2-十二烷基酚 | 5284-29-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 2-十二烷基酚
• 中文别名: 2-十二烷基苯酚；2-N-十二烷基酚
• 英文名称: 2-t-dodecyl-phenol
• 英文别名: o-(1-dodecyl)phenol；2-dodecylphenol；o-dodecylphenol；dodecylphenol；mono-dodecylphenol；2-Dodecyl-phenol
• CAS: 5284-29-7
• 化学式: C₁₈H₃₀O
• 分子量: 262.436
• InChiKey: CYEJMVLDXAUOPN-UHFFFAOYSA-N

物化性质

• 熔点：
  39°C
• 物理描述：
  Straw-colored liquid with a phenolic odor. (USCG, 1999) Dodecylphenol is considered a marine pollutant by the US Department Of Transportation. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Since it is a liquid it can easily penetrate the soil and contaminate groundwater.
• 沸点：
  310 to 335 °F at 760 mm Hg (USCG, 1999)
• 闪点：
  325 °F (USCG, 1999)
• 密度：
  0.94 at 68 °F (USCG, 1999)

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

ADMET

毒理性

• 副作用

Dermatotoxin - 皮肤烧伤。

Dermatotoxin - Skin burns.

来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

安全信息

• 安全说明：
  S26
• 危险类别码：
  R36/37/38
• 海关编码：
  2907199090
• 储存条件：
  存储在室温条件下，并且置于惰性气体中。

SDS

2-Dodecylphenol Revision number: 5
SAFETY DATA SHEET

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Section 1. IDENTIFICATION
Product name: 2-Dodecylphenol

Revision number: 5

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Section 2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS Not classified
HEALTH HAZARDS
Skin corrosion/irritation Category 2
Category 2A
Serious eye damage/eye irritation
ENVIRONMENTAL HAZARDS Not classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Signal word Warning
Hazard statements Causes skin irritation
Causes serious eye irritation
Precautionary statements:
Wash hands thoroughly after handling.
[Prevention]
Wear protective gloves/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
[Response]
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture: Substance
Components: 2-Dodecylphenol
Percent: >98.0%(GC)
CAS Number: 5284-29-7
Synonyms: 2-Laurylphenol
C18H30O
Chemical Formula:

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Section 4. FIRST AID MEASURES
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
2-Dodecylphenol

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Section 4. FIRST AID MEASURES
Skin contact: Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion: Get medical advice/attention if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.

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Section 5. FIRE-FIGHTING MEASURES
Suitable extinguishing Dry chemical, foam, water spray, carbon dioxide.
media:
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protective When extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, Use personal protective equipment. Keep people away from and upwind of spill/leak.
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures: Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a local exhaust if dust or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Storage conditions: Keep container tightly closed. Store in a cool and dark place.
Store away from incompatible materials such as oxidizing agents.
Packaging material: Comply with laws.

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Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Hand protection: Protective gloves.
Safety glasses. A face-shield, if the situation requires.
Eye protection:
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C): Solid
Crystal- Powder
Form:
Colour: White - Almost white
No data available
Odour:
pH: No data available
Melting point/freezing point:46°C
2-Dodecylphenol

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling point/range: No data available
Flash point: No data available
Flammability or explosive
limits:
Lower: No data available
Upper: No data available
Relative density: No data available
Solubility(ies):
[Water] No data available
[Other solvents]
Soluble: Methanol

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Section 10. STABILITY AND REACTIVITY
Chemical stability: Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

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Section 11. TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
Skin corrosion/irritation: No data available
Serious eye No data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC = No data available
No data available
NTP =
Reproductive toxicity: No data available

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Section 12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: No data available
Crustacea: No data available
Algae: No data available
Persistence / degradability: No data available
No data available
Bioaccumulative
potential(BCF):
Mobility in soil
Log Pow: No data available
Soil adsorption (Koc): No data available
Henry's Law No data available
constant(PaM3/mol):

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Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.

