2-丙烯酸,2-甲基-,2-丁基-2-乙基-1,3-丙二基酯 | 15422-98-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-丙烯酸,2-甲基-,2-丁基-2-乙基-1,3-丙二基酯
• 英文名称: 3,3-bis-methacryloyloxymethyl-heptane
• 英文别名: 2-Aethyl-2-butyl-1,3-bis-methacryloyloxy-propan；3,3-Bis-methacryloyloxymethyl-heptan；2-Butyl-2-ethyl-1,3-propanediol dimethacrylate；[2-ethyl-2-(2-methylprop-2-enoyloxymethyl)hexyl] 2-methylprop-2-enoate
• CAS: 15422-98-7
• 化学式: C₁₇H₂₈O₄
• 分子量: 296.407
• InChiKey: NEJNOEFCQDFDQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 、 2-丁基-2-乙基-1,3-丙二醇 在 硫酸 、 苯 作用下， 生成 2-丙烯酸,2-甲基-,2-丁基-2-乙基-1,3-丙二基酯
  参考文献：
  名称：

  Cross-linked Polymers. I. Factors Influencing the Efficiency of Cross-linking in Copolymers of Methyl Methacrylate and Glycol Dimethacrylates¹

  摘要：

  DOI：

  10.1021/ja01110a068

文献信息

• POLYMER HAVING BIS(DIPHENYLPHOSPHINO)BINAPHTHYL GROUPS
  申请人：Shimada Toyoshi

  公开号：US20100022800A1

  公开（公告）日：2010-01-28

  A polymer having bis(diphenylphosphino)binaphthyl groups that can be used as a catalyst for an addition reaction, especially an asymmetric 1,4-addition reaction, or a reduction reaction, especially an asymmetric reduction reaction, and that can be easily recovered and recycled. The polymer having the bis(diphenylphosphino)binaphthyl groups is one resulting from repetition of a racemic or optically active 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound substituted at 5-position thereof with an unsaturated terminal of one (meth)acryloyl group of a compound having multiple (meth)acryloyl groups, that another 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound of a next unit is substituted at 5′-position thereof with an unsaturated terminal of another (meth)acryloyl group of the compound having multiple (meth)acryloyl groups so as to have a molecular weight of 1500 to 10000. The reduction catalyst comprises this polymer and a transition metal.

  具有双(二苯基膦)联萘基团的聚合物可用作催化剂，特别是用于加成反应，尤其是不对称的1,4-加成反应，或还原反应，特别是不对称还原反应，并且可以轻松回收和循环利用。具有双(二苯基膦)联萘基团的聚合物是由重复使用在其5位取代有一种具有多个(甲基)丙烯酰基团的化合物的不对称或光学活性2,2′-双(二苯基膦)-1,1′-联萘化合物所得，下一个单元的另一种2,2′-双(二苯基膦)-1,1′-联萘化合物在其5′位取代有另一种具有多个(甲基)丙烯酰基团的化合物的不饱和末端，以使其分子量为1500至10000。还原催化剂包括该聚合物和过渡金属。
• GAS-BARRIER FILM, AND METHOD FOR SEALING DISPLAY DEVICE WITH GAS-BARRIER FILM
  申请人：TSUKAHARA Jiro

  公开号：US20090061223A1

  公开（公告）日：2009-03-05

  Disclosed is A gas barrier film comprising a substrate film and a barrier layer containing an organic region and an inorganic region on the substrate film, in which, when the organic region is provided on one surface of the gas barrier film, the outermost layer on the side with the organic region is an adhesive layer, or when the organic regions are provided on both surfaces of the gas barrier film, at least one outermost layer of the gas barrier film is an adhesive layer. The gas barrier film is capable of simplifying the working process with it and keeping its good gas-barrier property.

  本发明涉及一种气体阻隔薄膜，包括基材薄膜和位于基材薄膜上的含有有机区域和无机区域的阻隔层，其中，当有机区域位于气体阻隔薄膜的一侧时，有机区域所在侧的最外层为粘合层；或者当有机区域位于气体阻隔薄膜的两侧时，气体阻隔薄膜至少有一侧的最外层为粘合层。该气体阻隔薄膜能够简化使用过程并保持其良好的气体阻隔性能。
• Transparent resin and plastic lens
  申请人：HITACHI CHEMICAL CO., LTD.

  公开号：EP0661307A2

  公开（公告）日：1995-07-05

  A transparent resin obtained by polymerizing a monomer having an alkylene oxide group, a polyfunctional (meth)acrylate having a divalent branched hydrocarbon group and other copolymerizable vinyl monomer, if necessary, is suitable as an elementary material for a plastic lens with excellent heat resistance and hue.

  通过聚合具有环氧亚烷基的单体、具有二价支链烃基的多官能（甲基）丙烯酸酯和其他可共聚的乙烯基单体（如有必要）而得到的透明树脂，适合作为塑料镜片的基本材料，具有优异的耐热性和色调。
• DI(METH)ACRYLATES
  申请人：Kyowa Yuka Co., Ltd.

  公开号：EP0909752A1

  公开（公告）日：1999-04-21

  The present invention relates to di(meth)acrylate which is useful as a UV light or electron ray curing coating agent, etc., represented by the following general formula (I). (wherein, R1 and R2 are the same or different and represent a hydrogen atom or CH3, and R3 and R4 are the same or different and represent lower alkyl of 1∼6 carbon atoms). The di(meth)acrylate of the present invention is easily cured to provide a cured product having superior toughness and flexibility.

  本发明涉及可用作紫外线或电子射线固化涂层剂等的二(甲基)丙烯酸酯，其通式(I)如下。 (其中，R1 和 R2 相同或不同，代表氢原子或 CH3，R3 和 R4 相同或不同，代表 1∼6 个碳原子的低级烷基）。 本发明的二（甲基）丙烯酸酯易于固化，固化后的产品具有极佳的韧性和柔韧性。
• PHOTOCURING TRANSFER SHEET, METHOD FOR MANUFACTURING OPTICAL INFORMATION RECORDING MEDIUM USING THE SHEET, AND OPTICAL INFORMATION RECORDING MEDIUM
  申请人：Bridgestone Corporation

  公开号：EP1674505A1

  公开（公告）日：2006-06-28

  A photo-curable transfer sheet having a photo-curable transfer layer comprising a photo-curable composition, the photo-curable composition being deformable by application of pressure and containing a reactive polymer having a photopolymerizable functional group, wherein the photo-curable transfer layer shows linearity in relationship between strain [γ] (%) and time [t] (second) measured by a creep test using a dynamic viscoelasticity measuring apparatus under the conditions of an ordinary temperature, stress of 50Pa and a time period of 120 seconds, and satisfies a following formula: log γ = a + b·log t, in which "a" is a real number, and "b" is in the range of 0.10 to 0.53; and a process for the preparation of an optical information recording medium using the sheet and an optical information recording medium.

  一种光固化转印片材，其光固化转印层由光固化组合物组成，光固化组合物在施加压力时可变形，并含有具有可光聚合官能团的反应性聚合物、 其中，光固化转移层在普通温度、50Pa 的应力和 120 秒的时间周期条件下，通过使用动态粘弹性测量仪器进行蠕变试验测得的应变[γ]（％）和时间[t]（秒）之间的关系呈线性，并满足以下公式：log γ = a + b-log t，其中 "a "为实数，"b "的范围为 0.10至0.53的范围内；以及使用该薄片和光学信息记录介质制备光学信息记录介质的工艺。