bis(2-hydroxyethyl) fumarate | 3207-11-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: bis(2-hydroxyethyl) fumarate
• 英文别名: di-(2-hydroxyethyl) fumarate；bis(2-hydroxyethyl) (E)-but-2-enedioate
• CAS: 3207-11-2
• 化学式: C₈H₁₂O₆
• 分子量: 204.18
• InChiKey: SMPWDQQFZPIOGD-OWOJBTEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.2
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  bis(2-hydroxyethyl) fumarate 在 sodium hydrogensulfite 作用下， 以 水 为溶剂， 生成 Sodium;1,4-bis(2-hydroxyethoxy)-1,4-dioxobutane-2-sulfonate
  参考文献：
  名称：

  CN115583901

  摘要：

  公开号：
• 作为产物：
  描述：

  反丁烯二酰氯 、 乙二醇 反应 24.0h， 以54%的产率得到bis(2-hydroxyethyl) fumarate
  参考文献：
  名称：

  Charlton, James L.; Maddaford, Shawn, Canadian Journal of Chemistry, 1993, vol. 71, # 6, p. 827 - 833

  摘要：

  DOI：

文献信息

• [EN] POLYGLYOXYLATES, MANUFACTURE AND USE THEREOF<br/>[FR] POLYGLYOXYLATES, LEUR PRODUCTION ET LEUR UTILISATION
  申请人：UNIV WESTERN ONTARIO

  公开号：WO2015168809A1

  公开（公告）日：2015-11-12

  Self-immolative polymers degrade by an end-to-end depolymerisation mechanism in response to the cleavage of a stabilizing end-cap from the polymer terminus. Examples include homopolymers, mixed polymers including block copolymers, suitable for a variety of applications. A polyglyoxylate can be end-capped or capped with a linker as in a block copolymer.

  自焚式聚合物通过从聚合物末端切割稳定端盖，以端到端解聚机制进行降解。例如包括均聚物、混合聚合物包括区块共聚物，适用于各种应用。聚乙二醇酸可以端接或与连接剂如区块共聚物一样封端。
• PARABEN DERIVATIVES FOR PRESERVING CELLULOSIC MATERIALS
  申请人：CARLSON William B.

  公开号：US20130004785A1

  公开（公告）日：2013-01-03

  A method of preserving a cellulosic material are provided. The method includes contacting the cellulosic material with a paraben-containing monomer and polymerizing the paraben-containing monomer. Articles including a cellulosic material and at least one polymer which includes paraben moieties are also provided.

  提供了一种保存纤维素材料的方法。该方法包括将纤维素材料与含对羟基苯甲酸酯单体接触，并聚合含有对羟基苯甲酸酯单体的聚合物。还提供了包括纤维素材料和至少一种包含对羟基苯甲酸酯基团的聚合物的制品。
• URETHANE-FORMING REACTION CATALYST AND METHOD FOR PRODUCING URETHANE MATERIAL
  申请人：Oki Hironobu

  公开号：US20110237758A1

  公开（公告）日：2011-09-29

  The present invention provides a urethane-forming reaction catalyst which is useful for catalyzing a reaction between an isocyanate compound, in particular, an aliphatic isocyanate and a hydroxyl group-containing compound to form a urethane material, which does not affect the performance of the urethane material, and which can be easily removed from the resulting urethane material, and a method for producing a metal compound-free urethane material using the urethane-forming reaction catalyst. The catalyst of the present invention is a urethane-forming reaction catalyst for producing a urethane material by allowing a hydroxyl group-containing compound to react with an isocyanate compound, the catalyst being at least one solid acid catalyst selected from the group consisting of a (A) composite metal oxide in which a metal oxide (A-2) or a non-metal compound (A-3) is carried on a surface of a metal oxide carrier (A-1), (B) zeolite, and a (C) heteropoly acid.

  本发明提供了一种尿素形成反应催化剂，用于催化异氰酸酯化合物（特别是脂肪族异氰酸酯）和含羟基化合物之间的反应，形成尿素材料，该催化剂不影响尿素材料的性能，并且可以轻松从所得到的尿素材料中去除。同时，本发明还提供了一种使用该尿素形成反应催化剂生产无金属化合物的尿素材料的方法。本发明的催化剂是一种尿素形成反应催化剂，通过使含羟基化合物与异氰酸酯化合物反应来生产尿素材料，所述催化剂是至少一种固体酸催化剂，所述固体酸催化剂选自以下群组中的至少一种：(A)将金属氧化物（A-2）或非金属化合物（A-3）负载在金属氧化物载体（A-1）表面的复合金属氧化物；(B)沸石；以及(C)杂多酸。
• ADHESIVE COMPOSITION
  申请人：ZEON CORPORATION

  公开号：US20150225618A1

  公开（公告）日：2015-08-13

  An adhesive composition containing a latex of a highly saturated nitrile rubber (A) which has α,β-ethylenically unsaturated nitrile monomer units 10 to 55 wt %, conjugated diene monomer units 25 to 89 wt %, and α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units 1 to 20 wt % and has an iodine value of 120 or less and a polyvalent amine compound (B).

  一种黏合剂组合物，包含高度饱和丙烯腈橡胶（A）的乳液，其中α，β-乙烯基不饱和丙烯腈单体单位占10至55重量％，共轭二烯单体单位占25至89重量％，α，β-乙烯基不饱和二羧酸单酯单体单位占1至20重量％，并且具有碘值不超过120和多价胺化合物（B）。
• Lithographic ink containing oxidatively curable reactive diluent and use thereof
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0015147A1

  公开（公告）日：1980-09-03

  In lithographic inks containing colorant, binder resin and reactive diluent, the diluent comprises oxidatively curable ester prepared by reaction of drying oil fatty acid with hydroxyl-containing, addition polymerizable compounds, such as reaction product of polyol with addition polymerizable acid, hydroxyalkyl ester of such acid, hydroxyalkyl vinyl sulfide or hydroxyalkyl vinyl ether. The curable ester may also be prepared by reaction of addition polymerizable acid with hydroxyl-containing reaction product of polyol with drying oil fatty acid. Transesterifiable esters can be used instead of the acids. Preferred drying oil acids are derived from tung oil, linseed oil, safflower oil, soybean oil or dehydrated castor oil. The curable ester preferably comprises acryloxy alkyl or methacryloxy alkyl drying oil fatty acid ester.

  在含有着色剂、粘合剂树脂和活性稀释剂的平版印刷油墨中，稀释剂包括通过干燥油脂酸与含羟基的可加成聚合化合物（如多元醇与可加成聚合酸的反应产物、此类酸的羟烷基酯、羟烷基乙烯基硫醚或羟烷基乙烯基醚）反应制备的氧化可固化酯。固化酯也可以通过可加成聚合酸与多元醇与干燥油脂肪酸的含羟基反应产物反应制备。也可以使用可酯化的酯来代替酸。首选的干燥油酸来自桐油、亚麻籽油、红花油、大豆油或脱水蓖麻油。固化酯最好包括丙烯酰氧基烷基或甲基丙烯酰氧基烷基干燥油脂肪酸酯。