bis(3-nitrophenyl) glutarate | 130912-21-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: bis(3-nitrophenyl) glutarate
• 英文别名: Bis(3-nitrophenyl) pentanedioate
• CAS: 130912-21-9
• 化学式: C₁₇H₁₄N₂O₈
• 分子量: 374.307
• InChiKey: MHJFESMNSZYPLI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  144
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (1S,3R,5R,6R,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31S,33R,35R,36R,37R,38R,39R,40R,41R,42R,43R,44R,45R,46R,47R,48R,49R)-5-(aminomethyl)-10,15,20,25,30,35-hexakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29,32,34-tetradecaoxaoctacyclo[31.2.2.23,6.28,11.213,16.218,21.223,26.228,31]nonatetracontane-36,37,38,39,40,41,42,43,44,45,46,47,48,49-tetradecol 、 bis(3-nitrophenyl) glutarate 生成 N,N'-bis[[(1S,3R,5R,6R,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31S,33R,35R,36R,37R,38R,39R,40R,41R,42R,43R,44R,45R,46R,47R,48R,49R)-36,37,38,39,40,41,42,43,44,45,46,47,48,49-tetradecahydroxy-10,15,20,25,30,35-hexakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29,32,34-tetradecaoxaoctacyclo[31.2.2.23,6.28,11.213,16.218,21.223,26.228,31]nonatetracontan-5-yl]methyl]pentanediamide
  参考文献：
  名称：

  COATES, JOHN H.;EASTON, CHRISTOPHER J.;VAN, EYK STEPHEN J.;LINCOLN, STEPH+, J. CHEM. SOC. PT 1. PERKIN TRANS. PT 1,(1990) N, C. 2619-2620

  摘要：

  DOI：
• 作为产物：
  描述：

  间硝基苯酚 、 戊二酸 生成 bis(3-nitrophenyl) glutarate
  参考文献：
  名称：

  COATES, JOHN H.;EASTON, CHRISTOPHER J.;VAN, EYK STEPHEN J.;LINCOLN, STEPH+, J. CHEM. SOC. PT 1. PERKIN TRANS. PT 1,(1990) N, C. 2619-2620

  摘要：

  DOI：

文献信息

• A Versatile Synthesis of Linked Cyclodextrins
  作者：Christopher J. Easton、Steven J. van Eyk、Stephen F. Lincoln、Bruce L. May、John Papageorgiou、Michael L. Williams

  DOI：10.1071/c96168

  日期：——

  Reactions of amino-substituted cyclodextrins with bis(3-nitrophenyl) oxalate, malonate, succinate and glutarate, and with diphenyl carbonate, afford a range of linked cyclodextrins. These include α- and β-cyclodextrin dimers, joined by substitution at either C6 or C3, and asymmetric species with a β-cyclodextrin bonded to an a-cyclodextrin and a C3-substituted cyclodextrin attached to a C6-substituted moiety.

  氨基取代的环糊精与双（3-硝基苯基）草酸酯、丙二酸酯、琥珀酸酯和戊二酸酯以及碳酸二苯酯的反应生成了一系列的环糊精、 丙二酸二（3-硝基苯基）草酸盐、丙二酸二（3-硝基苯基 环糊精。其中包括 α- 和 β-环糊精二聚体、 环糊精二聚体，通过 C6 或 C3 取代连接，以及具有 β-环糊精与 a-环糊精结合，C3-取代的环糊精与 C6 环糊精与 C6 取代的分子相连。
• COATES, JOHN H.;EASTON, CHRISTOPHER J.;VAN, EYK STEPHEN J.;LINCOLN, STEPH+, J. CHEM. SOC. PT 1. PERKIN TRANS. PT 1,(1990) N, C. 2619-2620
  作者：COATES, JOHN H.、EASTON, CHRISTOPHER J.、VAN, EYK STEPHEN J.、LINCOLN, STEPH+

  DOI：——

  日期：——
• Coates, John H.; Easton, Christopher J.; Eyk, Stephen J. van, Journal of the Chemical Society. Perkin transactions I, 1990, # 9, p. 2619 - 2620
  作者：Coates, John H.、Easton, Christopher J.、Eyk, Stephen J. van、Lincoln, Stephen F.、May, Bruce L.、et al.

  DOI：——

  日期：——
• CYCLODEXTRIN COMPOSITIONS AND METHODS FOR PHARMACEUTICAL AND INDUSTRIAL APPLICATIONS
  申请人：AUSTRALIAN COMMERCIAL RESEARCH & DEVELOPMENT LIMITED

  公开号：EP0518930A1

  公开（公告）日：1992-12-23
• EP0518930A4
  申请人：——

  公开号：EP0518930A4

  公开（公告）日：1993-09-15