5-[[2-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl]thio]-methyl-2,2'-bipyridine | 1346143-00-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 5-[[2-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl]thio]-methyl-2,2'-bipyridine
• 英文别名: 5-[[2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanylmethyl]-2-pyridin-2-ylpyridine；5-[[2-[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanylmethyl]-2-pyridin-2-ylpyridine
• CAS: 1346143-00-7
• 化学式: C₂₀H₁₈N₂S₈
• 分子量: 542.904
• InChiKey: GSVYDODNISMBAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  228
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  五羰基溴铼(I) 、 5-[[2-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl]thio]-methyl-2,2'-bipyridine 以 甲苯 为溶剂， 以73%的产率得到(5-[[2-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl]thio]-methyl-2,2'-bipyridine)tricarbonylbromorhenium(I)
  参考文献：
  名称：

  Rhenium(I) tricarbonyl complexes based on the new tetrathiafulvalene bipyridine ligand

  摘要：

  Using the deprotection-realkylation methodology, a new electroactive tetrathiafulvalene-based bipyridine ligand, 5-[{2-[4,5-Bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl}thio]-methyl-2,2'-bipyridine (L), has been synthesized. Reactions of the above ligand with Re(CO)(5)Br or Re(CO)(5)Cl afford the corresponding tricarbonyl rhenium(I) complexes ReL(CO)(3)X (X = Br, 1; X = Cl, 2), respectively. Crystal structures of 1 and 2 have been described. The absorption properties of these new compounds have been studied. Electrochemical measurements have been performed and TTF/TTF+center dot/TTF2+ redox processes are observed. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.09.017
• 作为产物：
  描述：

  5-(溴甲基)-2-吡啶-2-基吡啶 、 2-(2'-cyanoethylthio)-3,6,7-tris(methylthio)tetrathiafulvalene 在 cesiumhydroxide monohydrate 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以42%的产率得到5-[[2-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl]thio]-methyl-2,2'-bipyridine
  参考文献：
  名称：

  Rhenium(I) tricarbonyl complexes based on the new tetrathiafulvalene bipyridine ligand

  摘要：

  Using the deprotection-realkylation methodology, a new electroactive tetrathiafulvalene-based bipyridine ligand, 5-[{2-[4,5-Bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl}thio]-methyl-2,2'-bipyridine (L), has been synthesized. Reactions of the above ligand with Re(CO)(5)Br or Re(CO)(5)Cl afford the corresponding tricarbonyl rhenium(I) complexes ReL(CO)(3)X (X = Br, 1; X = Cl, 2), respectively. Crystal structures of 1 and 2 have been described. The absorption properties of these new compounds have been studied. Electrochemical measurements have been performed and TTF/TTF+center dot/TTF2+ redox processes are observed. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.09.017

文献信息

• Rhenium(I) tricarbonyl complexes based on the new tetrathiafulvalene bipyridine ligand
  作者：Tao Jin、Gao-Nan Li、Xin-Hui Zhou、Jing-Lin Zuo

  DOI：10.1016/j.inoche.2011.09.017

  日期：2011.12

  Using the deprotection-realkylation methodology, a new electroactive tetrathiafulvalene-based bipyridine ligand, 5-[2-[4,5-Bis(methylthio)-1,3-dithiol-2-ylidene]-5-(methylthio)-1,3-dithiol-4-yl}thio]-methyl-2,2'-bipyridine (L), has been synthesized. Reactions of the above ligand with Re(CO)(5)Br or Re(CO)(5)Cl afford the corresponding tricarbonyl rhenium(I) complexes ReL(CO)(3)X (X = Br, 1; X = Cl, 2), respectively. Crystal structures of 1 and 2 have been described. The absorption properties of these new compounds have been studied. Electrochemical measurements have been performed and TTF/TTF+center dot/TTF2+ redox processes are observed. (C) 2011 Elsevier B.V. All rights reserved.