1,2,3-Trimethyl-5-propoxy-benzene | 138376-24-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,2,3-Trimethyl-5-propoxy-benzene
• 英文别名: 1,2,3-Trimethyl-5-propoxybenzene
• CAS: 138376-24-6
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: GJZKOZFLABJTFP-UHFFFAOYSA-N

物化性质

• 沸点：
  270.3±9.0 °C(Predicted)
• 密度：
  0.912±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  丙醇 、 异佛尔酮 在 ammonium cerium(IV) nitrate 、 碘 作用下， 反应 25.0h， 以66%的产率得到1,2,3-Trimethyl-5-propoxy-benzene
  参考文献：
  名称：

  α,β-不饱和环己酮与碘-铈 (IV) 硝酸铵在酒精中的新氧化芳构化

  摘要：

  2-环己烯-1-酮衍生物与碘-铈（IV）硝酸铵在醇（甲醇、乙醇、1-丙醇、2-丙醇和1-丁醇）中回流反应，得到相应的烷基苯基醚良好的收益。在二醇（乙二醇、1,3-丙二醇和1,4-丁二醇）的情况下，获得苯氧基链烷醇衍生物。本方法也适用于异佛尔酮的氧化重排。

  DOI：

  10.1246/cl.1991.1921

文献信息

• ORGANIC ELECTROLUMINESCENCE ELEMENT, WHITE LIGHT EMITTING ELEMENT, DISPLAY DEVICE AND ILLUMINATING DEVICE
  申请人：KONICA MINOLTA HOLDINGS, INC.

  公开号：EP1988143A1

  公开（公告）日：2008-11-05

  Provided is an organic EL element having a controlled emission wavelength, high emission efficiency and a long emission life. A white light emitting element, a display device and an illuminating device using such organic EL element are also provided.

  本发明提供了一种具有可控发射波长、高发射效率和长发射寿命的有机 EL 元件。还提供了使用这种有机 EL 元件的白光发光元件、显示设备和照明设备。
• ORGANIC ELECTROLUMINESCENCE ELEMENT, LIGHTING DEVICE AND DISPLAY DEVICE
  申请人：Katakura Rie

  公开号：US20100045171A1

  公开（公告）日：2010-02-25

  Disclosed is an organic electroluminescent device having high external quantum efficiency and long emission life. Also disclosed are an illuminating device and a display, each comprising such an organic electroluminescent device. The organic electroluminescent device is characterized by comprising at least an anode and a cathode on a supporting substrate, while having at least one light-emitting layer between the anode and the cathode. The organic electroluminescent device is also characterized by containing a polymer which at least partially contains a compound A having a partial structure represented by the general formula (a) below and a reactive group, and is obtained by polymerizing the compound A through the reactive group. (In the formula, Ar1 and Ar2 respectively represent an aromatic ring.)
• ORGANIC ELECTROLUMINESCENCE ELEMENT, NEW COMPOUND FOR THE SAME, DISPLAY DEVICE AND LIGHTING DEVICE USING THE SAME
  申请人：KATAKURA Rie

  公开号：US20110006670A1

  公开（公告）日：2011-01-13

  Disclosed is an organic electroluminescence element comprising an anode, a cathode and a plurality of organic compound layers between the anode and the cathode, provided that one of the organic compound layers is a light emitting layer containing a phosphorescence emitting compound, wherein at least one of the organic compound layers contains a compound represented by Formula (1), wherein, X represents O or S; Y 1 to Y 3 each represents a hydrogen atom, a substituent or a group represented by Formula (A) disclosed in the specification, provided that at least two of Y 1 to Y 3 are groups represented by Formula (A), not all of Y 1 to Y 3 are the same group, and at least one of the groups represented by Formula (A) has Ar of a carbazolyl group, or an azacarbazolyl group containing 2 to 5 nitrogen atoms.
• US8852757B2
  申请人：——

  公开号：US8852757B2

  公开（公告）日：2014-10-07
• US9315542B2
  申请人：——

  公开号：US9315542B2

  公开（公告）日：2016-04-19