Decahydronaphthalene-1-peroxol | 26447-25-6

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氢过氧化物
• 英文名称: Decahydronaphthalene-1-peroxol
• 英文别名: 1-hydroperoxy-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene
• CAS: 26447-25-6
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.25
• InChiKey: WOUQTOJLBCLQHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Decahydronaphthalene-1-peroxol 生成 十氢萘-1-酚
  参考文献：
  名称：

  KONIG, T.;HABICHER, W. D.;SCHWETLICK, K., J. PRAKT. CHEM., 331,(1989) N, C. 913-922

  摘要：

  DOI：

文献信息

• Unsaturated polyoxyalkylene adduct/fumarate diester reaction product for cellular foam stabilization
  申请人：Sloss Industries Corporation

  公开号：EP0124111A2

  公开（公告）日：1984-11-07

  Polyoxyalkylene surfactants for cellular foams can be prepared by reacting under free radical polymerization conditions (1) an unsaturated polyoxyalkylene adduct and (2) an esterified unsaturated dibasic acid ingredient, wherein unsaturated diester ingredient (2) either completely or partially comprises a fumarate diester.

  用于蜂窝泡沫的聚氧亚烷基表面活性剂可通过在自由基聚合条件下使（1）不饱和聚氧亚烷基加合物和（2）酯化的不饱和二元酸成分反应制备，其中不饱和二元酸成分（2）完全或部分包括富马酸二元酯。
• Vinyl polymer polyols and polyurethane foams made therefrom
  申请人：ARCO CHEMICAL TECHNOLOGY INC.

  公开号：EP0177192A2

  公开（公告）日：1986-04-09

  Polyurethane plastics, including foams, made from polyisocyanates and polymer polyols exhibit enhanced load-bearing properties and reduced polymer loadings when the polymer polyol is a simple polymer polyol prepared by polymerizing at least one vinyl monomer in the presence of an epoxy resin-modified polyol via a free-radical reaction. An especially suitable epoxy resin-modified polyol is one in which an initiator is reacted with an alkylene oxide and epoxy resin in such a way that the epoxy resin is added internally along the length of an alkylene oxide chain.

  用多异氰酸酯和聚合物多元醇制成的聚氨酯塑料（包括泡沫塑料），如果聚合物多元醇是一种简单的聚合物多元醇，其制备方法是在环氧树脂改性多元醇存在的情况下，通过自由基反应聚合至少一种乙烯基单体。一种特别合适的环氧树脂改性多元醇是将引发剂与环氧亚烷基和环氧树脂反应，使环氧树脂沿着环氧亚烷基链的长度在内部加入。
• Thermosetting resin composition
  申请人：Daiso Co., Ltd.

  公开号：EP0295347A1

  公开（公告）日：1988-12-21

  A thermosetting resin composition comprising (A) 60 to 95% by weight of a prepolymer or precopolymer selected from (A-1) a prepolymer of a diallyl phthalate, (A-2) a precopolymer derived from diallyl terephthalate and an aromatic benzyl hydrocarbon having at least one a-hydrogen atom (A-3) a mixture of (A-1) and (A-2), and (B) 40 to 5% by weight of a polyacrylate or polymethacrylate of dipentaerythritol having at least 4 acryloyl or methacryloyl groups in the molecule.

  一种热固性树脂组合物，包括 (A) 以重量计，60%至 95%的预聚物或预聚合物，选自以下物质 (A-1) 邻苯二甲酸二烯丙酯的预聚物、 (A-2) 由对苯二甲酸二烯丙酯和具有至少一个 a-氢原子的芳香族苄基碳氢化合物衍生的预聚物 (A-3) (A-1)和(A-2)的混合物，以及 (B) 40-5%（按重量计）的二季戊四醇聚丙烯酸酯或聚甲基丙烯酸酯，其分子中至少有 4 个丙烯酰基或甲基丙烯酰基。
• An acrylic ester copolymer plastisol composition
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0544201A1

