[3-[3-[(5,5-Dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxy]-2,2-bis[3-[(5,5-dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxymethyl]propyl] 3-[(5,5-dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoate | 1034024-85-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [3-[3-[(5,5-Dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxy]-2,2-bis[3-[(5,5-dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxymethyl]propyl] 3-[(5,5-dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoate
• 英文别名: [3-[3-[(5,5-dimethyl-2-sulfanylidene-1,3,2λ5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxy]-2,2-bis[3-[(5,5-dimethyl-2-sulfanylidene-1,3,2λ5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxymethyl]propyl] 3-[(5,5-dimethyl-2-sulfanylidene-1,3,2λ5-dioxaphosphinan-2-yl)sulfanyl]propanoate
• CAS: 1034024-85-5
• 化学式: C₃₇H₆₄O₁₆P₄S₈
• 分子量: 1145.33
• InChiKey: KIMOOLJAPNSAIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  65
• 可旋转键数：
  28
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  409
• 氢给体数：
  0
• 氢受体数：
  24

反应信息

• 作为产物：
  描述：

  5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane 、 季戊四醇四丙烯酸酯 以 二氯甲烷 为溶剂， 反应 96.0h， 生成 [3-[3-[(5,5-Dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxy]-2,2-bis[3-[(5,5-dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoyloxymethyl]propyl] 3-[(5,5-dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]propanoate
  参考文献：
  名称：

  Phosphorus-sulfur FR additives and polymer systems containing same

  摘要：

  磷硫化合物在有机聚合物系统中具有阻燃活性。磷硫化合物的结构可以表示为：其中X为氧或硫，T为共价键，氧，硫或氮，要求至少X和T中的一个为硫，每个X′独立地为氧或硫，每个m在X′为氧时独立地为零或1，在X′为硫时为零，1或2，n至少为1，最好至少为2，每个R独立地为未取代或惰性取代的烃基，或R基共同形成未取代或惰性取代的二价有机基团，A为有机连接基团。

  公开号：

  US08058332B2

文献信息

• PHOSPHORUS-SULFUR FR ADDITIVES AND POLYMER SYSTEMS CONTAINING SAME
  申请人：Shankar Ravi B.

  公开号：US20110034573A1

  公开（公告）日：2011-02-10

  Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.

  磷硫化合物在有机聚合物系统中具有阻燃活性。磷硫化合物的结构可以表示为：其中X为氧或硫，T为共价键，氧、硫或氮，但至少一个X和T为硫，每个X'独立地为氧或硫，每个m独立地为零或1（当X'为氧时）和零、1或2（当X'为硫时），n至少为1且最好至少为2，每个R独立地为未取代或惰性取代的烃基，或R基共同形成未取代或惰性取代的二价有机基团，A为有机连接基团。
• Phosphorus-sulfur flame retardant additives and polymer systems containing same
  申请人：Dow Global Technologies LLC

  公开号：EP2514788B1

  公开（公告）日：2017-02-01
• US8058332B2
  申请人：——

  公开号：US8058332B2

  公开（公告）日：2011-11-15
• Phosphorus-sulfur FR additives and polymer systems containing same
  申请人：Dow Global Technologies LLC

  公开号：US08058332B2

  公开（公告）日：2011-11-15

  Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.

  磷硫化合物在有机聚合物系统中具有阻燃活性。磷硫化合物的结构可以表示为：其中X为氧或硫，T为共价键，氧，硫或氮，要求至少X和T中的一个为硫，每个X′独立地为氧或硫，每个m在X′为氧时独立地为零或1，在X′为硫时为零，1或2，n至少为1，最好至少为2，每个R独立地为未取代或惰性取代的烃基，或R基共同形成未取代或惰性取代的二价有机基团，A为有机连接基团。