4-Bromotetrafluorothiophenol | 173441-75-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: 4-Bromotetrafluorothiophenol
• 英文别名: 4-bromotetrafluorobenzenethiol；4-bromo-2,3,5,6-tetrafluorobenzenethiol；4-Bromo-2,3,5,6-tetrafluorobenzene-thiol
• CAS: 173441-75-3
• 化学式: C₆HBrF₄S
• 分子量: 261.038
• InChiKey: TUOPQRPSDZNMBQ-UHFFFAOYSA-N

物化性质

• 沸点：
  203.6±35.0 °C(Predicted)
• 密度：
  1.932±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-Bromotetrafluorothiophenol 在 碘 、 硝酸 作用下， 反应 8.12h， 生成 Perfluoro-2,3-dihydrobenzothiophene-1-oxide
  参考文献：
  名称：

  含氟有机硫的化合物。二。全氟-2,3-二氢苯并[ b ]噻吩的合成及其某些化学性质的研究

  摘要：

  全氟-2,3-二氢苯并[ b ]噻吩（I）和一些全氟茚满，是通过在碘存在下，将许多4-取代的四氟噻吩酚与四氟乙烯进行共水解而获得的。已经研究了硫化物I与某些亲核试剂和氧化剂的相互作用。已经合成了多氟-2，3-二氢苯并噻吩的5-和6-取代的衍生物。

  DOI：

  10.1016/0022-1139(95)03294-n
• 作为产物：
  描述：

  溴五氟苯 在 吡啶 、 potassium hydrosulfide 作用下， 以 乙二醇 为溶剂， 反应 0.25h， 生成 4-Bromotetrafluorothiophenol
  参考文献：
  名称：

  含氟有机硫的化合物。二。全氟-2,3-二氢苯并[ b ]噻吩的合成及其某些化学性质的研究

  摘要：

  全氟-2,3-二氢苯并[ b ]噻吩（I）和一些全氟茚满，是通过在碘存在下，将许多4-取代的四氟噻吩酚与四氟乙烯进行共水解而获得的。已经研究了硫化物I与某些亲核试剂和氧化剂的相互作用。已经合成了多氟-2，3-二氢苯并噻吩的5-和6-取代的衍生物。

  DOI：

  10.1016/0022-1139(95)03294-n

文献信息

• Cu(I)/Chiral Bisoxazoline‐Catalyzed Enantioselective Doyle‐Kirmse Reaction of Allenyl Sulfides with <i>α</i> ‐Diazoesters
  作者：Kang Wang、Shu‐Sen Li、Jianbo Wang

  DOI：10.1002/chem.202200170

  日期：2022.4.12

  A Cu(I)/chiral bisoxazoline-catalyzed enantioselective Doyle-Kirmse reaction of polyfluoroaryl allenyl sulfides with α-diazoesters, generating chiral tertiary homopropargylic sulfides in good enantioselectivities under mild conditions.

  Cu(I)/手性双恶唑啉催化的多氟芳基烯基硫化物与α-重氮酯的对映选择性 Doyle-Kirmse 反应，在温和条件下生成具有良好对映选择性的手性叔丙炔丙基硫化物。
• METHOD FOR PRODUCING STRUCTURE WHEREIN AROMATIC POLYMER IS BONDED TO BASE, STRUCTURE HAVING AROMATIC POLYMER CHAIN BONDED TO CONDUCTIVE BASE, AND ELECTRONIC DEVICE COMPRISING THE STRUCTURE
  申请人：Tanaka Kenta

