4-(4-bromophenyl)-6-(1-naphthyl)-2-phenylpyrimidine | 869085-84-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 4-(4-bromophenyl)-6-(1-naphthyl)-2-phenylpyrimidine
• 英文别名: 4-(4-Bromophenyl)-6-naphthalen-1-yl-2-phenylpyrimidine
• CAS: 869085-84-7
• 化学式: C₂₆H₁₇BrN₂
• 分子量: 437.338
• InChiKey: MMPOPAAZSFHWSZ-UHFFFAOYSA-N

物化性质

• 沸点：
  513.6±32.0 °C(Predicted)
• 密度：
  1.358±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  29
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(4-bromophenyl)-6-(1-naphthyl)-2-phenylpyrimidine 、 3-(quinolin-8-yl)carbazole 在 18-冠醚-6 、 三叔丁基膦 、 palladium diacetate 、 potassium carbonate 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 、 甲苯 为溶剂， 反应 20.0h， 以91%的产率得到9-[4-(6-naphthyl-2-phenylpyrimidin-4-yl)phenyl]-3-(quinolin-8-yl)carbazole
  参考文献：
  名称：

  JP2015/6995

  摘要：

  公开号：
• 作为产物：
  描述：

  1-(4-bromophenyl)-3-(1-naphthyl)-2-propen-1-one 、 苄脒盐酸盐 在 potassium hydroxide 作用下， 以 乙醇 为溶剂， 反应 17.0h， 以52%的产率得到4-(4-bromophenyl)-6-(1-naphthyl)-2-phenylpyrimidine
  参考文献：
  名称：

  JP2015/6995

  摘要：

  公开号：

文献信息

• COMPOUNDS WITH SPIROBIFLUORENE-STRUCTURES
  申请人：Merck Patent GmbH

  公开号：US20190106391A1

  公开（公告）日：2019-04-11

  The present invention describes spirobifluorene derivatives substituted by pyridine and/or pyrimidine groups, especially for use in electronic devices. The invention further relates to a process for preparing the compounds of the invention and to electronic devices comprising these.

  本发明描述了由吡啶和/或嘧啶基团取代的螺环联苯衍生物，特别适用于电子器件。该发明还涉及制备本发明化合物的方法以及包含这些化合物的电子器件。
• AROMATIC AMINE DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2589596A1

  公开（公告）日：2013-05-08

  An aromatic amine derivative represented by the following formula (1), wherein at least one of Ar1 to Ar3 is represented by the following formula (2), wherein X1 to X3 are independently a nitrogen atom or CR2, provided that two of X1 to X3 are a nitrogen atom and X1 and X3 are not simultaneously a nitrogen atom.

  由下式（1）表示的芳香胺衍生物，其中 Ar1 至 Ar3 中至少有一个由下式（2）表示，其中 X1 至 X3 独立地为氮原子或 CR2，条件是 X1 至 X3 中的两个为氮原子，且 X1 和 X3 不同时为氮原子。
• Organic Electroluminescent Device
  申请人：Ikeda Kiyoshi

  公开号：US20070224448A1

  公开（公告）日：2007-09-27

  Provided is an organic electroluminescence device having high luminous efficiency, high heat resistance and an extremely long lifetime. The organic electroluminescence device of the present invention includes an organic thin film layer composed of one or more layers containing at least a light emitting layer is interposed between a cathode and an anode. The light emitting layer includes a compound containing a condensed ring and a luminescent metal complex capable of emitting light having a red-based color. It is preferable that the compound containing a condensed ring includes a host material, while the luminescent metal complex capable of emitting light having a red-based color includes a phosphorescent dopant.
• Aromatic amine derivative and organic electroluminescence device using the same
  申请人：Kato Tomoki

  公开号：US20120001154A1

  公开（公告）日：2012-01-05

  An aromatic amine derivative represented by the following formula (1), wherein at least one of Ar 1 to Ar 3 is represented by the following formula (2), wherein X 1 to X 3 are independently a nitrogen atom or CR 2 , provided that two of X 1 to X 3 are a nitrogen atom and X 1 and X 3 are not simultaneously a nitrogen atom.
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US20140018536A1

  公开（公告）日：2014-01-16

  An aromatic amine derivative represented by the following formula (1), wherein at least one of Ar 1 to Ar 3 is represented by the following formula (2), wherein X 1 to X 3 are independently a nitrogen atom or CR 2 , provided that two of X 1 to X 3 are a nitrogen atom and X 1 and X 3 are not simultaneously a nitrogen atom