2-methylundecane-1,11-diol | 10348-43-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-methylundecane-1,11-diol
• CAS: 10348-43-3
• 化学式: C₁₂H₂₆O₂
• 分子量: 202.337
• InChiKey: CIGNWKYMOLNJPU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  tert-butyldimethyl((9-(2-methyloxiran-2-yl)nonyl)oxy)silane 在 [(cyclopentadienyl)(titanium)(chloride)(C5H4C(CH3)2CH2C(NH(Bn))O)] chloride 、 四丁基氟化铵 、 2,4,6-collidine hydrochloride 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 46.0h， 生成 2-methylundecane-1,11-diol
  参考文献：
  名称：

  氢原子转移催化中酰胺取代的钛新世

  摘要：

  报道了两个新的氢原子转移（HAT）催化体系，涉及钛茂（III）配合物与侧基酰胺配体的N-H键。在单金属体系中，使用双官能催化剂，其根据酰胺配体的配位通过HAT催化产生和还原自由基。侧基酰胺配体用于活化Crabtree催化剂，以产生有效的双金属体系，用于自由基生成和HAT催化。

  DOI：

  10.1002/anie.201509548

文献信息

• Tandem Reductive Hydroformylation of Castor Oil Derived Substrates and Catalyst Recycling by Selective Product Crystallization
  作者：Marc R. L. Furst、Vedat Korkmaz、Tom Gaide、Thomas Seidensticker、Arno Behr、Andreas J. Vorholt

  DOI：10.1002/cctc.201700965

  日期：2017.12.8

  An orthogonal tandem catalytic system consisting of rhodium and ruthenium complexes yielded linear C12 α,ω‐bifunctional compounds from commercial, castor oil derived renewable substrates. With aldehyde yields up to 88 % and selectivities to the linear species of up to 95 %, this approach is direct and atom economic and provides easy access to potential polymer precursors for polycondensates. Additionally

  正交串联催化系统，包括产生直链C铑和钌络合物的12 α，从商业，蓖麻油ω-双官能化合物衍生而来的可再生的底物。醛的收率高达88％，对线性物质的选择性高达95％，这种方法是直接的，原子经济的，可轻松获得潜在的缩聚物聚合物前体。此外，还开发了一种直接的选择性产物结晶方法，该方法可将串联催化体系循环使用两次，具有出色的活性，并同时提供了高纯度的产物。
• Merging Catalysis in Single Electron Steps with Photoredox Catalysis—Efficient and Sustainable Radical Chemistry
  作者：Zhenhua Zhang、Ruben B. Richrath、Andreas Gansäuer

  DOI：10.1021/acscatal.9b00787

  日期：2019.4.5

  a combination of catalysts that allows the coupling of titanocene(III) catalysis with photoredox catalysis. Oxidation of radical intermediates by a photoredox catalyst opens novel catalytic mechanisms for reductive epoxide ring opening and redox-neutral epoxide radical arylation. In the former case, the requirement of metallic reductants and stoichiometric acidic additives is bypassed.

  我们描述了催化剂的组合，其允许钛茂（III）催化与光氧化还原催化的偶联。用光氧化还原催化剂氧化自由基中间体可以为还原性环氧开环和氧化还原中性环氧自由基芳基化打开新的催化机理。在前一种情况下，无需使用金属还原剂和化学计量的酸性添加剂。
• PHOTOCURABLE RESIN COMPOSITION
  申请人：Kuraray Noritake Dental Inc.

  公开号：EP3778681A1

  公开（公告）日：2021-02-17

  The present invention provides a photocurable resin composition that has good fabricability, and that exhibits superior flexibility, fracture resistance, and water resistance in the form of a cured product. The present invention relates to a photocurable resin composition comprising: a urethanized (meth)acrylic compound (A); a mono(meth)acrylic acid ester compound (B) containing no urethane bond; and a photopolymerization initiator (C), the urethanized (meth)acrylic compound (A) being a (meth)acrylate comprising, per molecule, at least one kind of structure selected from the group consisting of a polyester, a polycarbonate, a polyurethane, a polyether, a poly-conjugated diene, and a hydrogenated poly-conjugated diene; and a urethane bond, the mono(meth)acrylic acid ester compound (B) containing no urethane bond comprising at least one selected from the group consisting of a mono(meth)acrylic acid ester compound (b-I) represented by general formula (I), and a mono(meth)acrylic acid ester compound (b-II) represented by general formula (II).