  公开号：US20100069603A1

  公开（公告）日：2010-03-18

  Disclosed is a method for efficiently producing a structure wherein an aromatic polymer is bonded to a base. Also disclosed is such a structure wherein the base is electrically conductive. Specifically disclosed is a method for producing a structure, which comprises a step for polycondensing an aromatic compound represented by the formula (I) below in the presence of a polymerization catalyst and a base having a group represented by the formula (II) below. MY n Ar—X  (I) (In the formula (I), Ar represents a divalent group composed of an aromatic ring; X represents a halogen atom or the like; Y represents an oxygen atom, a sulfur atom, an imino group or the like; n represents 0 or 1; and M represents a hydrogen atom, —B(OQ 1 ) 2 (wherein Q 1 represents a hydrogen atom, a hydrocarbon group or the like) or the like.) —Ar a —(X a ) p (II) (In the formula (II), Ar a represents a group having a valence of (p+1) and composed of an aromatic ring; X a represents a halogen atom or a monovalent group expressed as —SO 3 Q a (wherein Q a represents a substituted or unsubstituted hydrocarbon group); p represents an integer not less than 1, and when p is an integer not less than 2, the plurality of X a 's may be the same as or different from each other.)

  公开了一种高效生产芳香族聚合物与基体结合的结构的方法。还公开了这样一种结构，其中基体具有电导性。具体公开了一种生产结构的方法，该方法包括在聚合催化剂和具有以下式子（II）中表示的基团的碱存在下，聚合表示为以下式子（I）的芳香族化合物的步骤。MYnAr—X  (I)（在式（I）中，Ar表示由芳香族环组成的二价基团；X表示卤素原子或类似物；Y表示氧原子、硫原子、亚胺基或类似物；n表示0或1；M表示氢原子，-B（OQ1）2（其中Q1表示氢原子、碳氢基团或类似物）或类似物。）—Ara—（Xa）p（II）（在式（II）中，Ararepresents具有（p+1）价且由芳香族环组成的基团；Xarepresents卤素原子或表示为-SO3Qa的一价基团（其中Qarepresents取代或未取代的碳氢基团）；p表示不小于1的整数，当p为不小于2的整数时，Xa的多个可以相同也可以不同。）
• Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5
  作者：P. V. Nikul’shin、А. M. Maksimov、V. Е. Platonov

  DOI：10.1134/s1070428016020068

  日期：2016.2

  Replacement of the thiol group in polyfluoroarenethiols with chlorine was performed by treating with PCl5 as chlorinating agent. By heating in ampules at 200-220A degrees C polyfluoro- and polyfluorochloroarenethiols with PCl5 mono- and dichloropolyfluoroarenes and also 1,2,4-trifluorotrichlorobenzene were synthesized. Dichloropolyfluoroarenes contain chlorine atoms in ortho- and para-positions.
• Reaction of polyfluoroarenesulfonyl bromides with allyl bromide. Synthesis of allyl polyfluoroaryl sulfones
  作者：R. A. Bredikhin、A. M. Maksimov、V. E. Platonov

  DOI：10.1134/s1070428011030080

  日期：2011.3

  Reactions of polyfluoroarenesulfonyl bromides 4-XC6F4SO2Br (X = F, H, Cl, Br, CF3) with allyl bromide gave 84-94% of the corresponding allyl polyfluoroaryl sulfones.
• Fluoroorganic sulphur-containing compounds. II. The synthesis of perfluoro-2,3-dihydrobenzo[b]thiophene and an investigation of some of its chemical properties
  作者：V.E. Platonov、A.M. Maksimov、P.I. Maslovsky

  DOI：10.1016/0022-1139(95)03294-n

  日期：1995.11

  Perfluoro-2,3-dihydrobenzo[b] thiophene (I), along with some quantities of perfluoroindane, has been obtained by copyrolysis of a number of 4-substituted tetrafluorothiophenols with tetrafluoroethylene in the presence of iodine. The interaction of sulphide I with some nucleophilic and oxidizing agents has been studied. The 5-and 6-substituted derivatives of polyfluoro-2,3-dihydrobenzothiophene have

  全氟-2,3-二氢苯并[ b ]噻吩（I）和一些全氟茚满，是通过在碘存在下，将许多4-取代的四氟噻吩酚与四氟乙烯进行共水解而获得的。已经研究了硫化物I与某些亲核试剂和氧化剂的相互作用。已经合成了多氟-2，3-二氢苯并噻吩的5-和6-取代的衍生物。