acrylic acid-(2,2,3,3-tetrafluoro-3-trifluoromethoxy-propyl ester) | 356-71-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acrylic acid-(2,2,3,3-tetrafluoro-3-trifluoromethoxy-propyl ester)
• 英文别名: Acrylsaeure-(2,2,3,3-tetrafluor-3-trifluormethoxy-propylester)；3-Acryloyloxy-1,1,2,2-tetrafluor-1-trifluormethoxy-propan；Acrylic acid 2,2,3,3-tetrafluoro-3-(trifluoromethoxy)propyl ester；[2,2,3,3-tetrafluoro-3-(trifluoromethoxy)propyl] prop-2-enoate
• CAS: 356-71-8
• 化学式: C₇H₅F₇O₃
• 分子量: 270.104
• InChiKey: LDGUDDRJNBKFHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  丙烯酸 在 对苯二酚 、 三氟乙酸酐 作用下， 生成 acrylic acid-(2,2,3,3-tetrafluoro-3-trifluoromethoxy-propyl ester)
  参考文献：
  名称：

  Fluorinated acrylates and polymers

  摘要：

  公开号：

  US02826564A1

文献信息

• DEVICE AND METHOD FOR SOLUBILIZING, SEPARATING, REMOVING AND REACTING CARBOXYLIC ACIDS IN OILS, FATS, AQUEOUS OR ORGANIC SOLUTIONS BY MEANS OF MICRO-OR NANOEMULSIFICATION
  申请人：Dietz Ulrich

  公开号：US20130090488A1

  公开（公告）日：2013-04-11

  The present invention is directed to solubilizing compounds, a device and a method for solubilizing and removing carboxylic acids and especially fatty acids from oils, fats, aqueous emulsion, aqueous media and organic solutions. Devices utilizing the inventive method shall be used for separating carboxylic acids from oils, fats, aqueous emulsion, lipophilic media or organic solutions, respectively by preparing an aqueous micro- or nanoemulsion of the carboxylic acids especially the fatty acids and the solubilizing compound which contains at least one amidino and/or gianidino group. Solubilization effects of solubilizing compounds combined with the inventive use of separation methods for carboxylic acids can be used to treat persons in need of removal of fatty acids or analyze carboxylic acids from blood or process other solutions in food, pharmacy, chemistry, bio fuel industry or other industrial processings.

  本发明涉及溶解化合物、用于从油、脂肪、水乳液、水介质和有机溶液中溶解和去除羧酸，特别是脂肪酸的装置和方法。采用本发明方法的装置将用于通过制备羧酸特别是脂肪酸和含有至少一种氨基甲酰基和/或肼基团的溶解化合物的水微观或纳米乳液，分离油、脂肪、水乳液、亲脂性介质或有机溶液中的羧酸。溶解化合物的溶解效果与本发明所述的羧酸分离方法相结合，可用于治疗需要去除脂肪酸或从血液中分析羧酸或处理食品、药品、化学、生物燃料工业或其他工业加工过程中的其他溶液的人员。
• Fluorine-containing graft copolymer and adhesive and composite membrane made thereof
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0183989A2

  公开（公告）日：1986-06-11

  A graft copolymer consisting essentially of a main chain polymer having a glass transition temperature (Tg) of at least 30°C and a graft chain fluorine-containing polymer having a repeating unit of the formula: wherein R1 is a hydrogen atom or a lower alkyl group, and R2 is a polyfluoroalkyl group.

  一种接枝共聚物，主要由玻璃化转变温度（Tg）至少为 30°C 的主链聚合物和具有以下重复单元的接枝链含氟聚合物组成： 其中 R1 为氢原子或低级烷基，R2 为多氟烷基。
• Preparation method of comb copolymer, acrylic comb copolymer, and impact resistant resin composition
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0357036A2

  公开（公告）日：1990-03-07

  A comb copolymer consisting of a methacrylic macromonomer as a branch ingredient and acrylic ester as a backbone ingredient and being suitable for an acrylic elastomer material which is excellent in trans­parency, weatherability and mechanical strenth; an impact resistant acrylic resin composition obtained by blending the above comb copolymer with a PMMA (co)polymer; and a comb copolymer similarly consisting of a methacrylic macromonomer as a branch component and acrylic ester as a backbone component and being an acrylic resin which is excellent in transparency, weatherability, gloss and light resistance, are dis­closed in this invention. Preparation methods of the high molecular weight comb compolymers useful for molding materials comprising the above mentioned comb copolymers are disclosed. The disclosed preparation methods comprise, in the copolymerization of the macromonomer having a vinyl group at one end of the main chain with a vinyl monomer, conducting aqueous suspension polymerization of the monomer mixture in the presence of an initiator in a solvent which is a good solvent for the macromono­mer and has a solubility of 10% by weight or more in water at 30°C, or conducting aqueous suspension poly­ merization of the monomer mixture in the presence of an initiator in a halogenated hydrocarbon solvent which is a good solvent for the macromonomer and has an azeo­tropic point with water raning from 30 to 90°C at a temperature above said azeotropic point.

