N,N'-bis(3-methyldiethoxysilylpropyl)-[4,4'-oxybis(benzyl amide)] | 464916-50-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(3-methyldiethoxysilylpropyl)-[4,4'-oxybis(benzyl amide)]
• 英文别名: N-[3-[diethoxy(methyl)silyl]propyl]-4-[4-[3-[diethoxy(methyl)silyl]propylcarbamoyl]phenoxy]benzamide
• CAS: 464916-50-5
• 化学式: C₃₀H₄₈N₂O₇Si₂
• 分子量: 604.891
• InChiKey: JBHUEISXHYOGOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.01
• 重原子数：
  41
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  104
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4,4’-二酰氯二苯醚 在 bi(cyclopentadienyl)platinum dichloride 、 三乙胺 作用下， 以 四氢呋喃 、 N-甲基吡咯烷酮 为溶剂， 反应 14.0h， 生成 N,N'-bis(3-methyldiethoxysilylpropyl)-[4,4'-oxybis(benzyl amide)]
  参考文献：
  名称：

  A Novel Aryl Amide-Bridged Ladderlike Polymethylsiloxane Synthesized by an Amido H-Bonding Self-Assembled Template

  摘要：

  A novel soluble aryl amide-bridged ladderlike polymethylsiloxane (A-LPMS) was synthesized by stepwise coupling polymerization on the basis of amido H-bonding self-assembling template from monomer NAr-bis(3-methyldiethoxylsilylpropyl)-[4,4'-oxybis(benzyl amide)]. The monomer was prepared in a high yield by the hydrosilylation reaction of template agent N,N'-diallyl-[4,4'-oxybis(benzyl amide)] with methyldiethoxysilane in the presence of dicyclopentadienylplatinum dichloride (Cp2PtCl2) as catalyst. A variety of techniques including H-1 NMR, C-13 NMR, Si-29 NMR, FTIR, XRD, DSC, and, especially, static and dynamic light scattering and viscosimetry were combined to confirm the presence of the ordered ladderlike structure of polymer A-LPMS.

  DOI：

  10.1021/ja025650c

文献信息

• A Novel Aryl Amide-Bridged Ladderlike Polymethylsiloxane Synthesized by an Amido H-Bonding Self-Assembled Template
  作者：Huadong Tang、Jin Sun、Jinqiang Jiang、Xiaoshu Zhou、Tengjiao Hu、Ping Xie、Rongben Zhang

  DOI：10.1021/ja025650c

  日期：2002.9.1

  A novel soluble aryl amide-bridged ladderlike polymethylsiloxane (A-LPMS) was synthesized by stepwise coupling polymerization on the basis of amido H-bonding self-assembling template from monomer NAr-bis(3-methyldiethoxylsilylpropyl)-[4,4'-oxybis(benzyl amide)]. The monomer was prepared in a high yield by the hydrosilylation reaction of template agent N,N'-diallyl-[4,4'-oxybis(benzyl amide)] with methyldiethoxysilane in the presence of dicyclopentadienylplatinum dichloride (Cp2PtCl2) as catalyst. A variety of techniques including H-1 NMR, C-13 NMR, Si-29 NMR, FTIR, XRD, DSC, and, especially, static and dynamic light scattering and viscosimetry were combined to confirm the presence of the ordered ladderlike structure of polymer A-LPMS.