4-deoxy-D-fructose | 50439-30-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-deoxy-D-fructose
• 英文别名: (3S,5S)-1,3,5,6-tetrahydroxyhexan-2-one
• CAS: 50439-30-0
• 化学式: C₆H₁₂O₅
• 分子量: 164.158
• InChiKey: UQZTYCQHZBCWQZ-WHFBIAKZSA-N

物化性质

• 沸点：
  467.6±45.0 °C(Predicted)
• 密度：
  1.421±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -2.3
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  98
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4-脱氧-D-木糖基-己糖 生成 4-deoxy-D-fructose
  参考文献：
  名称：

  KUCAR, S.;ZEMEK, J.;ZAMOCKY, J.

  摘要：

  DOI：

文献信息

• Enzyme-catalyzed synthesis of carbohydrates: synthetic potential of transketolase
  作者：Colette Demuynck、Jean Bolte、Laurence Hecquet、Valérie Dalmas

  DOI：10.1016/s0040-4039(00)93434-8

  日期：1991.9

  The synthetic potential of yeast or spinach transketolases was studied, using hydroxypyruvate as a donor substrate and 31 aldehydes as acceptors. All of them react, including aromatic, heteroaromatic and alpha,beta unsaturated aldehydes.
• Syntheses of 4-deoxy-d-fructose and enzymatic affinity study
  作者：Corinne André、Jean Bolte、Colette Demuynck

  DOI：10.1016/s0957-4166(98)00398-x

  日期：1998.11

  Enantiomerically pure 4-deoxy-D-fructose has been prepared and characterised in a protected form, acidic hydrolysis of which led to an aqueous solution of 4-deoxy-D-fructose. Activities of this compound with enzymes of the glycolysis pathway involved in glucose metabolism make possible access to 4-deoxy-D-fructose-6-phosphate, 4-deoxy-D-glucose-6-phosphate and 4-deoxy-D-gluconate-6-phosphate. (C) 1998 Elsevier Science Ltd. All rights reserved.
• KUCAR, S.;ZEMEK, J.;ZAMOCKY, J.
  作者：KUCAR, S.、ZEMEK, J.、ZAMOCKY, J.

  DOI：——

  日期：——