(1S,2R,6S,7R)-4-anthracen-1-yl-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione | 1315337-48-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: (1S,2R,6S,7R)-4-anthracen-1-yl-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
• CAS: 1315337-48-4
• 化学式: C₂₃H₁₇NO₂
• 分子量: 339.393
• InChiKey: PBRJQQMWQIFKSB-ALFLXDJESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-氨基蒽 、 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 在 zinc(II) acetate dihydrate 、 溶剂黄146 作用下， 反应 2.0h， 以90%的产率得到(1S,2R,6S,7R)-4-anthracen-1-yl-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
  参考文献：
  名称：

  N-1- and N-2-Anthryl Succinimide Derivatives: C–N Bond Rotational Behaviors and Fluorescence Energy Transfer

  摘要：

  New rigid bicyclic N-anthrylsuccinimide 1a, 1b, 2a, and 2b were prepared. The C-aryl-N-imide bond rotational barriers, intra/intermolecular arene-arene interactions, and photophysical properties were investigated. The rotational behaviors are more significantly controlled by the position of C-aryl-N-imide connection than the sidewall framework. The fluorescence energy transfer (Phi(ET)) in 1a and 1b was estimated to be 61% and 53%, respectively. The difference is attributed to the position of C-aryl-N-imide connection, which directly influences the relative orientation of donor (naphthalene) and acceptor (anthracene).

  DOI：

  10.1021/jo200665v