3-[5-(3-Hydroxyphenoxy)pentoxy]phenol | 34784-56-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-[5-(3-Hydroxyphenoxy)pentoxy]phenol
• CAS: 34784-56-0
• 化学式: C₁₇H₂₀O₄
• 分子量: 288.343
• InChiKey: XJCVXEXZUPOUJO-UHFFFAOYSA-N

物化性质

• 熔点：
  110.5-112 °C(Solv: benzene (71-43-2))
• 沸点：
  497.0±30.0 °C(Predicted)
• 密度：
  1.178±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-[5-(3-Hydroxyphenoxy)pentoxy]phenol 、 丙烯酰氯 生成 [3-[5-(3-Prop-2-enoyloxyphenoxy)pentoxy]phenyl] prop-2-enoate
  参考文献：
  名称：

  RESNICK, B. M.

  摘要：

  DOI：
• 作为产物：
  描述：

  1,5-二溴戊烷 、 间苯二酚 在 氢氧化钾 、 sodium dithionite 作用下， 以 乙醇 为溶剂， 以17%的产率得到3-[5-(3-Hydroxyphenoxy)pentoxy]phenol
  参考文献：
  名称：

  Multicyclic Polyethers Derived from 1,4-Dicyanotetrafluorobenzene and Flexible Diphenols

  摘要：

  1,4-Dicyanotetrafluorobenzene (DCTB) was polycondensed with various diphenols in DMF or DMSO using K2CO3 as catalyst and HF acceptor. At concentrations of 0.1 or 0.2 mol/ L for DCTB, gels were obtained with 1,4-bis[2-(4-hydroxyphenyl)-2-propyl] benzene, with 1,3-bis[(4-hydroxyphenyl)- 2- propyl] benzene and with alpha,omega-bis(4-hydroxyphenoxy) alkanes as comonomers. Yet soluble multicyclic polyethers were formed with alpha,omega-bis(3-hydroxyphenoxy) alkanes. The lengths of the alkane chains did not play any role for the successful syntheses of soluble multicycles. Furthermore, a model reaction with p-cresol was conducted, proving the feasibility of a quantitative tetrasubstitution of all four F-atoms in DCTB. The multicyclic polyethers were characterized by elemental analyses, C-13 NMR spectroscopy, MALDI-TOF mass spectrometry, DSC, viscosity, and SEC measurements. As expected, high polydispersities (up to 8) were found. The DSC measurements indicated an amorphous character of all multicycles with glass-transition temperatures (Tgs) between 75 and 161 degrees C.

  DOI：

  10.1021/ma060895l

文献信息

• RESNICK, B. M.
  作者：RESNICK, B. M.

  DOI：——

  日期：——
• US4320144A
  申请人：——

  公开号：US4320144A

  公开（公告）日：1982-03-16
• US9310681B2
  申请人：——

  公开号：US9310681B2

  公开（公告）日：2016-04-12
• Multicyclic Polyethers Derived from 1,4-Dicyanotetrafluorobenzene and Flexible Diphenols
  作者：Hans R. Kricheldorf、Johann Schellenberg、Gert Schwarz

  DOI：10.1021/ma060895l

  日期：2006.9.1

  1,4-Dicyanotetrafluorobenzene (DCTB) was polycondensed with various diphenols in DMF or DMSO using K2CO3 as catalyst and HF acceptor. At concentrations of 0.1 or 0.2 mol/ L for DCTB, gels were obtained with 1,4-bis[2-(4-hydroxyphenyl)-2-propyl] benzene, with 1,3-bis[(4-hydroxyphenyl)- 2- propyl] benzene and with alpha,omega-bis(4-hydroxyphenoxy) alkanes as comonomers. Yet soluble multicyclic polyethers were formed with alpha,omega-bis(3-hydroxyphenoxy) alkanes. The lengths of the alkane chains did not play any role for the successful syntheses of soluble multicycles. Furthermore, a model reaction with p-cresol was conducted, proving the feasibility of a quantitative tetrasubstitution of all four F-atoms in DCTB. The multicyclic polyethers were characterized by elemental analyses, C-13 NMR spectroscopy, MALDI-TOF mass spectrometry, DSC, viscosity, and SEC measurements. As expected, high polydispersities (up to 8) were found. The DSC measurements indicated an amorphous character of all multicycles with glass-transition temperatures (Tgs) between 75 and 161 degrees C.