  公开（公告）日：1993-06-02

  An acrylic ester copolymer plastisol composition comprises (A) copolymer particles comprising, as the major components thereof, (a) 98 to 50 weight % of an alkyl acrylate unit having an alkyl group of 1 to 8 carbon atoms and/or an alkyl methacrylate unit having an alkyl group of 1 to 8 carbon atoms and (b) 2 to 50 weight % of a diene monomer unit, (B) a plasticizer and, optionally, (C) a vulcanizing agent. Another acrylic ester copolymer plastisol composition comprises (A) copolymer particles comprising an ionic crosslinked copolymer prepared by ionic crosslinking of a copolymer comprising, as the major components thereof, (a) 97 to 50 weight % of an alkyl acrylate unit having an alkyl group of 1 to 8 carbon atoms and/or an alkyl methacrylate unit having an alkyl group of 1 to 8 carbon atoms, (b) 2 to 40 weight % of a diene monomer unit and (c) 1 to 20 weight % of a radical polymerizable unsaturated carboxylic acid unit of 3 to 8 carbon atoms having a carboxyl group and (B) a plasticizer. The ionic crosslinking is made through the carboxyl group in the copolymer by addition of a monovalent or divalent metal cation. The acrylic ester copolymer plastisol composition has excellent storage stability even when generally used inexpensive plasticizers are used, gives a molded sheet showing no bleeding and generates no toxic gas on heating to a high temperature, on burning or in case of fire.

  一种丙烯酸酯共聚物塑料溶胶组合物包括(A)共聚物颗粒，其主要成分为(a)98-50 重量％的具有 1-8 个碳原子烷基的丙烯酸烷基酯单元和/或具有 1-8 个碳原子烷基的甲基丙烯酸烷基酯单元，以及(b)2-50 重量％的二烯单体单元，(B)增塑剂，以及可选的(C)硫化剂。另一种丙烯酸酯共聚物塑料溶胶组合物包括 (A) 共聚物颗粒，该共聚物颗粒由离子交联共聚物制备而成，离子交联共聚物的 主要成分包括(a) 97 至 50 重量％的具有 1 至 8 个碳原子烷基的丙烯酸烷基酯单元和/或具有 1 至 8 个碳原子烷基的甲基丙烯酸烷基酯单元；(b) 2 至 40 重量％的二烯单体单元；(c) 1 至 20 重量％的具有 3 至 8 个碳原子羧基的可自由基聚合的不饱和羧酸单元；以及 (B) 增塑剂。离子交联是通过共聚物中的羧基加入一价或二价金属阳离子实现的。这种丙烯酸酯共聚物塑料溶胶组合物即使使用一般的廉价增塑剂，也具有极佳的贮存稳定性，成型后的板材不渗色，在加热到高温、燃烧或着火时也不会产生有毒气体。
• Foamable silicone rubber composition
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0704475A2

  公开（公告）日：1996-04-03

  This composition comprises (A) an organopolysiloxane having at least two SiOH groups in its molecule, (B) an organopolysiloxane having at least two SiH groups in its molecule, (C) a platinum family metal catalyst, and (D) a hydroperoxide. By using the hydroperoxide as a catalyst-retarding agent in cure reaction of a dehydrogenation system in which hydrogen is a foaming agent, this composition has a long pot life and can be cured and foamed to produce a foamed cured product in the form of a sponge having uniform cells.

  这种组合物包括：(A) 分子中至少有两个 SiOH 基团的有机聚硅氧烷；(B) 分子中至少有两个 SiH 基团的有机聚硅氧烷；(C) 铂族金属催化剂；(D) 过氧化氢。在以氢气为发泡剂的脱氢体系的固化反应中，使用过氧化氢作为催化剂缓凝剂，这种组合物具有较长的固化寿命，可以固化和发泡，生产出具有均匀细胞的海绵状发泡固化产品。