Dichlor-methyl-<2-phenylmercapto-aethyl>-silan | 17878-22-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Dichlor-methyl-<2-phenylmercapto-aethyl>-silan
• 英文别名: Dichloro-methyl-(2-phenylsulfanylethyl)silane；dichloro-methyl-(2-phenylsulfanylethyl)silane
• CAS: 17878-22-7
• 化学式: C₉H₁₂Cl₂SSi
• 分子量: 251.252
• InChiKey: CJVRKJUPDOOFIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.33
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Dichlor-methyl-<2-phenylmercapto-aethyl>-silan 、 potassium acetate 以 甲苯 为溶剂， 生成 methyl(2-(phenylthio)ethyl)silanediyl diacetate
  参考文献：
  名称：

  Andrianov,K.A. et al., Journal of general chemistry of the USSR, 1971, vol. 41, p. 883 - 885

  摘要：

  DOI：
• 作为产物：
  描述：

  甲基乙烯基二氯硅烷 、 苯硫酚 在 二苯甲酮 作用下， 反应 14.0h， 以98%的产率得到Dichlor-methyl-<2-phenylmercapto-aethyl>-silan
  参考文献：
  名称：

  Orthogonal reactivity of thiols toward chlorovinylsilanes: selective thiol-ene chemistry

  摘要：

  A variety of new chlorosilanes were synthesized by the selective thiol-ene reactions of various thiols (ethanethiol, 1,2-ethanedithiol, benzenethiol, and tetrakis(2-sulfanylethyl)silicate) with chlorovinylsilanes (chlorodimethylvinylsilane, dichloromethylvinylsilane, and trichlorovinylsilane). No silylthioester products were observed. All products were obtained in quantitatime or near quantitative yields and were characterized using multinuclear NMR (H-1, C-13, Si-29) spectroscopy. The products required no further purification. An example is presented which highlights the potential use of these compounds for future applications. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.09.113

文献信息

• Orthogonal reactivity of thiols toward chlorovinylsilanes: selective thiol-ene chemistry
  作者：Abby R. Jennings、Zahra S. Bassampour、Anish G. Patel、David Y. Son

  DOI：10.1016/j.tetlet.2014.09.113

  日期：2014.12

  A variety of new chlorosilanes were synthesized by the selective thiol-ene reactions of various thiols (ethanethiol, 1,2-ethanedithiol, benzenethiol, and tetrakis(2-sulfanylethyl)silicate) with chlorovinylsilanes (chlorodimethylvinylsilane, dichloromethylvinylsilane, and trichlorovinylsilane). No silylthioester products were observed. All products were obtained in quantitatime or near quantitative yields and were characterized using multinuclear NMR (H-1, C-13, Si-29) spectroscopy. The products required no further purification. An example is presented which highlights the potential use of these compounds for future applications. (C) 2014 Elsevier Ltd. All rights reserved.
• Andrianov,K.A. et al., Journal of general chemistry of the USSR, 1971, vol. 41, p. 883 - 885
  作者：Andrianov,K.A. et al.

  DOI：——

  日期：——