methyl N-methyl-N-phenyldithiocarbamate | 62603-94-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl N-methyl-N-phenyldithiocarbamate
• 英文别名: methyl-phenyl-dithiocarbamic acid methyl ester；Methyl-phenyl-dithiocarbamidsaeure-methylester；N-Methyl-dithiocarbanilsaeure-methylester；Methyl-phenyl-dithiourethylan；Carbamodithioic acid, methylphenyl-, methyl ester；methyl N-methyl-N-phenylcarbamodithioate
• CAS: 62603-94-5
• 化学式: C₉H₁₁NS₂
• 分子量: 197.325
• InChiKey: DAFDBQCIBPFTCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  60.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl N-methyl-N-phenyldithiocarbamate 在 碳酸氢钠 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.25h， 以47%的产率得到N-methyl-N-[methylsulfanyl(sulfinyl)methyl]aniline
  参考文献：
  名称：

  二硫代氨基甲酸酯的氧化和稳定亚砜的合成

  摘要：

  对各种二硫代氨基甲酸酯的氧化反应的研究表明，形成了相应的亚砜（S-氧化物）。尽管它们的稳定性非常适中，但仍可以分离和表征许多亚砜。当置于环境温度下时，它们分解为硫代氨基甲酸酯和二硫代氨基甲酸酯。来自仲二硫代氨基甲酸酯的亚砜导致形成二硫化物，对此进行了解释。通过在硫原子上存在空间位阻的芳基，制备了稳定的硫，并对其晶体结构进行了分析。

  DOI：

  10.1016/s0040-4039(98)02033-4
• 作为产物：
  描述：

  N-甲基-N,N'-二苯基巯基甲脒 生成 methyl N-methyl-N-phenyldithiocarbamate
  参考文献：
  名称：

  Bertram, Chemische Berichte, 1892, vol. 25, p. 57

  摘要：

  DOI：

文献信息

• A Facile Synthesis of Trifluoromethylamines by Oxidative Desulfurization–Fluorination of Dithiocarbamates
  作者：Kiyoshi Kanie、Katsuya Mizuno、Manabu Kuroboshi、Tamejiro Hiyama

  DOI：10.1246/bcsj.71.1973

  日期：1998.8

  conditions. When this reaction was applied to dithiocarbamates ArN(R)CS2Me at higher temperatures, the trifluoromethylation was accompanied by halogen substitution at the p-position of the Ar group. The synthesis of trifluoromethyl-substituted adenosine is also described.

  三氟甲胺很容易从二硫代氨基甲酸酯通过由四丁基二氢三氟化铵和 N-卤代酰亚胺组成的试剂系统在温和条件下合成。当该反应在较高温度下应用于二硫代氨基甲酸酯 ArN(R)CS2Me 时，三氟甲基化伴随着 Ar 基团对位的卤素取代。还描述了三氟甲基取代的腺苷的合成。
• Cycloaddition in synthesis of sulfonamide derivatives. III. Convenient synthesis of 3-alkylthio-4H-1,2,4-benzothiadiazine 1,1-dioxides.
  作者：Tsuneo IWAKAWA、Hiroto TAMURA、Yoshio HAYASE

  DOI：10.1248/cpb.38.1075

  日期：——

  Synthesis of 3-alkylthio-4-methyl-4H-1, 2, 4-benzothiadiazine 1, 1-dioxides was conveniently achieved by [2+2] cycloaddition reaction of S-alkyl N-methyl-N-phenyldithiocarbamates with chlorosulfonyl isocyanate with subsequent loss of carbonyl sulfide, followed by cyclization of the resulting chlorosulfonyl isothioureas under Friedel-Crafts conditions.

  3-烷基硫代-4-甲基-4H-1, 2, 4-苯并噻二唑-1, 1-二氧化物的合成可通过S-烷基N-甲基-N-苯基二硫氨基甲酸酯与氯磺酰异氰酸酯的[2+2]环加成反应方便地实现，随后失去硫代羰基，接着在Friedel-Crafts条件下对得到的氯磺酰异硫脲进行环化反应。
• 1-(Methyldithiocarbonyl)imidazole: a Useful Thiocarbonyl Transfer Reagent for Synthesis of Substituted Thioureas
  作者：Pramod K. Mohanta、Sanchita Dhar、S.K. Samal、H. Ila、H. Junjappa

  DOI：10.1016/s0040-4020(99)01026-1

  日期：2000.1

  1-(Methyldithiocarbonyl)imidazole 1 and its N-methyl quaternary salt 2 have been shown to be efficient methyldithiocarbonyl and thiocarbonyl transfer reagents for the synthesis of dithiocarbamates, symmetrical and unsymmetrical mono-, di- and tri-substituted thioureas in high yields under mild and simple non-hazardous reaction conditions.

  1-（甲基二硫代羰基）咪唑1及其N-甲基季盐2已被证明是有效的甲基二硫代羰基和硫代羰基转移试剂，可在温和，温和的条件下以高收率合成二硫代氨基甲酸酯，对称和不对称的单，二和三取代的硫脲。和简单的非危险反应条件。
• PATTERN FORMING METHOD, UNDER COATING AGENT, AND LAMINATE
  申请人：Oji Holdings Corporation

  公开号：US20200048491A1

  公开（公告）日：2020-02-13

  It is an object of the present invention to provide a pattern forming method capable of easily forming a phase-separated structure with high accuracy, even in the case of widening the applicable range of a pattern size. The present invention relates to a pattern forming method comprising: applying an under coating agent onto a substrate, and applying a self-assembly composition for pattern formation to the surface of the substrate, onto which the under coating agent has been applied, and then forming a self-assembly film according to self-assembly phase separation, wherein the self-assembly composition for pattern formation comprises a block copolymer comprising a polymerization unit (a) having at least one selected from a structure represented by a formula ( 103 ) and a structure represented by a formula ( 104 ), and a polymerization unit (b) having a structure represented by a formula ( 105 ).

  本发明的目的是提供一种能够在扩大图案尺寸适用范围的情况下，轻松形成具有高精度的相分离结构的图案形成方法。本发明涉及一种图案形成方法，包括：在基板上涂覆底涂剂，并将用于图案形成的自组装组合物应用到已涂覆底涂剂的基板表面上，然后根据自组装相分离形成自组装膜，其中用于图案形成的自组装组合物包括一种嵌段共聚物，该嵌段共聚物包括至少具有下列结构之一的聚合单元（a）和具有下列结构的聚合单元（b）。
• Coloring composition, and cured film, color filter, pattern forming method, method for manufacturing color filter, solid-state imaging device, image display device, and dye multimer, each using the coloring composition
  申请人：FUJIFILM Corporation

  公开号：US10175574B2

  公开（公告）日：2019-01-08

  A coloring composition having good light fastness and exposure sensitivity in the case of preparing a cured film; and a cured film, a color filter, a pattern forming method, a method for manufacturing a color filter, a solid-state imaging device, an image display device, and a dye multimer, each using the coloring composition, are provided. The coloring composition contains a dye multimer having a colorant structure and at least one structure selected from structures of Formulas (1) to (5) in the same molecule (Formula (1) is shown below), and a curable compound:

  本发明提供了一种在制备固化胶片时具有良好耐光性和曝光敏感性的着色组合物；以及使用该着色组合物的固化胶片、彩色滤光片、图案形成方法、彩色滤光片制造方法、固态成像设备、图像显示设备和染料多聚体。着色组合物含有染料多聚体，该染料多聚体在同一分子中具有着色剂结构和至少一种选自式（1）至（5）的结构（式（1）如下所示），还含有可固化化合物：