4-methoxy-6-methyl-1,3,5-triazin-2-yl-carbamic acid,phenyl ester | 87483-75-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-methoxy-6-methyl-1,3,5-triazin-2-yl-carbamic acid,phenyl ester
• 英文别名: O-phenyl (4-methyl-6-methoxy-1,3,5-triazin-2-yl)-carbamate；phenyl N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-carbamate；phenyl (4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamate；4-methoxy-6-methyl-1,3,5-triazin-2-yl-carbamic acid, phenyl ester；2-(N-phenyloxycarbonyl)amino-4-methoxy-6-methyl-1,3,5-triazine；O-phenyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamate；Carbamic acid, (4-methoxy-6-methyl-1,3,5-triazin-2-yl)-, phenyl ester；phenyl N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamate
• CAS: 87483-75-8
• 化学式: C₁₂H₁₂N₄O₃
• 分子量: 260.252
• InChiKey: KJYKABTWCXRMTA-UHFFFAOYSA-N

物化性质

• 密度：
  1.339±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  86.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-methoxy-6-methyl-1,3,5-triazin-2-yl-carbamic acid,phenyl ester 生成 1-[[6-(dimethylamino)-2-methyl-1,1-dioxo-2,3-dihydro-1-benzothiophen-7-yl]sulfonyl]-3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea
  参考文献：
  名称：

  DUMAS, DONALD J.;MOON, MARCUS P.

  摘要：

  DOI：
• 作为产物：
  描述：

  碳酸二苯酯 、 2-氨基-4-甲氧基-6-甲基-1,3,5-三嗪 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 4-methoxy-6-methyl-1,3,5-triazin-2-yl-carbamic acid,phenyl ester
  参考文献：
  名称：

  5-二烷基氨基取代的氯磺隆衍生物在碱性土壤中的降解

  摘要：

  磺酰脲类除草剂由于其超高效的活性而被广泛用作乙酰乳酸合酶（ALS）抑制剂。然而，一些磺酰脲类除草剂由于降解时间长，在轮作时表现出毒性，例如氯磺隆。我们的研究目标是获得降解时间可控、作物安全性好、除草活性高的氯磺隆除草剂。基于我们之前报道的酸性土壤结果，我们研究了 5-二烷基氨基取代的氯磺隆衍生物 (NL101–NL108) 在碱性土壤 (pH 8.39) 中的降解行为。实验数据表明，氯磺隆苯环上添加5-二烷基氨基大大加速了其在碱性土壤中的降解。这些氯磺隆衍生物的降解速度比氯磺隆快 10.8 至 51.8 倍，并且对小麦和玉米表现出优异的作物安全性（通过出苗前处理）。综合考虑结构、生物测定活性、土壤退化和作物安全性，可以得出结论，5-二烷基氨基取代的氯磺隆衍生物是一种潜在的绿色磺酰脲类除草剂，可用于小麦和玉米的芽前处理。该研究还为发现用于轮作的新型磺酰脲类除草剂提供了有价值的信息。

  DOI：

  10.3390/molecules27051486

文献信息

• Herbicidal sulfonamides
  申请人：E. I. DuPont De Nemours and Company

  公开号：US04746356A1

  公开（公告）日：1988-05-24

  This invention relates to novel sulfonylurea herbicidal compounds, agriculturally suitable compositions thereof and a method-of-use of said compounds and compositions as general preemergence and/or postemergence herbicides or their use as plant growth regulants.

  这项发明涉及新型磺酰脲除草剂化合物，其农业适用组合物以及所述化合物和组合物作为一般前期和/或后期除草剂或作为植物生长调节剂的使用方法。
• Herbicidal pyrrolesulfonylureas
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US05472933A1

  公开（公告）日：1995-12-05

  This invention relates to certain herbicidal pyrrolesulfonylureas, compositions thereof and a method for their use as herbicides or plant growth regulants.

  这项发明涉及某些除草剂吡咯磺酰脲类化合物，其组成以及作为除草剂或植物生长调节剂使用的方法。
• Herbicidal sulfonylureas
  申请人：Ciba-Geigy Corporation

  公开号：US04602936A1

  公开（公告）日：1986-07-29

  Substituted N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal bases or alkaline earth metal bases, or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formula the symbols have the following meanings: R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 alkylsulfinyl, --CO--R.sup.8, --NR.sup.9 R.sup.10, --CO--NR.sup.11 R.sup.12 or --SO.sub.2 --NR.sup.13 R.sup.14, R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl or C.sub.1 -C.sub.4 alkylsulfonyl, R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or cyano, R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sup.5 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sup.6 and R.sup.7 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.15 R.sup.16, R.sup.8 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio or C.sub.2 -C.sub.4 alkoxyalkoxy, R.sup.9, R.sup.10, R.sup.11, R.sup.12, R.sup.13, R.sup.14, R.sup.15 and R.sup.16 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl, A is a radical --Y--(CH.sub.2).sub.n --R.sup.17 or ##STR2## R.sup.17 is a 5- or 6-membered unsaturated heterocyclic radical, R.sup.18 and R.sup.19 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, nitro or cyano, E is nitrogen or --CH.dbd., Y is oxygen, sulfur or a direct bond, T and Z are each independently oxygen or sulfur, and n is 0 or 1.

