butane-1,1,4-tricarboxylic acid-1,1-diethyl ester | 854463-51-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: butane-1,1,4-tricarboxylic acid-1,1-diethyl ester
• 英文别名: Butan-1,1,4-tricarbonsaeure-1,1-diaethylester；Butan-tricarbonsaeure-(1,1,4)-1,1-diethylester；6-Ethoxy-5-ethoxycarbonyl-6-oxohexanoic acid；6-ethoxy-5-ethoxycarbonyl-6-oxohexanoic acid
• CAS: 854463-51-7
• 化学式: C₁₁H₁₈O₆
• 分子量: 246.26
• InChiKey: PMFHXJJNMAHFJA-UHFFFAOYSA-N

物化性质

• 沸点：
  119.5-120 °C(Press: 0.03 Torr)
• 密度：
  1.161±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  89.9
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  butane-1,1,4-tricarboxylic acid-1,1-diethyl ester 在 sodium hydroxide 作用下， 生成 丁烷-1,1,4-三羧酸
  参考文献：
  名称：

  Trave,R. et al., Gazzetta Chimica Italiana, 1963, vol. 93, p. 1327 - 1342

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 platinum(IV) oxide 、 溶剂黄146 作用下， 生成 butane-1,1,4-tricarboxylic acid-1,1-diethyl ester
  参考文献：
  名称：

  Ruggli; Richter, Helvetica Chimica Acta, 1949, vol. 32, p. 1434,1436

  摘要：

  DOI：

文献信息

• Ruggli; Maeder, Helvetica Chimica Acta, 1943, vol. 26, p. 1494
  作者：Ruggli、Maeder

  DOI：——

  日期：——
• Die Reaktion von Succinylchlorid mit Natrium-malonester I. Über den sog. Succinyl-malonester (2-Butanoliden-malonester) und den Succinyl-dimalonester. (1. Mitteilung über Ketonsäuren, Enol-lactone und Ringketone)
  作者：Paul Ruggli、Arthur Maeder

  DOI：10.1002/hlca.19430260516

  日期：1943.8.2
• PHOTOINITIATOR, NOVEL COMPOUND, AND PHOTOCURABLE COMPOSITION
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP1490412A1

  公开（公告）日：2004-12-29
• [EN] PHOTOINITIATOR, NOVEL COMPOUND, AND PHOTOCURABLE COMPOSITION<br/>[FR] PHOTO-INITIATEUR, NOUVEAU COMPOSE ET COMPOSITION PHOTODURCISSABLE
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2003082929A1

  公开（公告）日：2003-10-09

  A photoinitiator is provided which exhibits excellent photosensitivity, yields colorless products, and is usable in thick layer UVcurable coating. A novel chemical compound is also provided which is usable for the photoinitiator. Photocurable composition is also provided which has these properties. The photoinitiator consists essentially of a compound having a molicular weight of 1000 or less, and having a chemical structure represented by the following formula (1), wherein R3 and R4 independently denote a specific alkyl group, and R1 and R2 independently de note an electron attracting group or a specific alkyl group, and weight percentage of a chemical structure element represented by the following formula (2), which is expressed in formula (1) based on the total molecular weight of the compound, is 17% to 54% by mass.
• Trave,R. et al., Gazzetta Chimica Italiana, 1963, vol. 93, p. 1327 - 1342
  作者：Trave,R. et al.

  DOI：——

  日期：——