2-丙烯酰氨基-2-苯基-乙磺酸 | 32885-13-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-丙烯酰氨基-2-苯基-乙磺酸
• 英文名称: 2-(Acryloylamino)-2-phenylethanesulfonic acid
• 英文别名: 2-phenyl-2-(prop-2-enoylamino)ethanesulfonic acid
• CAS: 32885-13-5
• 化学式: C₁₁H₁₃NO₄S
• 分子量: 255.295
• InChiKey: CGRRTNMGLUWMLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  91.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯乙烯 、 丙烯腈 在 硫酸 、 乙酸酐 作用下， 反应 4.0h， 以75.4%的产率得到2-丙烯酰氨基-2-苯基-乙磺酸
  参考文献：
  名称：

  Podgornova; Khalistova; Ustavshchikov, Russian Journal of Applied Chemistry, 1996, vol. 69, # 1, p. 110 - 113

  摘要：

  DOI：

文献信息

• Electrically conductive compositions and electrodes utilizing same
  申请人：MEDTRONIC, INC.

  公开号：EP0085327A1

  公开（公告）日：1983-08-10

  Electrically conductive compositions particularly useful for biomedical electrodes wherein the conductive composition comprises the physical and electrical interface between the electrode and the skin of a subject. The conductive composition is conformable, flexible, adhesive and forms a cohesive body (12) readily adaptable to use at the interface area of the electrode (10). The compositions comprise in interpenetrating polymer network consisting essentially of a hydrophyllic crosslinked polymer formed from a water soluble monomer and a hydrophyllic, polymer which is not crosslinked, a humectant, and water.

  特别适用于生物医学电极的导电组合物，其中导电组合物包括电极和受试者皮肤之间的物理和电气界面。 导电组合物具有保形性、柔韧性和粘合性，并形成一个易于在电极（10）界面区域使用的内聚体（12）。 组合物包括互穿聚合物网络，该网络主要由水溶性单体和未交联的水溶性聚合物形成的水合交联聚合物、保湿剂和水组成。
• PROCESS FOR PREPARING AMIDOALKANESULFONIC ACID DERIVATIVES
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0112921A1

  公开（公告）日：1984-07-11

  A novel process for preparing amidoalkanesulfonic acids represented by formula (3) and their derivatives by reacting a nitrile compound (1) with p-hydroxyalkanesulfonic acid or its derivative (2) in conc. sulfuric acid. Of the compounds of the formula (3) and their derivatives, unsaturated amidophenyl- substitued alkanesulfonic acids represented by formula (4) and their derivatives, particularly, 2-acrylamido-2-phenylpropanesulfonic acid and its derivatives are copolymerized with other monomers to provide useful materials such as copolymer-coated solid substances, copolymer emulsions, and pigment-dispersing agent.

  一种新工艺，通过腈化合物（1）与对羟基烷磺酸或其衍生物（2）在浓硫酸中反应，制备以式（3）为代表的氨基烷磺酸及其衍生物。在式 (3) 及其衍生物中，式 (4) 所代表的不饱和氨基苯基取代烷磺酸及其衍生物，特别是 2-丙烯酰胺基-2-苯基丙磺酸及其衍生物，可与其他单体共聚，以提供有用的材料，如共聚物涂层固体物质、共聚物乳液和颜料分散剂。
• High temperature profile modification agents and methods for using same
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0200062A2

  公开（公告）日：1986-11-05

  @ A new and improved composition and method for profile modification of subterranean formations characterized by high reservoir temperatures and/or harsh brine conditions are disclosed. The new and improved profile modification agents comprise a gelable composition comprising: (a) water; (b) a water-thickening and crosslinkable amount of a water-dispersible copolymer comprising from about 30 to about 99 mol % of units derived from at least one N-sulfohydrocarbon substituted acrylamide monomer copolymerized with from about 1 to about 70 mol % of units derived from at least one other monomer bearing a carboxyl group or a carboxyl precursor group; and (c) an amount of a polyvalent metal sufficient to crosslink the copolymer to form a stable gel. The profile modification agents are effective to alter the permeability of preselected portions of an underground formation by forming strong gels which are stable in harsh brine at temperatures of up to about 120°C. The composition and method are particularly adapted for use in enhanced oil recovery operations.

