dimethyl 3,6-dimethyl-4,5-diphenylphthalate | 86552-03-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dimethyl 3,6-dimethyl-4,5-diphenylphthalate
• 英文别名: Dimethyl 3,6-dimethyl-4,5-diphenylbenzene-1,2-dicarboxylate
• CAS: 86552-03-6
• 化学式: C₂₄H₂₂O₄
• 分子量: 374.436
• InChiKey: QYFOMSSCSULOTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dimethyl 3,6-dimethyl-4,5-diphenylphthalate 在 氢氧化钾 作用下， 生成 3,6-Dimethyl-4,5-diphenyl-phthalsaeure-anhydrid
  参考文献：
  名称：

  Carbonyl Bridge Compounds

  摘要：

  DOI：

  10.1021/ja01258a006
• 作为产物：
  描述：

  5-O,6-O-dibenzyl 2-O,9-O-dimethyl 1,10-dimethyl-13-oxo-11,12-diphenyl-5,6-diazapentacyclo[8.2.1.14,7.02,9.03,8]tetradec-11-ene-2,5,6,9-tetracarboxylate 在 palladium on activated charcoal 、 mercury(II) oxide 作用下， 以 乙酸乙酯 为溶剂， 生成 dimethyl 3,6-dimethyl-4,5-diphenylphthalate
  参考文献：
  名称：

  A transannular π-bond pairing approach to the synthesis of 1,3-cyclopentadiene diesters and maleimido-oxepines and a report on their isomerisation.

  摘要：

  DOI：

  10.1016/s0040-4039(00)97246-0

文献信息

• REACTION OF PYRIDINIUM PHENACYLIDES AND RELATED YLIDES WITH CYCLOPENTADIENONE DERIVATIVES
  作者：Yoshiro Yamashita、Yukio Miyauchi、Mitsuo Masumura

  DOI：10.1246/cl.1983.489

  日期：1983.4.5

  Reaction of pyridinium phenacylides with cyclopentadienone derivatives gave bicyclo[3.1.0]hex-3-en-2-one derivatives by the nucleophilic addition reaction followed by pyridine elimination. Isoquinolinium phenacylide underwent the 1,3-dipolar cycloaddition reaction with a cyclopentadienone.

  吡啶鎓phenacylides 与环戊二烯酮衍生物的反应通过亲核加成反应随后吡啶消除得到双环[3.1.0]hex-3-en-2-one衍生物。Isoquinolinium phenacylide 与环戊二烯酮发生 1,3-偶极环加成反应。
• The reaction between 7-oxanorbornadienes and tetraarylcyclopentadienones: a short synthesis of 1,2,3,4-tetraarylbenzenes
  作者：Albert J. Fry、Laura R. Sherman、Alessandrina R. Beaulieu、Carol Sherwin

  DOI：10.1021/jo00288a078

  日期：1990.1
• Photoisomerisation of bicyclo[4.2.0]octadienes to tricyclo[4.2.0.02,5] octenes: Application to the synthesis of [n]ladderanes
  作者：Ronald N. Warrener、Ian G. Pitt、Eric E. Nunn、Colin H.L. Kennard

  DOI：10.1016/s0040-4039(00)75854-0

  日期：1994.1

  A new approach for the extension of [n]adderanes is described which involves formation of an end-fused bicyclo[4.2.0]octadiene and its photoisomerisation to the related tricyclo[4.2.0.0(2,5)] octene as the ladderane extension step. The protocol is illustrated with the synthesis of [3]ladderane (9) from an unsubstituted cyclobutene and nor[5]ladderane (13) from an ester activated cyclobutene. The exo-stereochemistry of (13) is confirmed by reference to intermediate (23) for which a single crystal X-Ray structure analysis was obtained.
• YAMASHITA Y.; MASUMURA M., TETRAHEDRON LETT., 1979, NO 20, 1765-1768
  作者：YAMASHITA Y.、 MASUMURA M.

  DOI：——

  日期：——
• FRY, ALBERT J.;SHERMAN, LAURA R.;BEAULIEU, ALESSANDRINA R.;SHERWIN, CAROL, J. ORG. CHEM., 55,(1990) N, C. 389-391
  作者：FRY, ALBERT J.、SHERMAN, LAURA R.、BEAULIEU, ALESSANDRINA R.、SHERWIN, CAROL

  DOI：——

  日期：——