phenyl (E)-3-cyclohexyl-2-methylprop-2-enoate | 1279110-69-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: phenyl (E)-3-cyclohexyl-2-methylprop-2-enoate
• CAS: 1279110-69-8
• 化学式: C₁₆H₂₀O₂
• 分子量: 244.334
• InChiKey: ZWOGWAVQWKXWPK-OUKQBFOZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯酚 在 palladium diacetate 、 乙酸酐 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 作用下， 以 均三甲苯 为溶剂， 反应 25.42h， 生成 phenyl (E)-2-cyclohexylbut-2-enoate 、 phenyl (E)-3-cyclohexyl-2-methylprop-2-enoate
  参考文献：
  名称：

  在不使用外部一氧化碳的情况下，采用芳烃型的炔烃的钯催化加氢酯化反应

  摘要：

  已经开发了在不使用外部一氧化碳的情况下并且在环境压力下使用芳基甲酸酯的炔烃的高效加氢酯化。在钯-黄磷催化剂体系存在下的反应以良好至高收率选择性地提供α，β-不饱和酯。甲酸芳基酯的使用至关重要，烷基甲酸酯根本不反应。降冰片烯和末端烯烃的加氢酯化也容易在相似的反应条件下进行。机理研究表明，加氢酯化过程中发生了芳基甲酸酯向一氧化碳和苯酚衍生物的转化。Xantphos作为芳基甲酸酯的转化和加氢酯化反应的配体都是非常有效的。

  DOI：

  10.1002/adsc.201000750

文献信息

• Acrylic resin composition
  申请人：Kawamura Akira

  公开号：US20050065252A1

  公开（公告）日：2005-03-24

  An acrylic resin composition comprising the following acrylic resins (1) and (2): acrylic resin (1): an acrylic resin containing a structural unit derived from a monomer (a) (structural unit (a)), a structural unit derived from a monomer (b) (structural unit (b)) and a structural unit derived from a monomer (c) (structural unit (c)) and containing the structural unit (c) in an amount of 0.05 to 5 parts by weight based on 100 parts by weight of the acrylic resin (1); acrylic resin (2): a straight chain acrylic resin containing the structural unit (a) as the main component; (a): a (meth)acrylate of the formula (A) (wherein, R 1 represents a hydrogen atom or methyl group, R 2 represents an alkyl group having 1 to 14 carbon atoms or an aralkyl group having 1 to 14 carbon atoms, and a hydrogen atom in the alkyl group R 2 or a hydrogen atom in the aralkyl group R 2 may be substituted with an alkoxy group having 1 to 10 carbon atoms.), (b): a monomer containing an olefinic double bond in the molecule and at least one 5- or more-membered heterocyclic group in the molecule, (c): a monomer containing at least two olefinic double bonds in the molecule.

  一种丙烯酸树脂组合物，由以下丙烯酸树脂(1)和(2)组成： 丙烯酸树脂(1)：一种丙烯酸树脂，含有源自单体(a)的结构单元(结构单元(a))、源自单体(b)的结构单元(结构单元(b))和源自单体(c)的结构单元(结构单元(c))，且结构单元(c)的含量为 0.丙烯酸树脂 (2)：含有结构单元 (a) 作为主要成分的直链丙烯酸树脂； (a)：式(A)的(甲基)丙烯酸酯 (其中，R 1 代表氢原子或甲基，R 2 代表具有 1 至 14 个碳原子的烷基或具有 1 至 14 个碳原子的芳烷基，烷基中的氢原子 R 2 中的一个氢原子或烷基基团 R 2 可被具有 1 至 10 个碳原子的烷氧基取代）、 (b) 分子中含有一个烯烃双键和至少一个五元或多元杂环基团的单体； (c) 分子中含有至少两个烯烃双键的单体。
• Adhesive
  申请人：Takeko Ryu

  公开号：US20060036040A1

  公开（公告）日：2006-02-16

  An adhesive obtained by compounding a cross-linking agent to an acrylic resin composition comprising a silane-based compound and the following acrylic resins (1) and (2), wherein the content of acrylic resin (1) is 10 to 50 parts by weight based on 100 parts by weight of the total amount of the acrylic resin (1) and acrylic resin (2); acrylic resin (1): an acrylic resin having a molecular weight of 50,000 to 500,000 and containing a structural unit derived from a monomer (a) (structural unit (a)); acrylic resin (2): an acrylic resin having a molecular weight of 1,000,000 to 1,500,000 and a molecular weight distribution (Mw/Mn) of 5 or less, and containing the structural unit (a) as the main component and a structural unit derived from a monomer (b) (structural unit (b)); (a): a (meth)acrylate of the formula (A) (b): a monomer containing one olefinic double bond and at least one polar functional group selected from the group consisting of a carboxyl group, hydroxyl group, amide group, amino group, epoxy group, oxetanyl group, aldehyde group and isocyanate group in the molecule.

