1-cloro-6-methylheptane | 2350-20-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1-cloro-6-methylheptane
• 英文别名: 1-chloro-6-methyl-heptane；7-Chlor-2-methyl-heptan；1-Chloro-6-methylheptane
• CAS: 2350-20-1
• 化学式: C₈H₁₇Cl
• 分子量: 148.676
• InChiKey: SFGBOBMTMFHZJH-UHFFFAOYSA-N

物化性质

• 保留指数：
  1021;1052

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-cloro-6-methylheptane 在 potassium tert-butylate 、 间氯过氧苯甲酸 、 sodium iodide 作用下， 以 四氢呋喃 、 二氯甲烷 、 乙腈 为溶剂， 反应 30.0h， 生成 2-癸基-3-(5-甲基己基)环氧乙烷
  参考文献：
  名称：

  Ujvary, Istvan; Voigt, Erzsebet; Lesko, Katalin, Acta Chimica Hungarica, 1988, vol. 125, # 1, p. 131 - 140

  摘要：

  DOI：
• 作为产物：
  描述：

  C7-9-烷基醇 在 氯化亚砜 、 N,N-二甲基苯胺 作用下， 生成 1-cloro-6-methylheptane
  参考文献：
  名称：

  588.支链烃的合成和反应。第十七部分。N-氯磺酰胺作氯化剂

  摘要：

  DOI：

  10.1039/jr9650003228

文献信息

• [EN] IMPACT OF TRACE ELEMENTS IN THE GRIGNARD REACTION<br/>[FR] IMPACT D'ÉLÉMENTS TRACE DANS LA RÉACTION DE GRIGNARD
  申请人：BASF SE

  公开号：WO2020193617A1

  公开（公告）日：2020-10-01

  The present invention relates to an improved process for preparing 2,4-dichloro-6-(4- methoxyphenyl)-1,3,5-triazine (DICAT) comprising reacting 4-bromoanisole with magnesium, and reacting the resulting Grignard reagent with cyanuric chloride, wherein the magnesium comprises additional metals as impurities in an amount of less than 0.027 % by weight, based on the total weight of the magnesium.

  本发明涉及一种改进的制备2,4-二氯-6-(4-甲氧苯基)-1,3,5-三嗪（DICAT）的方法，包括将4-溴苯甲醚与镁反应，然后将得到的格氏试剂与三聚氰氯反应，其中镁中含有少于总重量的0.027％的杂质金属。
• Preparation of spherical magnesium alkoxide particles
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0216402A2

  公开（公告）日：1987-04-01

  A process for preparing spherical particles of a compound with the general formula Mg(OR)2-a(OR')a in which R is an alkyl group with from 2 to 8 carbon atoms, R' is an alkyl group with from 1 to 7 carbon atoms and a is a number of from 0 to 0.5, which comprises preparing a homogeneous solution of a compound Mg(OR)₂ in an aliphatic alcohol with the general formula R'OH spray-drying the solution at a temperature of from 15 to 85 °C, suspending the spray-dried solid particles in an aliphatic alcohol with the formula ROH in which R is the same alkyl group as present in the said compound Mg(OR)₂ heating the suspension in order to remove an alcohol with the formula R'OH from the liquid phase by distillation and separating the solid particles from the liquid phase.

  一种制备通式为 Mg(OR)2-a(OR')a的化合物的球形颗粒的工艺，其中 R 是具有 2 至 8 个碳原子的烷基，R'是具有 1 至 7 个碳原子的烷基，a 是 0 至 0.5，其中包括制备通式为 R'OH 的 Mg（OR）₂化合物在脂肪醇中的均匀溶液，在 15 至 85 °C 的温度下喷雾干燥该溶液、将喷雾干燥后的固体颗粒悬浮在通式为 ROH 的脂肪醇中，其中 R 是与上述化合物 Mg(OR)₂ 中相同的烷基； 加热悬浮液，以便通过蒸馏从液相中除去通式为 R'OH 的醇，并将固体颗粒从液相中分离出来。
• Apparatus and method for preparation and supply of polymerization inhibitor
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1298147A2

  公开（公告）日：2003-04-02

  An apparatus for the preparation and supply of a polymerization inhibitor which constantly effects stable supply of a polymerization inhibitor solution adjusted to a prescribed concentration and enables a compound handled at the next step to be prevented from polymerization is provided. The apparatus for the preparation and supply of a polymerization inhibitor has at least two tanks and a stirring device, a liquid level detector, a polymerization inhibitor input port, a concentration-adjusting liquid input port, and a polymerization inhibitor solution feed opening, each being installed in at least one of said tanks.

  本发明提供了一种用于制备和供应聚合抑制剂的设备，该设备可持续稳定地供应调整到规定浓度的聚合抑制剂溶液，并可防止下一步处理的化合物发生聚合。 这种用于制备和供应聚合抑制剂的设备至少有两个罐和一个搅拌装置、一个液位检测器、一个聚合抑制剂输入口、一个浓度调节液输入口和一个聚合抑制剂溶液进料口，它们分别安装在上述至少一个罐中。
• PARTICLE SIZE DISTRIBUTION CONTROL THROUGH INTERNAL DONOR IN ZIEGLER-NATTA CATALYST
  申请人：Indian Oil Corporation Limited

  公开号：EP2966099A1

  公开（公告）日：2016-01-13

  The present invention describes a process for controlling particle size of a catalyst composition. The process comprising the steps of contacting an internal donor with an organomagnesium precursor solution to form an intermediate solution and treating the intermediate solution with a transition metal compound to form a catalyst composition, wherein particle size of the catalyst composition is controlled by controlling a contact time of the internal donor with the precursor solution during formation of the intermediate solution.

  本发明描述了一种控制催化剂组合物粒度的工艺。该工艺包括以下步骤：将内部供体与有机镁前驱体溶液接触以形成中间溶液，以及用过渡金属化合物处理中间溶液以形成催化剂组合物，其中催化剂组合物的粒度是通过在中间溶液形成过程中控制内部供体与前驱体溶液的接触时间来控制的。
• IMPROVED ZIEGLER-NATTA CATALYST SYNTHESIS AND PROCESS THEREOF
  申请人：Indian Oil Corporation Limited

  公开号：EP3162819A1

  公开（公告）日：2017-05-03

  The present invention describes a process of preparing a catalyst for olefin polymerization comprising: (i) treating a magnesium metal with an organohalide along with an internal donor to obtain a reaction mixture having solid component (A); (ii) treating the reaction mixture having solid component (A) with an acyl halide to obtain a reaction mixture having solid component (B); and (iii) treating the reaction mixture having solid component (B) of step (ii) with a transition metal compound to obtain the catalyst. The present invention also relates to a process for preparation of a catalyst system from said catalyst and preparation of a polyolefins from the catalyst system.

  本发明描述了一种制备烯烃聚合催化剂的工艺，包括：(i) 将金属镁与有机卤化物和内部供体一起处理，得到具有固体组分（A）的反应混合物；(ii) 将具有固体组分（A）的反应混合物与酰基卤化物一起处理，得到具有固体组分（B）的反应混合物；(iii) 将步骤(ii)中具有固体组分（B）的反应混合物与过渡金属化合物一起处理，得到催化剂。本发明还涉及用上述催化剂制备催化剂体系和用催化剂体系制备聚烯烃的工艺。