四苯醌 在 potassium phosphate 、 四(三苯基膦)钯 、 palladium bis[bis(diphenylphosphino)ferrocene] dichloride 、 硫酸 、 水 、 potassium acetate 、 sodium hydroxide 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 182.0h， 生成 terphenyl-2,5,2',5'-tetracarboxylic acid
  参考文献：
  名称：

  基于三联苯-2,5,2',5'-四羧酸的三种配位聚合物的合成及晶体结构

  摘要：

  三联苯-2,5,2',5'-四羧酸 (H4qptc) 和 MII (M=Co, Ni, Cu) 在 2,2'-联吡啶 (2,2'-bpy) 存在下的溶剂热反应得到三种新的配位聚合物，[M(qptc)0.5(2,2'-bpy)(H2O)] n (M=Co (1), Ni (2)) 和 [Cu(H2qptc)(2,2'-bpy) )] n (3)。结构已通过单晶 X 射线衍射分析确定，并通过元素分析、IR 和 TGA 进一步表征。复合物 1 和 2 是同构的并显示出二维层，其中 qptc4- 是连接 CoII 中心的扭曲 H 形配体。此外，1和2中的3-D结构是通过相邻2,2'-bpy配体之间的链间π…π相互作用形成的，质心-质心距离为3.619-3.822 Å。在图 3 中，H2qptc2- 的两个去质子化羧基是 Z 形配体，将 CuII 中心连接到一维锯齿形聚合物链。

  DOI：

  10.1080/00958972.2012.713099
• 作为试剂：
  描述：

  4,4-二(1H-咪唑-1-基)-1,1-联苯 、 nickel(II) chloride hexahydrate 、 水 在 terphenyl-2,5,2',5'-tetracarboxylic acid 、 sodium hydroxide 作用下， 反应 72.0h， 以51%的产率得到{[Ni0.5(4,4′-bis(imidazol-1-yl)biphenyl)Cl][(4,4′-bis(imidazol-1-yl)biphenyl)0.5]·H2O}n
  参考文献：
  名称：

  Coordination polymers (Ni^II and Co^II) based on the rigid bridging ligand, 4,4′-bis(imidazol-1-yl)biphenyl, with (4⁶) topology

  摘要：

  Two coordination polymers, {[Ni-0.5(4,4'-bib)Cl][(4,4'-bib)(0.5)]center dot H2O}(n) (1) and {[Co(4,4'-bib)(3)(H2O)(2)][NO3](2)center dot H2O}(n) (2) (4,4'-bib = 4,4'-bis(imidazol-1-yl)biphenyl) have been hydrothermally synthesized. Their structures have been determined by single-crystal X-ray diffraction analyses and are further characterized by elemental analyses, IR, thermogravimetric analyses, and powder X-ray diffraction. In 1, each Ni-II is linked by four mu(2-4),4'-bib ligands in 2-D (4,4)-networks, which are further connected through host-guest interaction to form a 3-D packing diagram with 1-D channels. In 2, each Co-II is linked by two mu(2-4),4'-bib and two mu(1-4),4'-bib ligands in a 1-D zigzag chain, further connected through non-covalent interactions (including O-H center dot center dot center dot N, O-H center dot center dot center dot O, C-H center dot center dot center dot pi, and pi center dot center dot center dot pi interactions) to form a 3-D supramolecular structure. 4,4'-bib exhibits mu(2)-, mu(1)-, and mu(0)-coordination during the construction of 1 and 2. From the topological view, the overall structures of 1 and 2 possess (4(6)) topology.

  DOI：

  10.1080/00958972.2013.798653

文献信息

• A series of coordination polymers based on terphenyl tetracarboxylates and bis-pyridyl ligands with water vapor sorption properties
  作者：Ling Li、Lei Lv、Ru-Dan Huang

  DOI：10.1039/c6ra25319a

  日期：——

  Six new coordination polymers, namely, [Mn2(L1)(bpfp)(H2O)2]·6H2O·(CH3OH)}n (1), [Mn4(μ3-O)2(L1)2(bpe)2(H2O)2]·2H2O}n (2), [Ni(HL1)(Hbpmp)(H2O)2]n (3), [Co2(μ2-OH)(HL1)(bpmp)(H2O)4]n (4), [Co2(L2)(bpfp)(H2O)2]·4H2O}n (5), [Co2(L2)2(bpe)2(H2O)2·2H2O]·(NH4)4}n (6) (H4L1 = [1,1′:4′,1′′-terphenyl]-2,2′′,5,5′′-tetracarboxylic acid, H4L2 = [1,1′:4′,1′′-terphenyl]-3,3′′,5,5′′-tetracarboxylic acid, bpfp

  六个新的配位聚合物，即，[锰2（L1）（bpfp）（H 2 O）2 ]·6H 2 O·（CH 3 OH）} Ñ（1），[锰4（μ 3 -O）2（L1）2（bpe）2（H 2 O）2 ]·2H 2 O} n（2），[Ni（HL1）（Hbpmp）（H 2 O）2 ] n（3），[Co 2（ μ 2 -OH）（HL1）（的Bpmp）（H 2 O）4 ] ñ（4），[Co 2（L2）（bpfp）（H 2 O）2 ]·4H 2 O} n（5），[Co 2（L2）2（bpe）2（H 2 O）2 · 2H 2 O]·（NH 4）4 } n（6）（H 4 L1 = [1,1'：4'，1''-三联苯] -2,2''，5,5''-四羧酸，H 4 L2 = [1,1'：4'，1''-三联苯] -3,3''，5,5''-四羧酸，bpfp =双（4-吡啶基甲酰基）哌嗪，bpe = 1， 2-双（吡啶-4-基）乙烷和bpmp
• Syntheses, crystal structures and UV-visible absorption properties of five metal–organic frameworks constructed from terphenyl-2,5,2′,5′-tetracarboxylic acid and bis(imidazole) bridging ligands
  作者：Liming Fan、Xiutang Zhang、Wei Zhang、Yuanshuai Ding、Weiliu Fan、Liming Sun、Yue Pang、Xian Zhao

