1-Methyl-cyclopent-2-enyl-hydroperoxide | 70447-78-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氢过氧化物
• 英文名称: 1-Methyl-cyclopent-2-enyl-hydroperoxide
• 英文别名: 3-Hydroperoxy-3-methylcyclopentene
• CAS: 70447-78-8
• 化学式: C₆H₁₀O₂
• 分子量: 114.144
• InChiKey: CXHJANDXJICKBM-UHFFFAOYSA-N

物化性质

• 沸点：
  178.8±20.0 °C(Predicted)
• 密度：
  1.06±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cis-1,2,3,6-tetrahydrophthalic anhydride 、 1-Methyl-cyclopent-2-enyl-hydroperoxide 以50%的产率得到
  参考文献：
  名称：

  AXMEDOVA, R. EH., AZERB. XIM. ZH.,(1987) N 4, 124-126

  摘要：

  DOI：
• 作为产物：
  描述：

  1-甲基环戊烯 生成 1-Methyl-cyclopent-2-enyl-hydroperoxide
  参考文献：
  名称：

  LOPEZ SASTRE J. A., AFINIDAD, 1981, 38, NO 372, 153-155

  摘要：

  DOI：

文献信息

• Controlling Photoreactions with Restricted Spaces and Weak Intermolecular Forces:  Exquisite Selectivity during Oxidation of Olefins by Singlet Oxygen
  作者：Arunkumar Natarajan、Lakshmi S. Kaanumalle、Steffen Jockusch、Corinne L. D. Gibb、Bruce C. Gibb、Nicholas J. Turro、V. Ramamurthy

  DOI：10.1021/ja070086x

  日期：2007.4.1

  Highly regioselective photooxidation of methyl cycloalkenes has been performed in an aqueous medium by selectively blocking two of the three allylic hydrogens through supramolecular steric effect. Hydrophobic, steric, and weak intermolecular C−H−π interactions are suggested to be responsible for the specific orientation of the olefin within a water-soluble, deep-cavity cavitand with eight carboxylic

  通过超分子空间效应选择性阻断三个烯丙基氢中的两个，甲基环烯烃的高度区域选择性光氧化在水性介质中进行。疏水性、空间性和弱分子间 C-H-π 相互作用被认为是烯烃在具有八个羧酸基团的水溶性深腔空腔中的特定取向的原因。
• Kinetics of the Oxygenation of Unsaturated Organics with Singlet Oxygen Generated from H₂O₂ by a Heterogeneous Molybdenum Catalyst
  作者：Bert F. Sels、Dirk E. De Vos、Pierre A. Jacobs

  DOI：10.1021/ja065849f

  日期：2007.5.1

  A heterogeneous catalyst containing MoO42- exchanged on layered double hydroxides (Mo-LDHs) is used to produce O-1(2) from H2O2, and with this dark O-1(2), unsaturated hydrocarbons are oxidized in allylic peroxides. The oxidation kinetics are studied in detail and are compared with the kinetics of oxidation by O-1(2), formed from H2O2 by a homogeneous catalyst. A model is proposed for the heterogeneously catalyzed O-1(2) generation and peroxide formation. The model divides the reaction suspension in two compartments: (1) the intralamellar and intragranular zones of the LDH catalyst; (2) the bulk solution. The 2-compartment model correctly predicts the oxidant efficiency and peroxide yield for a series of olefin peroxidation reactions. O-1(2) is generated at a high rate by the heterogeneous catalyst, but somewhat more O-1(2) is lost by quenching with the heterogeneous catalyst than using the homogeneous catalyst. Quenching occurs mainly as a result of collision with the LDH hydroxyl surface, as is evidenced by using LDH supports containing strong O-1(2) deactivators such as Ni2+. A total of 15 organic substrates were peroxidized on a preparative scale using the best Mo-LDH catalyst under optimal conditions.
• Blau, K.; Mueller, U.; Pritzkow, W., Journal fur praktische Chemie (Leipzig 1954), 1980, vol. 322, # 6, p. 915 - 932
  作者：Blau, K.、Mueller, U.、Pritzkow, W.、Schmidt-Renner, W.、Sedshaw, Z.

  DOI：——

  日期：——
• MUSAEV M. R.; GAJDAROVA EH. EH.; AXMEDOVA R. EH., DOKL. AN AZSSR, 1980, 36, HO 7, 51-53
  作者：MUSAEV M. R.、 GAJDAROVA EH. EH.、 AXMEDOVA R. EH.

  DOI：——

  日期：——
• AXMEDOVA, R. EH., AZERB. XIM. ZH.,(1987) N 4, 124-126
  作者：AXMEDOVA, R. EH.

  DOI：——

  日期：——