  一种由甲基丙烯酸大单体作为支链成分和丙烯酸酯作为主链成分组成的梳状共聚物，适用于透明性、耐候性和机械强度优异的丙烯酸弹性体材料；一种通过将上述梳状共聚物与 PMMA（共）聚合物混合而获得的抗冲击丙烯酸树脂组合物；以及一种同样由甲基丙烯酸大单体作为支链组分、丙烯酸酯作为主链组分组成的梳状共聚物，它是一种在透明度、耐候性、光泽度和耐光性方面都非常出色的丙烯酸树脂。 本发明公开了高分子量梳状共聚物的制备方法，这种高分子量梳状共聚物可用于由上述梳状共聚物组成的成型材料。所公开的制备方法包括：在主链一端带有乙烯基的大单体与乙烯基单体的共聚过程中，在引发剂的存在下，在对大单体而言是良好溶剂且在 30°C 时在水中的溶解度为 10%（重量）或以上的溶剂中对单体混合物进行水悬浮聚合、或在有引发剂存在的情况下，在卤代烃溶剂中对单体混合物进行水悬浮聚合，该卤代烃溶剂是大单体的良好溶剂，在 30 至 90°C 之间与水有共沸点，温度高于所述共沸点。
• Acrylic comb copolymer, and impact resistant resin composition
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0612774A2

  公开（公告）日：1994-08-31

  A comb copolymer consisting of a methacrylic macromonomer as a branch ingredient and acrylic ester as a backbone ingredient and being suitable for an acrylic elastomer material which is excellent in transparency, weatherability and mechanical strength; and an impact resistant acrylic resin composition obtained by blending the above comb copolymer with a PMMA (co)polymer; are disclosed in this invention.

  本发明公开了一种由甲基丙烯酸大单体作为支链成分、丙烯酸酯作为主链成分组成的梳状共聚物，适用于透明性、耐候性和机械强度优异的丙烯酸弹性体材料；以及通过将上述梳状共聚物与 PMMA（共）聚合物混合而获得的抗冲击丙烯酸树脂组合物。
• Device and method for solubilizing, separating, removing and reacting carboxylic acids in aqueous or organic solutions by means of micro- or nanoemulsification
  申请人：Dietz, Ulrich

  公开号：EP2399885A1

  公开（公告）日：2011-12-28

  The invention is related to the emulsification effects achiveable by arginine and arginine analogues on carboxylic acids in aqueous and organic media and the use of these effects to solubilize, separate and remove carboxylic acids as well as increasing physical or chemical interactions and reactions. Furthermore, the invention is directed to the nanoemulsifying properties of arginine and arginine analogues on carboxlic acids and poorly soluble molecules. Solubilization effects of arginine and arginine analogues combined with the inventive use of separation methods for carboxylic acids can be used to treat persons in need of removal of fatty acids or analyze carboxylic acids from blood or process other solutions in food, pharmacy, chemistry or other industrial processings. The inventive effects of arginine and arginine analogues enable the use of methods for nano-filtration of carboxylic acids. Moreover, the use of arginine and arginine anlogues as well as carboxylic acids used to functionalize the interface of micro- and nanofluidic separation media including hydro- or organogels by means of surface functionalization, adsorption or incorporation enables the use of electrophoretic and nanofiltration techniques to be applied on carboxylic acids.

  本发明涉及精氨酸和精氨酸类似物在水性和有机介质中对羧酸的乳化作用，以及利用这些作用来增溶、分离和去除羧酸以及增加物理或化学相互作用和反应。此外，本发明还涉及精氨酸和精氨酸类似物对羧酸和难溶分子的纳米乳化特性。精氨酸和精氨酸类似物的增溶作用与羧酸分离方法的创造性使用相结合，可用于治疗需要去除脂肪酸的人，或分析血液中的羧酸，或处理食品、制药、化学或其他工业加工中的其他溶液。精氨酸和精氨酸类似物的创造性作用使得纳米过滤羧酸的方法得以使用。此外，使用精氨酸和精氨酸类似物以及羧酸，通过表面官能化、吸附或结合的方式，使包括水凝胶或有机凝胶在内的微流体和纳米流体分离介质的界面功能化，可将电泳和纳滤技术应用于羧酸。