((1Z)-1-methyl-2-(1-pyrrolin-2-yl)vinyl)methylamine | 849243-17-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: ((1Z)-1-methyl-2-(1-pyrrolin-2-yl)vinyl)methylamine
• 英文别名: (Z)-1-(3,4-dihydro-2H-pyrrol-5-yl)-N-methylprop-1-en-2-amine
• CAS: 849243-17-0
• 化学式: C₈H₁₄N₂
• 分子量: 138.213
• InChiKey: MXNKKQHHJKKSLG-SREVYHEPSA-N

物化性质

• 沸点：
  210.5±32.0 °C(Predicted)
• 密度：
  0.98±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  copeer(II) ethanoate 、 ((1Z)-1-methyl-2-(1-pyrrolin-2-yl)vinyl)methylamine 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Remarkably Volatile Copper(II) Complexes of N,N‘-Unsymmetrically Substituted 1,3-Diketimines as Precursors for Cu Metal Deposition via CVD or ALD

  摘要：

  To enhance the volatility of the copper precursor in the copper deposition process, it was envisioned that N,N'-unsymmetrically substituted 1,3-diketimines should be more volatile than their symmetrically substituted counterparts. A variety of Cu(II) (N,N'-unsymmetrically substituted 1,3-diketiminate) complexes have been synthesized and have proven to be much more volatile than their symmetrical counterparts. This makes the new materials particularly attractive to the ALD and CVD processes. Among the new compounds, 8-a and 8-b are sublimable even at room temperature.

  DOI：

  10.1021/ja051158s
• 作为产物：
  描述：

  2-甲基吡咯啉 在 正丁基锂 、 二异丙胺 、 硫酸二甲酯 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 4.5h， 生成 ((1Z)-1-methyl-2-(1-pyrrolin-2-yl)vinyl)methylamine
  参考文献：
  名称：

  Routes to N,N‘-Unsymmetrically Substituted 1,3-Diketimines

  摘要：

  [GRAPHICS]A series of novel N,N'-unsymmetrically substituted 1,3-diketimines (3, 12, and 27) have been synthesized from the reaction of exocyclic enaminoketones 8 with amines or metalloenamines (from 13 or 14) with imidoyl thioether 25 or 26.

  DOI：

  10.1021/jo047798f

文献信息

• Nonfluorinated Volatile Copper(I) 1,3-Diketiminates as Precursors for Cu Metal Deposition via Atomic Layer Deposition
  作者：Kyung-Ho Park、Alexander Z. Bradley、Jeffery S. Thompson、Will J. Marshall

  DOI：10.1021/ic061016e

  日期：2006.10.1

  Novel nonfluorinated Cu(diketiminate) L complexes with L = neutral olefinic ligand have been prepared as stable, volatile Cu( I) precursors for the deposition of copper films by an atomic layer deposition (ALD) process. Among them, the complexes of 4-a and 5-a are the most volatile and stable at low temperature (55 degrees C). A clean, conformal copper film was deposited at 120 degrees C in an ALD process. These Cu(I) complexes are the first examples of nonfluorinated copper(I) diketiminates that can be readily applied to an industrial microelectronic fabrication process.
• Routes to <i>N</i>,<i>N</i>‘-Unsymmetrically Substituted 1,3-Diketimines
  作者：Kyung-Ho Park、Will J. Marshall

  DOI：10.1021/jo047798f

  日期：2005.3.1

  [GRAPHICS]A series of novel N,N'-unsymmetrically substituted 1,3-diketimines (3, 12, and 27) have been synthesized from the reaction of exocyclic enaminoketones 8 with amines or metalloenamines (from 13 or 14) with imidoyl thioether 25 or 26.
• Remarkably Volatile Copper(II) Complexes of <i>N,N</i><i>‘</i>-Unsymmetrically Substituted 1,3-Diketimines as Precursors for Cu Metal Deposition via CVD or ALD
  作者：Kyung-Ho Park、Will J. Marshall

  DOI：10.1021/ja051158s

  日期：2005.7.1

  To enhance the volatility of the copper precursor in the copper deposition process, it was envisioned that N,N'-unsymmetrically substituted 1,3-diketimines should be more volatile than their symmetrically substituted counterparts. A variety of Cu(II) (N,N'-unsymmetrically substituted 1,3-diketiminate) complexes have been synthesized and have proven to be much more volatile than their symmetrical counterparts. This makes the new materials particularly attractive to the ALD and CVD processes. Among the new compounds, 8-a and 8-b are sublimable even at room temperature.