2,3-dihydroxypropyl N-allylcarbamate | 82771-98-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 2,3-dihydroxypropyl N-allylcarbamate
• 英文别名: 2,3-dihydroxypropyl N-prop-2-enylcarbamate
• CAS: 82771-98-0
• 化学式: C₇H₁₃NO₄
• 分子量: 175.185
• InChiKey: MMFRAXZJMWLJDZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  78.8
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  羟甲基二氧杂戊环酮 、 丙烯胺 以 四氢呋喃 为溶剂， 反应 120.0h， 生成 1,3-dihydroxyprop-2-yl N-allylcarbamate 、 2,3-dihydroxypropyl N-allylcarbamate
  参考文献：
  名称：

  Tosylated glycerol carbonate, a versatile bis-electrophile to access new functionalized glycidol derivatives

  摘要：

  The reactivity of tosylated glycerol carbonate 2 toward nucleophiles has been exploited to generate glycidol analogues protected with carbonate or carbamate groups. The activated glycerol 2 is a reasonable linking agent with thiol and alcohol nucleophiles and an excellent and selective one with primary amines, allowing efficient bis-functionalizations of glycerol. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.07.095

文献信息

• Alkyl and/or alkenyl glycerol carbamates
  申请人：——

  公开号：US20040110659A1

  公开（公告）日：2004-06-10

  Alkyl and/or alkenyl glycerol carbamate prepared by reacting a carbonate selected from the group consisting of glycerol carbonate, diglycerol carbonate, polyglycerol carbonate and mixtures thereof, with an amine of the general formula (I): HNR 1 R 2 (I) wherein R 1 represents a hydrogen atom or a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 1 to 22 carbon atoms and R 2 represents a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 4 to 22 carbon atoms, and cyclic alkyl groups having 5 or 6 carbon atoms, are described along with methods for their use as thickeners in surface-active preparations.

  烷基和/或烯基甘油氨基甲酸酯，其制备方法是将选自甘油碳酸酯、二甘油碳酸酯、聚甘油碳酸酯及其混合物的碳酸酯与通式 (I) 的胺反应： HNR 1 R 2 (I) 其中 R 1 代表氢原子或烃基，选自由碳原子数为 1-22 个的烷基和烯基组成的组，且 R 2 代表从具有 4 至 22 个碳原子的烷基和烯基以及具有 5 或 6 个碳原子的环状烷基组成的组中选出的烃基。