  一种通过将交联剂与丙烯酸树脂组合物复合而获得的粘合剂，该丙烯酸树脂组合物包括硅烷基化合物和以下丙烯酸树脂(1)和(2)，其中丙烯酸树脂(1)的含量以丙烯酸树脂(1)和丙烯酸树脂(2)总量的 100 重量份计为 10 至 50 重量份；丙烯酸树脂(1)：丙烯酸树脂 (2)：分子量为 1,000,000 至 1,500,000 且分子量分布 (Mw/Mn) 为 5 或以下的丙烯酸树脂，包含作为主要成分的结构单元 (a) 和衍生自单体 (b) 的结构单元 (结构单元 (b))； (a) 式（A）的（甲基）丙烯酸酯 (b): 分子中含有一个烯烃双键和至少一个极性官能团的单体，该极性官能团选 自羧基、羟基、酰胺基、氨基、环氧基、氧杂环丁烷基、醛基和异氰酸酯基。
• Acrylic resin
  申请人：Kawamura Akira

  公开号：US20050215743A1

  公开（公告）日：2005-09-29

  An acrylic resin (1) containing a structural unit derived from the following monomer (a) (structural unit (a)), a structural unit derived from the following monomer (b) (structural unit (b)), and a structural unit derived from the following monomer (c) (structural unit (c)): (a): a (meth)acrylate of the formula (A), (b): a monomer containing one olefinic double bond and at least one monomer containing an alicyclic structure in the molecule (the olefinic double bond contained in (b) may be contained in the alicyclic structure), and (c): a monomer containing at least two olefinic double bonds in the molecule.
• Optical laminate
  申请人：Takeko Ryu

  公开号：US20060062938A1

  公开（公告）日：2006-03-23

  An optical laminate comprising an anti-reflection film 1 , polarizing film 2 , adhesive layer 3 , glass cell for liquid crystal display 4 , adhesive layer 5 and polarizing film 6 laminated sequentially, wherein the ratio (A/B) of the maximum value A of the loss tangent of the adhesive layer 3 to the maximum value B of the loss tangent of the adhesive layer 5 is 1.1 or more. The maximum value of the loss tangent means the maximum value of loss modulus (E″)/storage modulus (E′) (=tan δ), each measured by heating the adhesive layer in a temperature range of −70° C. to 200° C. at a temperature rising rate of 4° C./min and a frequency of 1 Hz.
• ACRYLIC RESIN COMPOSITION
  申请人：KAWAMURA Akira

  公开号：US20080131640A1

  公开（公告）日：2008-06-05

  An acrylic resin composition comprising the following acrylic resins (1) and (2): acrylic resin (1): an acrylic resin containing a structural unit derived from a monomer (a) (structural unit (a)) and a structural unit derived from a monomer (b) (structural unit (b)); acrylic resin (2): an acrylic resin having a molecular weight of 1,100,000 to 1,500,000, and containing the structural unit (a) as the main component and a structural unit derived from a monomer (c) (structural unit (c)) and substantially not containing the structural unit (b); (a): a (meth)acrylate of the formula (A) (wherein, R 1 represents a hydrogen atom or methyl group, R 2 represents an alkyl group having 1 to 14 carbon atoms or an aralkyl group having 1 to 14 carbon atoms, and a hydrogen atom in the alkyl group R 2 or a hydrogen atom in the aralkyl group R 2 may be substituted with an alkoxy group having 1 to 10 carbon atoms), (b): a monomer containing an olefinic double bond in the molecule and at least one 5- or more-membered heterocyclic group in the molecule, (c): a monomer not containing 5- or more-membered heterocyclic group and containing one olefinic double bond and at least one polar functional group selected from the group consisting of a carboxyl group, hydroxyl group, amide group, amino group, epoxy group, oxetanyl group, aldehyde group and isocyanate group in the molecule.