2-{(甲基硒基)[二(三甲基硅烷基)]甲基}吡啶 | 569322-21-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 2-{(甲基硒基)[二(三甲基硅烷基)]甲基}吡啶
• 英文名称: 2-{(Methylselanyl)[bis(trimethylsilyl)]methyl}pyridine
• 英文别名: trimethyl-(methylselanyl-pyridin-2-yl-trimethylsilylmethyl)silane
• CAS: 569322-21-0
• 化学式: C₁₃H₂₅NSeSi₂
• 分子量: 330.479
• InChiKey: HQQBQHSDQLSHEI-UHFFFAOYSA-N

物化性质

• 沸点：
  330.1±42.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.78
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  五羰基溴化锰(I) 、 2-{(甲基硒基)[二(三甲基硅烷基)]甲基}吡啶 以 氯仿 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Synthesis and spectroscopic studies of organometallic Mn(I) complexes containing the novel mixed donor ligands 2-{MeSeCH(2−n)(SiMe3)n}C5H4N (n=0–2)

  摘要：

  Treatment of MnBr(CO)(5) with one equivalent of the bidentate ligand, 2-{RECH(2-n)(SiMe3)(n)}C5H4N (E = S, R = Me, Ph, n = 0; E = Se, R = Me, n = 0, 1, 2) affords the complexes [MnBr(CO)(3)L] as orange powders. The effect of stepwise substitution at the alpha-carbon of the ligand by a trimethylsilyl group was investigated using Se-77(H-1)- and Mn-55-NMR, and IR spectroscopies. In the case of the pyridyl-selenoether-containing complexes, each additional Me3Si - group increases the sigma-donating properties of the ligand, in turn reflected in increased Mn-->CO backbonding. The solid-state structure of the parent [MnBr(CO)(3){2-(PhSCH2)C5H4N}] showed the molecule to have distorted fac-octahedral geometry. All other compounds were assigned the same stereochemistry based on CdropO stretching frequency comparisons. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00206-7
• 作为产物：
  描述：

  2-(bis(trimethylsilyl)methyl)pyridine 、 碘甲烷 在 正丁基锂 、 selenium 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以22%的产率得到2-{(甲基硒基)[二(三甲基硅烷基)]甲基}吡啶
  参考文献：
  名称：

  Synthesis and spectroscopic studies of organometallic Mn(I) complexes containing the novel mixed donor ligands 2-{MeSeCH(2−n)(SiMe3)n}C5H4N (n=0–2)

  摘要：

  Treatment of MnBr(CO)(5) with one equivalent of the bidentate ligand, 2-{RECH(2-n)(SiMe3)(n)}C5H4N (E = S, R = Me, Ph, n = 0; E = Se, R = Me, n = 0, 1, 2) affords the complexes [MnBr(CO)(3)L] as orange powders. The effect of stepwise substitution at the alpha-carbon of the ligand by a trimethylsilyl group was investigated using Se-77(H-1)- and Mn-55-NMR, and IR spectroscopies. In the case of the pyridyl-selenoether-containing complexes, each additional Me3Si - group increases the sigma-donating properties of the ligand, in turn reflected in increased Mn-->CO backbonding. The solid-state structure of the parent [MnBr(CO)(3){2-(PhSCH2)C5H4N}] showed the molecule to have distorted fac-octahedral geometry. All other compounds were assigned the same stereochemistry based on CdropO stretching frequency comparisons. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00206-7

文献信息

• Synthesis and spectroscopic studies of organometallic Mn(I) complexes containing the novel mixed donor ligands 2-{MeSeCH(2−n)(SiMe3)n}C5H4N (n=0–2)
  作者：Brian W Skelton、Vicki-Anne Tolhurst、Allan H White、Alan M Williams、Adele J Wilson

  DOI：10.1016/s0022-328x(03)00206-7

  日期：2003.5

  Treatment of MnBr(CO)(5) with one equivalent of the bidentate ligand, 2-RECH(2-n)(SiMe3)(n)}C5H4N (E = S, R = Me, Ph, n = 0; E = Se, R = Me, n = 0, 1, 2) affords the complexes [MnBr(CO)(3)L] as orange powders. The effect of stepwise substitution at the alpha-carbon of the ligand by a trimethylsilyl group was investigated using Se-77(H-1)- and Mn-55-NMR, and IR spectroscopies. In the case of the pyridyl-selenoether-containing complexes, each additional Me3Si - group increases the sigma-donating properties of the ligand, in turn reflected in increased Mn-->CO backbonding. The solid-state structure of the parent [MnBr(CO)(3)2-(PhSCH2)C5H4N}] showed the molecule to have distorted fac-octahedral geometry. All other compounds were assigned the same stereochemistry based on CdropO stretching frequency comparisons. (C) 2003 Elsevier Science B.V. All rights reserved.