  DOI：10.1039/c3dt53379d

  日期：——

  and 2 are isomorphous and exhibit a 3D (3,4)-connected tfi framework with the point Schläfli symbol of (4·62)(4·66·83). Complex 3 shows an unprecedented 3D (4,4)-connected framework with the point Schläfli symbol of (4·64·82)2(42·84). Complex 4 displays a novel 2D self-catenating 5-connected network with the Schläfli symbol of (46·64) based on three interpenetrating 44-sql subnets. Complex 5 features

  在四个双（咪唑）存在下，二苯基-2,5,2'，5'-四羧酸（H 4 TPTc）与过渡金属阳离子（Ni II，Mn II）的溶剂热反应提供了五个新颖的配位聚合物（CPs） ）桥接配体（1,3-bimb = 1,3-双（咪唑-1-基甲基）苯，1,4-bmib = 1,4-双（2-甲基咪唑-1-基甲基）苯，4,4' -bibp = 4,4'-双（咪唑-1-基）联苯，4,4'-bimbp = 4,4'-双（咪唑-1-基甲基）联苯），即[M（TPTc）0.5（ 1,3- BIMB）（H 2 O）] ñ（M =镍为1，锰为2），[镍（TPTC）0.5（1,4- bmib）]·0.25H 2 ö} ñ（3），[Ni（TPTc）0.5（4,4'-bibpp）2（H 2 O）]·2H 2 O} n（4）和[Ni（TPTc）0.5（4,4'-bimbp）1.5（H 2 O）]·H 2 O} n（5）。它
• Polyamide chain extension process and functionalized polyamides produced thereby
  申请人：——

  公开号：US20020007041A1

  公开（公告）日：2002-01-17

  Polyamides including functional groups and methods of preparing such polyamides. The polyamides are useful, for example, to prepare filaments.

  聚酰胺包括功能基团及其制备方法。例如，这些聚酰胺可用于制备纤维。
• A pillar-layered binuclear 3D cobalt(<scp>ii</scp>) coordination polymer as an electrocatalyst for overall water splitting and as a chemosensor for Cr(<scp>vi</scp>) anion detection
  作者：Dongsheng Zhao、Junqi Song、Xiutang Zhang、Feng Wang、Bei Li、Lulu Yang、Yuxin Deng、Qingbo Li、Liming Fan

  DOI：10.1039/d1ce00685a

  日期：——

  A 3D pillar-layered cobalt(ii) CP with a 3D (4,6)-connected 4⁴·6¹⁰·8}4⁴·6²} fsc net was designed and it showed great potential as an electrocatalyst in the overall water splitting and as a chemosensor for Cr(vi) anion detection.

  一种三维柱状层状钴（II）配合物被设计出来，其具有一个三维（4,6）连接的4^4·6^10·8}4^4·6^2} fsc 网络，表现出在整体水分解中作为电催化剂和作为 Cr（VI）阴离子检测的化学传感器的巨大潜力。
• A Fluorescent Anionic MOF with Zn₄(trz)₂ Chain for Highly Selective Visual Sensing of Contaminants: Cr(III) Ion and TNP
  作者：Xiao-Xia Jia、Ru-Xin Yao、Fu-Qiang Zhang、Xian-Ming Zhang

  DOI：10.1021/acs.inorgchem.6b02872

  日期：2017.3.6

  Zn4(trz)2 chain-based 3D anionic structure with channels filled by [Me2NH2]+ cations. It is worth noting that the material exhibits selective adsorption and recyclable detection of heavy-metal Cr3+ ion in aqueous solutions, which may be the synergy from the metal charge, bond ability of metal ions to carboxylate oxygen atom, and soft–hard acid–base properties. Furthermore, it can selectively sense of 2

  重金属离子和硝基芳族物质具有剧毒，对人体健康和生态环境有害。选择性检测和捕获这些有毒物质是迫在眉睫的问题。通过将三唑配体引入π-共轭芳族羧酸酯体系并借鉴有机模板开放骨架的思想，可以得到稳定的荧光骨架[Me 2 NH 2 ] 4 [Zn 6（qptc）3（trz）4 ]·6H 2 O（1）（H 4 qptc =联苯-2,5,2'5'-四羧酸，trz = 1,2,4-三唑）已成功合成，它具有Zn 4（trz）2链的3D阴离子结构，其通道充满[Me 2 NH 2 ] +阳离子。值得注意的是，该材料在水溶液中表现出对重金属Cr 3+离子的选择性吸附和可回收检测，这可能是金属电荷，金属离子与羧酸氧原子的键合能力以及软硬酸的协同作用。 –基本属性。此外，它可以选择性地感测具有2,08，10 6 M –1的大淬灭系数K sv的2,4,6-三硝基苯酚。