4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2"]terpyridine | 1428944-86-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2"]terpyridine
• 英文别名: 2,6-Dipyridin-2-yl-4-[4-(4-pyridin-4-ylphenyl)phenyl]pyridine；2,6-dipyridin-2-yl-4-[4-(4-pyridin-4-ylphenyl)phenyl]pyridine
• CAS: 1428944-86-8
• 化学式: C₃₂H₂₂N₄
• 分子量: 462.553
• InChiKey: SCLXHMBMMNOTPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  36
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2"]terpyridine 以 甲醇 、 乙腈 为溶剂， 生成 C₆₆H₅₀FeN₈⁽⁴⁺⁾
  参考文献：
  名称：

  The exchangeable self-assembly behaviour of bis-pseudorotaxanes with metallo-bisviologens (CH₃PyTpyFeTpyPyCH₃⁴⁺) and crown ether (Tpy = 2,2′:6′,2′′-terpyridine)

  摘要：

  两种不同的以三联吡啶配位的Fe2+配合物，其中含有两个甲基吡啶盐，可以与二苯并24-冠-8醚自组装，生成可交换的双金属伪轮烷。

  DOI：

  10.1039/c4ra12749h
• 作为产物：
  描述：

  4'-(4'-bromo(1,1'-biphenyl)-4-yl)[2,2':6',2'']terpyridine 、 吡啶-4-硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 反应 24.0h， 以91%的产率得到4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2"]terpyridine
  参考文献：
  名称：

  Synthesis, structure, and luminescence properties of arylpyridine-substituted terpyridine Zn(II) and Cd(II) complexes

  摘要：

  Two terpyridine derivatives, 4'-(4-(pyridin-4-yl)phenyl)-[2,2':6',2 '']terpyridine (L1) and 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2 '']terpyridine (L2) have been synthesized by palladium-catalyzed cross-coupling reactions, and their metal complexes [Zn(L1)(2)](ClO4)(2)center dot 2MeOH center dot CHCl3 (1) and [Cd(L2)(2)] (ClO4)(2)center dot DMF.2.8H(2)O (2) characterized by single crystal X-ray crystallography and spectroscopic methods including electronic absorption and emission measurements. In the crystalline materials, both metal ions have the expected pseudo-octahedral N-6 coordination environment and the lattice structures appear to be influenced by aromatic aromatic interactions involving the heteroaryl tails and the pyridyl rings of the terpyridine units. In solution and in the solid state, the complexes display blue emission attributed to an intramolecular charge transfer transition. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.054

文献信息

• Synthesis, structure, and luminescence properties of arylpyridine-substituted terpyridine Zn(II) and Cd(II) complexes
  作者：Emi Kubota、Young Hoon Lee、Akira Fuyuhiro、Satoshi Kawata、Jack M. Harrowfield、Yang Kim、Shinya Hayami

  DOI：10.1016/j.poly.2012.08.054

  日期：2013.3

  Two terpyridine derivatives, 4'-(4-(pyridin-4-yl)phenyl)-[2,2':6',2 '']terpyridine (L1) and 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2 '']terpyridine (L2) have been synthesized by palladium-catalyzed cross-coupling reactions, and their metal complexes [Zn(L1)(2)](ClO4)(2)center dot 2MeOH center dot CHCl3 (1) and [Cd(L2)(2)] (ClO4)(2)center dot DMF.2.8H(2)O (2) characterized by single crystal X-ray crystallography and spectroscopic methods including electronic absorption and emission measurements. In the crystalline materials, both metal ions have the expected pseudo-octahedral N-6 coordination environment and the lattice structures appear to be influenced by aromatic aromatic interactions involving the heteroaryl tails and the pyridyl rings of the terpyridine units. In solution and in the solid state, the complexes display blue emission attributed to an intramolecular charge transfer transition. (C) 2012 Elsevier Ltd. All rights reserved.
• The exchangeable self-assembly behaviour of bis-pseudorotaxanes with metallo-bisviologens (CH₃PyTpyFeTpyPyCH₃⁴⁺) and crown ether (Tpy = 2,2′:6′,2′′-terpyridine)
  作者：Tun Wu、Yuan Guo、Jie Yuan、Zhilong Jiang、Die Liu、Pingshan Wang

  DOI：10.1039/c4ra12749h

  日期：——

  Two different terpyridine chelated Fe²⁺ complexes which contain two methyl-pyridinium salts could be self-assembled with dibenzo-24-crown-8 ether to generate exchangeable double metallo-pseudorotaxanes.

  两种不同的以三联吡啶配位的Fe2+配合物，其中含有两个甲基吡啶盐，可以与二苯并24-冠-8醚自组装，生成可交换的双金属伪轮烷。