2-十四烷基硫烷基丁二酸 | 60713-01-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-十四烷基硫烷基丁二酸
• 英文名称: tetradecylmercapto-succinic acid
• 英文别名: Tetradecylmercapto-bernsteinsaeure；-bernsteinsaeure；S-n-Tetradecylmercaptobernsteinsaeure；S-Tetradecylmercaptobernsteinsaeure；2-Tetradecylsulfanylbutanedioic acid
• CAS: 60713-01-1
• 化学式: C₁₈H₃₄O₄S
• 分子量: 346.532
• InChiKey: AWUNRJFNMPBSLS-UHFFFAOYSA-N

物化性质

• 熔点：
  103-104 °C
• 沸点：
  454.2±35.0 °C(Predicted)
• 密度：
  1.052±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  23
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  99.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-十四烷基硫烷基丁二酸 在 双氧水 作用下， 以 溶剂黄146 为溶剂， 生成 n-Tetradecylsulfonylbernsteinsaeure
  参考文献：
  名称：

  Tanchuk,Yu.V.; Kornienko,A.A., Soviet progress in chemistry, 1976, vol. 42, # 8, p. 49 - 53

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Tetradecylsulfanyl-succinic acid 4-decyl ester 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 生成 2-十四烷基硫烷基丁二酸
  参考文献：
  名称：

  Tanchuk,Yu.V. et al., Soviet progress in chemistry, 1977, vol. 43, # 12, p. 77 - 82

  摘要：

  DOI：

文献信息

• Surface‐active properties and thermal behavior of S‐alkylthio‐carboxylic acids and their potassium salts
  作者：Katsuhisa Kamio、Kohro Kamata、Seiji Mima、Toshiharu Kuroda、Hiroshi Ookawara、Masafumi Moriya、Hisao Hidaka

  DOI：10.1007/bf02541029

  日期：1995.7

  S‐Alkylthiocarboxylic acids and their potassium salts were prepared by photoaddition of α‐olefins (C₁₀, C₁₂, and C₁₄) with mercapto carboxylic acids such as thiomalic acid, thiopropionic acid, and thioglycolic acid. The physicochemical solution properties and thermal stabilities for three series of thiosurfactants were evaluated. S‐Alkylthiocarboxylic acids that contain bridged S‐bonds provide excellent thermally stable surfactants, and their alkaline salts exhibit good surface activity.

  摘要通过α-烯烃（C10、C12 和 C14）与巯基羧酸（如硫代马来酸、硫代丙酸和硫代乙醇酸）的光加成，制备了烷基硫代羧酸及其钾盐。对三个系列的硫代表面活性剂的溶液理化性质和热稳定性进行了评估。含有桥接 S 键的 S-烷基硫代羧酸是热稳定性极佳的表面活性剂，其碱性盐具有良好的表面活性。
• S-Alkylmercaptosuccinic Acids as Solid Derivatives of Olefins, Alkyl Bromides, and Mercaptans
  作者：JOE G. HENDRICKSON、LEWIS F. HATCH

  DOI：10.1021/jo01080a018

  日期：1960.10
• Barry; O'Rourke; Twomey, Proceedings of the Royal Irish Academy. Section B: Biological, geological, and chemical science, 1947, vol. 51 B, p. 225
  作者：Barry、O'Rourke、Twomey

  DOI：——

  日期：——
• TANCHUK YU. V.; KORNIENKO A. A.; SKLYAR V. T., UKR. XIM. ZH., 1977, 43, HO 12, 1308-1313
  作者：TANCHUK YU. V.、 KORNIENKO A. A.、 SKLYAR V. T.

  DOI：——

  日期：——
• Image display medium, process for forming image, and multicolor image-forming apparatus
  申请人：——

  公开号：US20030184644A1

  公开（公告）日：2003-10-02

  An image display medium that includes a photoconductive layer containing a photochromic compound and an electron accepting compound; and a substrate, in which the photochromic compound contains a fulgide compound, and the electron accepting compound contains a compound selected at least from: a) a phosphonic acid compound having an aliphatic group containing 12 or more carbon atoms; b) an aliphatic carboxylic acid compound having an aliphatic group containing 12 or more carbon atoms; and c) a phenolic compound having an aliphatic group containing 12 or more carbon atoms, a process for forming an image using the medium, and a multicolor image-forming apparatus using the medium and suitable for the process.