  通用公式##STR1##中的N-苯基磺酰-N'-嘧啶基脲和N-苯基磺酰-N'-三嗪基脲及其与胺、碱金属碱或碱土金属碱，或与季铵基的盐具有良好的前期和后期选择性除草和生长调节性能。在上述公式中，符号的含义如下：R.sup.1是氢、卤素、硝基、氰基、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4卤代烷基、C.sub.1 -C.sub.4氧烷基、C.sub.1 -C.sub.4硫代烷基、C.sub.1 -C.sub.4磺酰基、C.sub.1 -C.sub.4亚砜基、--CO--R.sup.8、--NR.sup.9 R.sup.10、--CO--NR.sup.11 R.sup.12或--SO.sub.2--NR.sup.13 R.sup.14，R.sup.2是氢、卤素、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4氧烷基、C.sub.1 -C.sub.4硫代烷基、C.sub.1 -C.sub.4亚砜基，R.sup.3是氢、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4卤代烷基或氰基，R.sup.4是氢或C.sub.1 -C.sub.4烷基，R.sup.5是氢、C.sub.1 -C.sub.4烷基或C.sub.1 -C.sub.4氧烷基，R.sup.6和R.sup.7分别独立地是氢、卤素、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4氧烷基、C.sub.1 -C.sub.4卤代烷基、C.sub.1 -C.sub.4卤代氧烷基、C.sub.1 -C.sub.4硫代烷基、C.sub.1 -C.sub.4卤代硫代烷基、C.sub.2 -C.sub.4氧烷基、C.sub.3 -C.sub.6环烷基或--NR.sup.15 R.sup.16，R.sup.8是氢、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4卤代烷基、C.sub.1 -C.sub.4氧烷基、C.sub.1 -C.sub.4卤代氧烷基、C.sub.1 -C.sub.4硫代烷基或C.sub.2 -C.sub.4氧烷氧基，R.sup.9、R.sup.10、R.sup.11、R.sup.12、R.sup.13、R.sup.14、R.sup.15和R.sup.16分别独立地是氢或C.sub.1 -C.sub.4烷基，A是基团--Y--(CH.sub.2).sub.n --R.sup.17或##STR2##，R.sup.17是5-或6-成员不饱和杂环基，R.sup.18和R.sup.19分别独立地是氢、卤素、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4卤代烷基、C.sub.1 -C.sub.4氧烷基、C.sub.1 -C.sub.4卤代氧烷基、硝基或氰基，E是氮或--CH.dbd.，Y是氧、硫或直接键，T和Z分别独立地是氧或硫，n为0或1。
• SALTS OF 2-IODO-N-[(4-METHOXY-6-METHYL-1,3, 5-TRIAZINE-2-YL) CARBAMOYL] BENZENESULFONAMIDE, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF AS HERBICIDES AND PLANT GROWTH REGULATORS
  申请人：Waldraff Christian

  公开号：US20100285964A1

  公开（公告）日：2010-11-11

  The present invention relates to salts of 2-iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzenesulfonamide, to processes for their preparation and to their use as herbicides, in particular as herbicides for the selective control of unwanted harmful plants in crops of useful plants, permanent crops or on non-crop land, and also as plant growth regulators, on their own or with safeners and/or in combination with other herbicides, to their use for controlling unwanted harmful plants (such as, for example, broad-leaved/weed grasses) in specific crop plants or as crop protection regulators, for simultaneous and/or sequential application, either as a readymix or as a tank mix.

  本发明涉及2-碘-N-[(4-甲氧基-6-甲基-1,3,5-三嗪-2-基)氨基甲酰基]苯磺酰胺盐的制备方法及其作为除草剂的用途，特别是作为用于选择性控制作物中有害杂草的除草剂，永久作物或非作物土地上的除草剂，以及作为植物生长调节剂，单独使用或与安全剂和/或其他除草剂结合使用，用于控制特定作物中的有害杂草（例如，阔叶/杂草草）或作为作物保护调节剂，用于同时和/或顺序应用，无论是作为现成混合物还是作为混合罐。
• Herbicide utility on resistant crops
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US05084086A1

  公开（公告）日：1992-01-28

  This invention relates to sulfonylurea herbicides which control the growth of undesired vegetation and are safe to cotton or soybean plants that contain at least one gene that confers resistance to inhibitors of acetolactate synthase, agriculturally suitable compositions thereof and a method of their use.

  这项发明涉及控制不受欢迎植被生长的磺酰脲类除草剂，对含有至少一种使得棉花或大豆植物对乙醇乳酸合成酶抑制剂具有抗性的基因的植物安全，以及相应的农业适用组合物和使用方法。