(2-methyl-1-n-octylindol-3-yl)-(2-carboxyphenyl)ketone | 60316-84-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (2-methyl-1-n-octylindol-3-yl)-(2-carboxyphenyl)ketone
• 英文别名: 2-[(1-n-octyl-2-methyl-3-indolyl)carbonyl]benzoic acid；3-(2'-carboxybenzoyl)-1-n-octyl-2-methylindole；2-(2-Methyl-1-octyl-1H-indole-3-carbonyl)benzoic acid；2-(2-methyl-1-octylindole-3-carbonyl)benzoic acid
• CAS: 60316-84-9
• 化学式: C₂₅H₂₉NO₃
• 分子量: 391.51
• InChiKey: FYMHLSPXVORCNS-UHFFFAOYSA-N

物化性质

• 沸点：
  579.5±40.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  59.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-乙氧基-N-苯基苯胺 、 (2-methyl-1-n-octylindol-3-yl)-(2-carboxyphenyl)ketone 生成 3-[N-(4-ethoxyphenyl)-N-phenylamino]-3-(1-n-octyl-2-methyl-3-indolyl)phthalide
  参考文献：
  名称：

  3-(Pyrrolo and 3-indolyl)-3-diphenylamino substituted phthalides

  摘要：

  3-杂环芳基-3-(二苯胺基)邻苯二甲酸酐可用作压敏无碳复写系统、热标记系统和蜡纸复印系统中的显色剂，通过将2-(杂环芳基羰基)苯甲酸与二苯胺反应制备。

  公开号：

  US04431819A1
• 作为产物：
  描述：

  苯酐 、 1-辛基-2-甲基吲哚 生成 (2-methyl-1-n-octylindol-3-yl)-(2-carboxyphenyl)ketone
  参考文献：
  名称：

  3-(Pyrrolo and 3-indolyl)-3-diphenylamino substituted phthalides

  摘要：

  3-杂环芳基-3-(二苯胺基)邻苯二甲酸酐可用作压敏无碳复写系统、热标记系统和蜡纸复印系统中的显色剂，通过将2-(杂环芳基羰基)苯甲酸与二苯胺反应制备。

  公开号：

  US04431819A1

文献信息

• Carbazole containing phthalides
  申请人：Sterling Drug Inc.

  公开号：US04182714A1

  公开（公告）日：1980-01-08

  3-Heteroaryl-3-(diphenylamino)phthalides useful as color formers in pressure-sensitive carbonless duplicating systems, thermal marking systems and hectographic copying systems are prepared by reacting 2-(heteroarylcarbonyl)-benzoic acids with diphenylamines.

  用于压敏无碳复写系统、热标记系统和蜡纸复印系统的3-杂环芳基-3-(二苯胺基)邻苯二甲酸酐，通过将2-(杂环芳基羰基)-苯甲酸与二苯胺反应制备。
• 3-Indolyl-3-bis-amino-phenyl-phthalide compounds
  申请人：Ciba-Geigy Corporation

  公开号：US04153609A1

  公开（公告）日：1979-05-08

  A 3-indolyl-3-bis-aminophenyl-phthalide compound of the formula ##STR1## wherein R.sub.1 represents alkyl which has at most 12 carbon atoms and is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, cycloalkyl, or unsubstituted or substituted phenyl or benzyl wherein the substituents are halogen, nitro, lower alkyl or lower alkoxy, R.sub.2 represents hydrogen, alkyl which has at most 12 carbon atoms and is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, cycloalkyl, or benzyl which is unsubstituted or substituted by halogen, nitro, lower alkyl or lower alkoxy, or R.sub.1 and R.sub.2 together with the nitrogen atom linking them represent a 5- or 6-membered heterocyclic radical, X.sub.1 and X.sub.2 independently of one another represent hydrogen, lower alkyl, cycloalkyl, benzyl which is unsubstituted or substituted by halogen, nitro, lower alkyl or lower alkoxy, or acyl having 1 to 8 carbon atoms, and X.sub.1 also represents phenyl which is unsubstituted or substituted by halogen, nitro, lower alkyl or lower alkoxy, Y represents hydrogen, alkyl which has at most 12 carbon atoms and is unsubstituted or substituted by halogen, hydroxyl or cyano, or benzyl which is unsubstituted or substituted by halogen, nitro, lower alkyl or lower alkoxy, Z represents hydrogen, lower alkyl or phenyl, and the rings A and B independently of one another are unsubstituted or substituted by halogen, nitro, amino or lower alkylamino; there compounds are particularly useful as color formers which give intense green-blue, blue or violet-blues shades of excellent fastness to light when they are brought into contact with an electron-accepting co-reactant.

