3-Hexyl-2-methyl-furan | 95904-79-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 3-Hexyl-2-methyl-furan
• 英文别名: 3-Hexyl-2-methylfuran
• CAS: 95904-79-3
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: DXVOUWNXGDGSDU-UHFFFAOYSA-N

物化性质

• 沸点：
  210.5±9.0 °C(Predicted)
• 密度：
  0.887±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  仲辛酮 在 二氯二茂钛 硫酸 、 三氟化硼乙醚 、 ISOBUTYLMAGNESIUM BROMIDE 、 间氯过氧苯甲酸 作用下， 以 甲醇 、 乙醚 、 二氯甲烷 为溶剂， 反应 4.5h， 生成 3-Hexyl-2-methyl-furan
  参考文献：
  名称：

  制备3-三甲基甲硅烷基-2,5-二氢呋喃并将其转化为呋喃的简便方法

  摘要：

  将3-三甲基甲硅烷基-2-丙炔-1-醇（1）进行氢磁化，然后与醛或酮反应，可制得（E）-3-三甲基甲硅烷基-2-链烯-1,4-二醇（2），该物质易于脱水通过用BF 3 OEt 2处理得到3-三甲基甲硅烷基-2,5-二氢呋喃（3）。通过环氧化和随后用H 2 SO 4处理将化合物（3）转化为呋喃（5）。

  DOI：

  10.1016/s0040-4039(01)91120-7

文献信息

• PHOTOELECTRIC CONVERSION ELEMENT AND DYE-SENSITIZED SOLAR CELL
  申请人：FUJI-FILM Corporation

  公开号：EP2903080A1

  公开（公告）日：2015-08-05

  A photoelectric conversion element of the present invention includes a conductive substrate, a photosensitive layer containing an electrolyte, a charge transfer layer containing an electrolyte, and a counter electrode. The photosensitive layer contains semiconductor particles supporting a metal complex dye represented by the following Formula (I). A dye-sensitized solar cell of the present invention includes the photoelectric conversion element.         M(LD)(LA)·(CI)     Formula (I) In the formula, M represents a metal ion; each of LD and LA represents a specific heterocyclic tridentate ligand; and CI represents a counter ion necessary for neutralizing a charge.

  本发明的光电转换元件包括导电基板、含有电解质的光敏层、含有电解质的电荷转移层和对电极。光敏层含有支持由下式（I）表示的金属络合染料的半导体颗粒。本发明的染料敏化太阳能电池包括光电转换元件。 M(LD)(LA)-(CI) 式(I) 式中，M 代表金属离子；LD 和 LA 分别代表特定的杂环三叉配体；CI 代表中和电荷所需的反离子。
• PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, AND DYE SOLUTION
  申请人：FUJIFILM Corporation

  公开号：US20170092434A1

  公开（公告）日：2017-03-30

  A photoelectric conversion element having an electrically conductive support, a photoconductor layer including an electrolyte, a charge transfer layer including an electrolyte, and a counter electrode, in which the photoconductor layer has semiconductor fine particles carrying a metal complex dye represented by the following Formula (1), and a dye-sensitized solar cell; and a metal complex dye and a dye solution, each of which is used in the photoelectric conversion element and the dye-sensitized solar cell, ML1L2(X) n1 .CI mY Formula (1) in the formula, M represents a metal ion, L1 represents a tridentate ligand having a group L V represented by the following Formula (LV-1) or (LV-2); L2 represents a bidentate or tridentate ligand including at least one of aromatic ring groups having a specific sp 2 carbon atom to which a substituent is bonded; X represents a monodentate ligand; n1 represents 0 or 1; CI represents a required counterion; and mY represents an integer of 0 to 3, —R V1 ═R V2 —R V31 Formula (LV-1) —C≡C—R V32 Formula (LV-2) in the formulae, R V1 and R V2 each independently represent a nitrogen atom or CR V4 , R V4 represents a hydrogen atom or a substituent, R V31 represents a fused polycyclic aromatic ring group or a fused polycyclic heterocyclic group, and R V32 represents a fused polycyclic aromatic ring group or a heteroaryl group.
• A convenient method for the preparation of 3-trimethylsilyl-2,5-dihydrofurans and their conversion to furans
  作者：Fumie Sato、Hiroshi Kanbara、Youichi Tanaka

  DOI：10.1016/s0040-4039(01)91120-7

  日期：1984.1

  or ketones affords (E)-3-trimethylsilyl-2-alken-1,4-diols (2), which can be readily dehydrated to 3-trimethylsilyl-2,5-dihydrofurans (3) by treatment with BF3OEt2. The compounds (3) are converted to furans (5) by epoxidation and subsequent treatment with H2SO4.

  将3-三甲基甲硅烷基-2-丙炔-1-醇（1）进行氢磁化，然后与醛或酮反应，可制得（E）-3-三甲基甲硅烷基-2-链烯-1,4-二醇（2），该物质易于脱水通过用BF 3 OEt 2处理得到3-三甲基甲硅烷基-2,5-二氢呋喃（3）。通过环氧化和随后用H 2 SO 4处理将化合物（3）转化为呋喃（5）。