2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxo-8,19-dicyanoenneacene | 1454868-09-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxo-8,19-dicyanoenneacene
• 英文别名: CDPzN；6,17,25,36-Tetrachloro-11,12,30,31-tetrakis-decoxy-4,19,23,38-tetraoxa-8,15,27,34-tetrazanonacyclo[20.16.0.03,20.05,18.07,16.09,14.024,37.026,35.028,33]octatriaconta-1(22),2,5,7,9,11,13,15,17,20,24,26,28,30,32,34,36-heptadecaene-2,21-dicarbonitrile；6,17,25,36-tetrachloro-11,12,30,31-tetrakis-decoxy-4,19,23,38-tetraoxa-8,15,27,34-tetrazanonacyclo[20.16.0.03,20.05,18.07,16.09,14.024,37.026,35.028,33]octatriaconta-1(22),2,5,7,9,11,13,15,17,20,24,26,28,30,32,34,36-heptadecaene-2,21-dicarbonitrile
• CAS: 1454868-09-7
• 化学式: C₇₂H₈₈Cl₄N₆O₈
• 分子量: 1307.34
• InChiKey: GKQGRZWDGYGJII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.4
• 重原子数：
  90
• 可旋转键数：
  40
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  173
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  邻苯二酚 在 palladium 10% on activated carbon 、 硝酸 、 potassium carbonate 、 一水合肼 、 溶剂黄146 作用下， 以 乙醇 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 194.0h， 生成 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxo-8,19-dicyanoenneacene
  参考文献：
  名称：

  Synthesis, Characterization, and Nonvolatile Ternary Memory Behavior of a Larger Heteroacene with Nine Linearly Fused Rings and Two Different Heteroatoms

  摘要：

  To achieve ultrahigh density memory devices with the capacity of 3(n) or larger, organic materials with multilevel stable states are highly desirable. Here, we reported a novel larger stable heteroacene, 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxa-8,19-dicyanoenneacene (CDPzN), which has two different types of heteroatoms (O and N) and nine linearly fused rings. The sandwich-structure memory devices based on CDPzN exhibited excellent ternary memory behaviors with high ON2/ON1/OFF current ratios of 10(6.3)/10(4.3)/1 and good stability for these three states.

  DOI：

  10.1021/ja408208c

文献信息

• Synthesis, Characterization, and Nonvolatile Ternary Memory Behavior of a Larger Heteroacene with Nine Linearly Fused Rings and Two Different Heteroatoms
  作者：Pei-Yang Gu、Feng Zhou、Junkuo Gao、Gang Li、Chengyuan Wang、Qing-Feng Xu、Qichun Zhang、Jian-Mei Lu

  DOI：10.1021/ja408208c

  日期：2013.9.25

  To achieve ultrahigh density memory devices with the capacity of 3(n) or larger, organic materials with multilevel stable states are highly desirable. Here, we reported a novel larger stable heteroacene, 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxa-8,19-dicyanoenneacene (CDPzN), which has two different types of heteroatoms (O and N) and nine linearly fused rings. The sandwich-structure memory devices based on CDPzN exhibited excellent ternary memory behaviors with high ON2/ON1/OFF current ratios of 10(6.3)/10(4.3)/1 and good stability for these three states.