N₆,N₆'-diethyl-N₆,N₆'-di(3-fluorophenyl)-[2,2'-bipyridine]-6,6'-dicarboxamide | 1422573-62-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N₆,N₆'-diethyl-N₆,N₆'-di(3-fluorophenyl)-[2,2'-bipyridine]-6,6'-dicarboxamide
• 英文别名: N-ethyl-6-[6-[ethyl-(3-fluorophenyl)carbamoyl]pyridin-2-yl]-N-(3-fluorophenyl)pyridine-2-carboxamide
• CAS: 1422573-62-3
• 化学式: C₂₈H₂₄F₂N₄O₂
• 分子量: 486.521
• InChiKey: NCCZOGLRMWKLPF-UHFFFAOYSA-N

物化性质

• 沸点：
  686.5±55.0 °C(predicted)
• 密度：
  1.289±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.76
• 重原子数：
  36.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  66.4
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  N₆,N₆'-diethyl-N₆,N₆'-di(3-fluorophenyl)-[2,2'-bipyridine]-6,6'-dicarboxamide 、 uranyl 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  New potentialities of the UNEX process using polyheterocyclic diamides

  摘要：

  The possibilities of using 2,2 '-bipyridine-6,6 '-dicarboxamides in modified versions of the UNEX process were examined. The stability constants of complexes of Eu(III), Am(III), Th(IV), U(VI), and Np(V) ions with certain diamides substituted in the amide moiety or pyridine ring in acetonitrile were determined. The logarithms of the stability constants exceeded 7 for Eu(III) and reached 9 for 5f elements. The ability of the selected diamides in nitrobenzene and trifluoromethyl phenyl sulfone (FS-13) diluents to extract Am(III), Th(IV), U(VI), and Eu(III) was studied.

  DOI：

  10.1134/s1066362216060072
• 作为产物：
  描述：

  2,2'-联吡啶-6,6'-二羧酸 在 氯化亚砜 、 三乙胺 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 2.5h， 生成 N₆,N₆'-diethyl-N₆,N₆'-di(3-fluorophenyl)-[2,2'-bipyridine]-6,6'-dicarboxamide
  参考文献：
  名称：

  Novel diamides of 2,2′-dipyridyl-6,6′-dicarboxylic acid: synthesis, coordination properties, and possibilities of use in electrochemical sensors and liquid extraction

  摘要：

  该程序被提出用于合成各种二吡啶二酰胺。研究了它们在稀土元素系列中的各种性质。展示了利用合成的化合物在电化学传感器聚合物膜中开发新型传感器的可能性。进行了配体结构对萃取和传感器特性的影响的比较。

  DOI：

  10.1007/s11172-012-0124-4

文献信息

• Novel diamides of 2,2′-dipyridyl-6,6′-dicarboxylic acid: synthesis, coordination properties, and possibilities of use in electrochemical sensors and liquid extraction
  作者：D. O. Kirsanov、N. E. Borisova、M. D. Reshetova、A. V. Ivanov、L. A. Korotkov、I. I. Eliseev、M. Yu. Alyapyshev、I. G. Spiridonov、A. V. Legin、Yu. G. Vlasov、V. A. Babain

  DOI：10.1007/s11172-012-0124-4

  日期：2012.4

  The procedure was proposed for the synthesis of various dipyridyldiamides. Their various properties in the series of rare-earth elements were studied. The possibility to use the synthe-sized compounds in polymer membranes of electrochemical sensors for the development of novel types of sensors was shown. A comparison of the influence of the ligand structure on the extraction and sensor characteristics was performed.

  该程序被提出用于合成各种二吡啶二酰胺。研究了它们在稀土元素系列中的各种性质。展示了利用合成的化合物在电化学传感器聚合物膜中开发新型传感器的可能性。进行了配体结构对萃取和传感器特性的影响的比较。
• New potentialities of the UNEX process using polyheterocyclic diamides
  作者：N. E. Borisova、L. A. Korotkov、A. V. Ivanov、J. Lapka、A. Paulenova、E. V. Belova、S. V. Stefanovsky、B. F. Myasoedov

  DOI：10.1134/s1066362216060072

  日期：2016.11

  The possibilities of using 2,2 '-bipyridine-6,6 '-dicarboxamides in modified versions of the UNEX process were examined. The stability constants of complexes of Eu(III), Am(III), Th(IV), U(VI), and Np(V) ions with certain diamides substituted in the amide moiety or pyridine ring in acetonitrile were determined. The logarithms of the stability constants exceeded 7 for Eu(III) and reached 9 for 5f elements. The ability of the selected diamides in nitrobenzene and trifluoromethyl phenyl sulfone (FS-13) diluents to extract Am(III), Th(IV), U(VI), and Eu(III) was studied.