1-(4-phenylazo-naphthalen-1-ylamino)-anthraquinone | 1333247-44-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-(4-phenylazo-naphthalen-1-ylamino)-anthraquinone
• 英文别名: AAQ；1-[(4-Phenyldiazenylnaphthalen-1-yl)amino]anthracene-9,10-dione；1-[(4-phenyldiazenylnaphthalen-1-yl)amino]anthracene-9,10-dione
• CAS: 1333247-44-1
• 化学式: C₃₀H₁₉N₃O₂
• 分子量: 453.5
• InChiKey: SVLIWAVKDWGQTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70.9
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  1-氯蒽醌 、 4-苯偶氮-1-萘胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 caesium carbonate 、 R-(+)-1,1'-联萘-2,2'-双二苯膦 作用下， 以 甲苯 为溶剂， 反应 7.0h， 以67.8%的产率得到1-(4-phenylazo-naphthalen-1-ylamino)-anthraquinone
  参考文献：
  名称：

  Synthesis of New Single Black Pigments Based on Azo and Anthraquinone Moieties for LCD Black Matrix

  摘要：

  Based on azo group and anthraquinone moiety, new black matrix pigment materials AAQ and DAAQ were synthesized for the first time through Suzuki C-N coupling. As a result of verifying UV-visible absorption spectra of the synthesized materials, DAAQ was found to absorb the entire visible region in 400800nm in solution state with high extinction coefficient of 8.1x103L/cm center dot mol. Realization of black color using a single material is expected to be useful for black matrix application. Also in film state made through spin coating, both AAQ and DAAQ absorbed the entire visible region.

  DOI：

  10.1080/15421406.2010.495684