  该化合物是一种3-吲哚基-3-双氨基苯基邻苯二酸酐，其结构式为##STR1##其中，R.sub.1代表最多有12个碳原子的烷基，未取代或取代为卤素、羟基、氰基或较低的烷氧基、环烷基，或未取代或取代的苯基或苄基，其中取代基为卤素、硝基、较低的烷基或较低的烷氧基；R.sub.2代表氢、最多有12个碳原子的烷基，未取代或取代为卤素、羟基、氰基或较低的烷氧基、环烷基，或未取代或取代的苄基，其中取代基为卤素、硝基、较低的烷基或较低的烷氧基；或者R.sub.1和R.sub.2与它们连接的氮原子一起代表一个5-或6-成员的杂环基；X.sub.1和X.sub.2分别独立地代表氢、较低的烷基、环烷基、未取代或取代的苄基，其中取代基为卤素、硝基、较低的烷基或较低的烷氧基，或具有1至8个碳原子的酰基，X.sub.1还代表未取代或取代的苯基，其中取代基为卤素、硝基、较低的烷基或较低的烷氧基；Y代表氢、最多有12个碳原子的烷基，未取代或取代为卤素、羟基或氰基，或未取代或取代的苄基，其中取代基为卤素、硝基、较低的烷基或较低的烷氧基；Z代表氢、较低的烷基或苯基，环A和环B分别独立地未取代或取代为卤素、硝基、氨基或较低的烷基氨基。这些化合物特别适用于作为色形成剂，当它们与电子受体的共反应物接触时，能够产生强烈的绿蓝色、蓝色或紫蓝色的色调，并具有良好的耐光性。
• Marking systems containing 3-aryl-3-heterylphthalides and
  申请人：Sterling Drug Inc.

  公开号：US04189171A1

  公开（公告）日：1980-02-19

  3-Aryl-3-indolylphthalides, 3-aryl-3-pyrrolylphthalides and 3-aryl-3-carbazolylphthalides prepared by interaction of the appropriate 2-(heteroaryl)carbonylbenzoic acid and the appropriate phenylamine, and 3,3-bis(indolyl)phthalides prepared by the interaction of the appropriate 2-(indolyl)carbonylbenzoic acid and the appropriate indole are useful as color formers in pressure-sensitive carbonless duplicating systems, thermal marking systems and hectographic copying systems.

  通过适当的2-(杂环芳基)羧酸苯和适当的苯胺之间的相互作用制备的3-Aryl-3-indolylphthalides、3-aryl-3-pyrrolylphthalides和3-aryl-3-carbazolylphthalides，以及通过适当的2-(吲哚基)羧酸苯和适当的吲哚之间的相互作用制备的3,3-双(吲哚基)邻苯二甲酸酯，在压敏无碳复写系统、热标记系统和电写复印系统中作为显色剂有用。
• Phthalide compounds, processes and marking systems
  申请人：Sterling Drug Inc.

  公开号：US04251446A1

  公开（公告）日：1981-02-17

  3-Aryl-3-indolylphthalides, 3-aryl-3-pyrrolylphthalides and 3-aryl-3-carbazolylphthalides prepared by interaction of the appropriate 2-(heteroaryl)carbonylbenzoic acid and the appropriate phenylamine, and 3,3-bis(indolyl)phthalides prepared by the interaction of the appropriate 2-(indolyl)carbonylbenzoic acid and the appropriate indole are useful as color formers in pressure-sensitive carbonless duplicating systems, thermal marking systems and hectographic copying systems.

  3-芳基-3-吲哚基酞酮、3-芳基-3-吡咯基酞酮和3-芳基-3-咔唑基酞酮是通过适当的2-(杂环芳基)羰基苯甲酸和适当的苯胺相互作用制备的，而3,3-双(吲哚基)酞酮则是通过适当的2-(吲哚基)羰基苯甲酸和适当的吲哚相互作用制备的。它们在压敏无碳复写系统、热标记系统和铜版复印系统中作为色形成剂是有用的。
• Indolyl phthalide compounds
  申请人：Sterling Drug Inc.

  公开号：US04322352A1

  公开（公告）日：1982-03-30

  3-Aryl-3-indolylphthalides, 3-aryl-3-pyrrolylphthalides and 3-aryl-3-carbazolylphthalides prepared by interaction of the appropriate 2-(heteroaryl)carbonylbenzoic acid and the appropriate phenylamine, and 3,3-bis(indolyl)phthalides prepared by the interaction of the appropriate 2-(indolyl)carbonylbenzoic acid and the appropriate indole are useful as color formers in pressure-sensitive carbonless duplicating systems, thermal marking systems and hectographic copying systems.

  通过适当的2-(杂环芳基)羧基苯甲酸和适当的苯胺的反应制备的3-芳基-3-吲哚基邻苯二甲酸酯，3-芳基-3-吡咯基邻苯二甲酸酯和3-芳基-3-咔唑基邻苯二甲酸酯，以及通过适当的2-(吲哚基)羧基苯甲酸和适当的吲哚的反应制备的3,3-双(吲哚基)邻苯二甲酸酯，可用作压敏无碳复写系统、热标记系统和静电复印系统中的色素形成剂。