  本发明提供了一种光固化树脂组合物，该组合物具有良好的可制造性，并以固化产品的形式表现出优异的柔韧性、抗断裂性和耐水性。本发明涉及一种光固化树脂组合物，包括 聚氨酯化（甲基）丙烯酸化合物 (A)； 不含氨基甲酸酯键的单(甲基)丙烯酸酯化合物 (B)；以及 光聚合引发剂 (C)、 聚氨酯化(甲基)丙烯酸酯化合物(A)是一种(甲基)丙烯酸酯，其每个分子包含至少一种结构，这些结构选自由聚酯、聚碳酸酯、聚氨酯、聚醚、聚共轭二烯和氢化聚共轭二烯组成的组；以及一个聚氨酯键、 不含氨基甲酸乙酯键的单(甲基)丙烯酸酯化合物(B)包括至少一种选自通式(I)代表的单(甲基)丙烯酸酯化合物(b-I)和通式(II)代表的单(甲基)丙烯酸酯化合物(b-II)组成的组。
• RESIN COMPOSITION FOR OPTICAL SHAPING
  申请人：Kuraray Noritake Dental Inc.

  公开号：EP3862373A1

  公开（公告）日：2021-08-11

  The present invention provides a resin composition for optical shaping that, with its low viscosity, enables easy stereolithographical fabrication of an object, and that can produce an object having desirable toughness and desirable water resistance, particularly for dental mouthpieces and denture base materials. The present invention relates to a resin composition for optical shaping comprising a urethanized (meth)acrylic compound (A) and a photopolymerization initiator (B), the urethanized (meth)acrylic compound (A) being a (meth)acrylate containing at least one polyol moiety and a urethane bond per molecule, said at least one polyol moiety being selected from the group consisting of a polyester, a polycarbonate, a polyurethane, and a polyether each having a structure derived from a C4 to C18 aliphatic chain diol unit (a) having a branched structure.

  本发明提供了一种用于光学成型的树脂组合物，该组合物粘度低，可以方便地进行物体的立体平版印刷，并且可以生产出具有理想韧性和理想耐水性的物体，尤其适用于牙科口塞和义齿基底材料。本发明涉及一种用于光学成型的树脂组合物，该树脂组合物包括一种氨基磺酸化 （甲基）丙烯酸化合物（A）和一种光聚合引发剂（B），氨基磺酸化（甲基）丙烯酸化 合物（A）是一种（甲基）丙烯酸酯，每个分子至少含有一个多元醇分子和一个氨基磺 酸酯键、所述至少一个多元醇分子选自由聚酯、聚碳酸酯、聚氨酯和聚醚组成的组，每种多元醇分子的结构均源自具有支链结构的 C4 至 C18 脂肪族链二醇单元 (a)。
• RESIN COMPOSITION FOR OPTICAL MOLDING
  申请人：Kuraray Noritake Dental Inc.

  公开号：EP3900693A1

  公开（公告）日：2021-10-27

  The present invention provides a resin composition for optical shaping that emits a weaker odor, enables easy fabrication of an object by virtue of its low viscosity, and can be made into a fabricated product having desirable toughness and water resistance when used for stereolithographic fabrication (particularly by vat stereolithography) and that is particularly suited for dental occlusal splints, mouth guards, and denture base materials. The present invention relates to a resin composition for optical shaping comprising: an α,β-unsaturated double bond group-containing compound (A) having a ring structure (a) containing a nitrogen atom; a (meth)acrylic acid ester compound (B) having a boiling point of 280°C or more at normal pressure, having a carbocyclic group, and having no nitrogen-containing heterocyclic group; a photopolymerization initiator (C); and optionally, a polyfunctional polymerizable monomer (E) having a molecular weight of 500 or less and not comprised in the α,β-unsaturated double bond group-containing compound (A) and the (meth)acrylic acid ester compound (B), wherein the content of the polyfunctional polymerizable monomer (E) having a molecular weight of 500 or less is 20 mass% or less relative to the total amount of polymerizable compounds comprised in the resin composition for optical shaping.

  本发明提供了一种用于光学整形的树脂组合物，该组合物散发的气味较弱，因其粘度低而易于制造物体，在用于立体光刻制造（特别是大桶立体光刻）时，可制成具有理想韧性和耐水性的制成品，特别适用于牙科咬合夹板、护齿板和义齿基底材料。本发明涉及一种用于光学塑形的树脂组合物，包括具有含氮原子的环结构 (a) 的含 α、β-不饱和双键基团的化合物 (A)；(甲基) 丙烯酸酯化合物 (B)，在常压下的沸点为 280°C 或更高，具有碳环基团，且不含含氮杂环基团；光聚合引发剂 (C)；以及可选的分子量为 500 或以下且不包含在含α，β-不饱和双键基团的化合物（A）和（甲基）丙烯酸酯化合物（B）中的多功能可聚合单体（E），其中分子量为 500 或以下的多功能可聚合单体（E）的含量占光学成型用树脂组合物中可聚合化合物总量的 20% 或以下。