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Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not listed
2-Dodecylphenol

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Section 15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

溶于甲醇：几乎透明

反应信息

• 作为反应物：
  描述：

  2-十二烷基酚 在 lead(IV) acetate 、 sodium carbonate 、 对甲苯磺酸 作用下， 以 苯 为溶剂， 反应 20.0h， 生成 4-十八碳烯酸,6-羰基-,甲基酯,(E)-
  参考文献：
  名称：

  Snider, Barry B.; Shi, Zhongping, Journal of the American Chemical Society, 1992, vol. 114, # 5, p. 1790 - 1800

  摘要：

  DOI：
• 作为产物：
  描述：

  2-dodecyl(methoxymethoxy)benzene 在 盐酸 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 16.0h， 以99%的产率得到2-十二烷基酚
  参考文献：
  名称：

  基于Salen的两亲物：通过金属络合物指导水中的自组装。

  摘要：

  调整水中自组装结构的形态是一项重大挑战。本文中，我们介绍了一种基于Salen的两亲物，通过与不同的过渡金属离子的络合，可以有效地控制水中的自组装形态，如通过Cryo-TEM观察并通过DLS测量所证实的。将这种策略与各种金属离子一起使用，可得到从相同的两亲性配体开始的广谱自组装结构（从立方结构到囊泡和胶束）。热重分析和电导率测量揭示了水配位的关键作用，显然是造成不同装配行为的原因。

  DOI：

  10.1002/anie.201908010
• 作为试剂：
  描述：

  苯酚 、 1-十二烯十二碳烯α-十二碳烯α-十二碳烯 在 2-十二烷基酚 作用下， 反应 4.0h， 以537 g of dodecyl phenol was obtained by vacuum distillation的产率得到2-十二烷基酚
  参考文献：
  名称：

  HYDRAULIC FLUID AND HYDRAULIC SYSTEM

  摘要：

  本发明的液压油包含作为基础油的酯类，该酯类具有两个或更多环结构，其中两个或更多环结构至少选择自芳香环和饱和萘环中的一个。特别地，该液压油包含具有两个或更多芳香环的酯类作为基础油。该液压油由于压缩而具有低能量损失，并在液压电路中使用时表现出优异的响应性。因此，该液压油实现了在液压电路中的节能、高速操作和高精度控制。

  公开号：

  US20100130394A1

文献信息

• FUNGICIDAL ISOXAZOLIDINES
  申请人：TSENG CHI-PING

  公开号：US20090270407A1

  公开（公告）日：2009-10-29

  Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, wherein A, B, D, R 1 , R 2 , R 3 , X and m are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

  公开的是Formula 1的化合物，包括所有的几何和立体异构体、N-氧化物和盐， 其中 A、B、D、R 1 、R 2 、R 3 、X和m如披露中所定义。 还公开了含有Formula 1化合物的组合物，以及用于控制由真菌病原体引起的植物疾病的方法，包括施用本发明的化合物或组合物的有效量。
• [EN] FUNGICIDAL PYRIDAZINES<br/>[FR] PYRIDAZINES FONGICIDES
  申请人：DU PONT

  公开号：WO2010036553A1

  公开（公告）日：2010-04-01

  Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, wherein R1, R2, R3, R4, X, Y and m are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

  公开的是Formula 1的化合物，包括所有的几何和立体异构体、N-氧化物和盐，其中R1、R2、R3、R4、X、Y和m如披露中所定义。还公开了含有Formula 1化合物的组合物，以及用于控制由真菌病原体引起的植物疾病的方法，包括施用本发明的化合物或组合物的有效量。
• [EN] ISOXAZOLINE DERIVATIVES AND THEIR USES IN AGRICULTURE<br/>[FR] DÉRIVÉS D'ISOXAZOLINE ET LEURS UTILISATIONS EN AGRICULTURE
  申请人：DONGGUAN HEC PESTICIDES R&D CO LTD

  公开号：WO2021008485A1

  公开（公告）日：2021-01-21

  Provided are isoxazoline derivatives and uses thereof in agriculture; in particular, provided a compound having formula (I), a stereoisomer, an N-oxide or a salt thereof, preparation methods thereof, and compositions containng these compounds and uses thereof in agriculture, particularly uses as active ingredients of herbicide for controlling unwanted plants; wherein R1, R2, R3, R4, n, R5, R6, Ra, Rb, Rc, Rd and Re are defined as described in the invention.