  本研究公开了一种新的、改进的组合物和方法，用于对以储层温度高和/或盐水条件恶劣为特征的地下地层进行剖面改良。新型改进型剖面改良剂包括一种可凝胶化的组合物，其中包括： (a) 水 (b) 一定量的可遇水增稠和交联的水分散性共聚物，该共聚物包含约 30 至约 99 摩尔 % 的单元，这些单元来自至少一种 N-磺羟烃取代的丙烯酰胺单体，与约 1 至约 70 摩尔 % 的单元共聚，这些单元来自至少一种带有羧基或羧基前体基团的其他单体；以及 (c) 一定量的多价金属，足以使共聚物交联形成稳定的凝胶。剖面改性剂通过形成在温度高达约 120°C 的苛刻盐水中稳定的强凝胶体，可有效改变地下地层预选部分的渗透性。这种组合物和方法尤其适用于提高石油采收率的作业。
• Process for the production of modacrylic copolymers and acrylic copolymers thus obtained
  申请人：Montefibre S.p.A.

  公开号：EP0694566A1

  公开（公告）日：1996-01-31

  Process for the production of modacrylic copolymers comprising acrylonitrile, a halogenated comonomer and a comonomer containing hydrophilic groups by the polymerization in continuous of monomers in an aqueous suspension and in the presence of a catalyst, wherein the polymerization is carried out in a tubular reactor equipped with an overflow and having a ratio length/diameter of more than 1.8; the catalyst, acrylonitrile and comonomer containing the hydrophilic groups are fed into the lower area of the reactor; the catalyst is of the type with a high decomposition rate such as to decompose for at least 70% by weight, under polymerization conditions, before reaching the feeding area of the halogenated comonomer.

  在催化剂存在下，通过水悬浮液中单体的连续聚合反应，生产包含丙烯腈、卤代共聚单体和含亲水基团的共聚单体的改性丙烯酸共聚物的工艺，其中聚合反应在装有溢流且长度/直径比大于 1.8 的管式反应器中进行；催化剂、丙烯腈和含亲水基团的共聚单体被送入反应器的下部区域；催化剂是具有高分解率的类型，例如可分解丙烯腈、卤代共聚单体和含亲水基团的共聚单体。8；催化剂、丙烯腈和含有亲水基团的共聚单体被加入反应器的下部区域；催化剂是具有高分解率的类型，例如在聚合条件下，在到达卤化共聚单体的加入区域之前，按重量计至少分解70%。
• CURABLE COMPOSITION, CURED PRODUCT OF FUNCTIONAL POLYMER, STACK OR DEVICE PROVIDED WITH FUNCTIONAL POLYMER FILM, AMIDE COMPOUND AND METHOD FOR PRODUCING SAME
  申请人：Fujifilm Corporation

  公开号：EP3187516A1

  公开（公告）日：2017-07-05

  A curable composition that comprises an amide compound, said amide compound being represented by general formula (1) and having a sulfonic acid density of 3.9 meq/g or greater, a cured product of a functional polymer, a stack or device provided with a functional polymer film, an amide compound, and a method for producing the same. wherein: m is an integer of 1 or greater; n is an integer of 2 or greater; L1 represents an (m+1)-valent linking group; L2 represents an n-valent linking group; R1 represents a hydrogen atom or an alkyl group; R2 represents -SO3-M+ or -SO3R3 (wherein: R3 represents an alkyl group or an aryl group), provided that when there are two or more R2's, all of R2's do not represent -SO3R3 at the same time; and M+ represents a hydrogen ion, an inorganic ion or an organic ion.

  一种可固化组合物，包括酰胺化合物（所述酰胺化合物由通式（1）表示，其磺酸密度为 3.9 meq/g 或更高）、功能性聚合物的固化产物、带有功能性聚合物薄膜的堆栈或装置、酰胺化合物，以及生产上述组合物的方法。 其中：m 是 1 或更大的整数；n 是 2 或更大的整数；L1 代表 (m+1)- 价连接基团；L2 代表 n 价连接基团；R1 代表氢原子或烷基；R2 代表 -SO3-M+ 或 -SO3R3 （其中：R3代表烷基或芳基），但当有两个或两个以上的 R2 时，所有的 R2 不能同时代表-SO3R3；M+代表氢离子、无机离子或有机离子。