A cured composition including a reaction product of a mixture that includes an isocyanate component having one or more isocyanates and an isocyanate-reactive component having a butylene oxide based polyol, which has a number average molecular weight greater than 2,000 g/mol and less than 8,000 g/mol and a nominal hydroxyl functionality from (2) to (4). At least (50) wt % of a total weight of alkylene oxides used to form the butylene oxide based polyol is butylene oxide. An isocyanate index of the mixture is from (90) to (150). The cured composition in a cured state exhibits a first tan delta peak between a first temperature range of 50° C. to 0° C. and a second tan delta peak between a second temperature range of 75° C. and 150° C., according to a tan delta plot over a range of temperatures, and a value of the first tan delta peak and a value of the second tan delta peak each represents a ratio of a loss modulus of the cured composition and a storage modulus of the cured composition at a specific temperature within the range of temperatures, as measured according to dynamic mechanical thermal analysis. The values of the first and the second tan delta peaks are from (0.10) to (0.90).
一种固化组合物,包括一种混合物的反应产物,该混合物包括具有一种或多种
异氰酸酯的
异氰酸酯组分和具有
环氧丁烯基多元醇的
异氰酸酯反应组分,
环氧丁烯基多元醇的平均分子量大于 2,000 克/摩尔且小于 8,000 克/摩尔,标称羟基官能度为(2)至(4)。用于形成
环氧丁烯基多元醇的氧化亚
烷烃的总重量中至少有 (50) wt % 是
环氧丁烯。混合物的
异氰酸酯指数为 (90) 至 (150)。在固化状态下,固化组合物在 50° C 至 0° C 的第一温度范围内显示第一 tan delta 峰值,在 75° C 至 150° C 的第二温度范围内显示第二 tan delta 峰值、根据温度范围内的 tan delta 图,第一 tan delta 峰值和第二 tan delta 峰值各代表固化组合物的损耗模量和固化组合物在温度范围内特定温度下的存储模量之比,该比值是根据动态机械热分析测得的。第一和第二 tan delta 峰的值从 (0.10) 到 (0.90)。