  提供了异噁唑啉衍生物及其在农业中的用途；具体而言，提供了具有化学式（I）的化合物，其立体异构体，N-氧化物或其盐，其制备方法，以及含有这些化合物的组合物和在农业中的用途，特别是作为除草剂的活性成分用于控制不受欢迎的植物；其中R1、R2、R3、R4、n、R5、R6、Ra、Rb、Rc、Rd和Re如本发明所述定义。
• Metal oxide particle and its uses
  申请人：Takeda Mitsuo

  公开号：US20070154561A1

  公开（公告）日：2007-07-05

  An object of the present invention is to provide a metal oxide particle which exercises more excellent ultraviolet absorbency as a matter of course and combines therewith merits of, for example, either being shifted in ultraviolet absorption edge toward the longer wavelength side and being excellent also in the absorption efficiency of a long-wavelength range of ultraviolet rays, or having good transparency and, for example, even in cases where added into or coated onto substrates, not damaging the transparency or hue of the substrates. As a means of achieving this object, a metal oxide particle according to the present invention is a metal oxide particle such that a hetero-element is contained in a particle comprising an oxide of a specific metal element (M), wherein the metal oxide particle is: 1) a metal oxide particle in the form of a fine particle wherein the hetero-element is at least one specific metal element (M′); 2) a metal oxide particle wherein the hetero-element includes at least two specific metal elements (M′); 3) a metal oxide particle wherein: the hetero-element is a more specified metal element (M′) and at least a part thereof is 2 in valence; or the metal element (M) is a more specified metal element and the metal oxide particle is in a specific range in crystal grain diameter in the vertical direction to each of the (002) plane and the (100) plane; or 4) a metal oxide particle wherein: the hetero-element is at least one specific nonmetal element and an acyl group is contained in the particle; or the hetero-element includes at least two specific nonmetal elements; or the hetero-element is at least one specific nonmetal element and a component derived from a metal element (M′) other than the metal element (M) is contained in the particle.

  本发明的目的是提供一种金属氧化物微粒，它自然具有更优异的紫外线吸收性能，并结合了例如向长波长侧移动紫外线吸收边缘且在紫外线长波长范围的吸收效率也极佳的优点，或者具有良好的透明性，例如，即使添加到或涂覆在基材上，也不会损害基材的透明性或色调。为实现这一目的，根据本发明的金属氧化物微粒是一种特定金属元素（M）的氧化物的微粒中包含异元素金属氧化物微粒，其中该金属氧化物微粒是：1）一种微粒形式的细小金属氧化物微粒，其中异元素至少是一种特定金属元素（M′）；2）一种金属氧化物微粒，其中异元素包括至少两种特定金属元素（M′）；3）一种金属氧化物微粒，其中：异元素是一种更特定的金属元素（M′）且至少其部分是二价的；或者金属元素（M）是一种更特定的金属元素，且金属氧化物微粒在垂直于（002）面和（100）面的晶体粒度直径在特定范围内；或者4）一种金属氧化物微粒，其中：异元素至少是一种特定非金属元素，且微粒中包含酰基；或者异元素包括至少两种特定非金属元素；或者异元素至少是一种特定非金属元素，且微粒中包含来自金属元素（M′）以外的金属元素的成分。
• [EN] HERBICIDAL DIHYDRO OXO SIX-MEMBERED AZINYL ISOXAZOLINES<br/>[FR] DIHYDRO OXO AZINYLE ISOXAZOLINES À SIX ÉLÉMENTS HERBICIDES
  申请人：DU PONT

  公开号：WO2009158258A1

  公开（公告）日：2009-12-30

  Disclosed are compounds of Formula (I), including all geometric and stereoisomers, N-oxides, and salts thereof, Formula (I) wherein J is Formula (II) and R1, R2, R3, R4, R5, R6, R7, R8a, R8b, R8c, R8d, Q1, Q2, Q3, Q4, W1, W2, W3, W4, Y1, Y2, Y3, Y4, m and n are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (I) and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

  公开了公式(I)的化合物，包括所有的几何异构体、立体异构体、N-氧化物和它们的盐，公式(I)中J是公式(II)，R1、R2、R3、R4、R5、R6、R7、R8a、R8b、R8c、R8d、Q1、Q2、Q3、Q4、W1、W2、W3、W4、Y1、Y2、Y3、Y4、m和n的定义如披露中所述。还公开了包含公式(I)化合物的组合物，以及控制不需要的植被的方法，该方法包括将不需要的植被或其环境与有效量的本发明的化合物或组合物接触。

表征谱图