环己基乙烯基氨基甲酸酯 | 15896-09-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 环己基乙烯基氨基甲酸酯
• 英文名称: Cyclohexyl vinylcarbamate
• 英文别名: cyclohexyl N-ethenylcarbamate
• CAS: 15896-09-0
• 化学式: C₉H₁₅NO₂
• 分子量: 169.22
• InChiKey: KEBIPYRRRTZHIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  异氰酸乙烯酯 、 、 环己醇 以 乙酸乙酯 为溶剂， 反应 3.0h， 生成 环己基乙烯基氨基甲酸酯
  参考文献：
  名称：

  Surface-coating binders which contain blocked isocyanate groups and are

  摘要：

  基于含有三级胺基、阻塞异氰酸酯基、羟基和醚基的共聚物的表面涂层粘合剂，由于与酸部分或完全盐化，具有水溶性或水分散性。共聚物包含共聚单元，包括具有三级胺基的烯烃未饱和化合物，一种N-(烷基-1-烯基)异氰酸酯，使用CH-、OH-或NH-酸性阻塞剂阻塞，以及基于双酚A和环氧氯丙烷的环氧树脂的加成物，分子量为380至3,500，与具有3至20个碳原子的烯烃未饱和醇和具有3至20个碳原子的烯烃未饱和羧酸共聚，并且可以带或不带一个或多个其他共聚性烯烃未饱和化合物，平均分子量为1,000至20,000。这种新型表面涂层粘合剂可用于金属制品的阴极电泳涂装，既可作为自交联粘合剂，也可作为需要外部交联剂的粘合剂。

  公开号：

  US04461880A1

文献信息

• Surface-coating binders containing blocked isocyanate groups, and their
  申请人：BASF Aktiengesellschaft

  公开号：US04399256A1

  公开（公告）日：1983-08-16

  Surface-coating binders based on a copolymer which contains tertiary amino groups, blocked isocyanate groups, hydroxyl groups and ether groups and which, due to partial or complete salification with an acid, is water-soluble or water-dispersible. This copolymer contains, as copolymerized units, one or more olefinically unsaturated compounds possessing a tertiary amino group, an N-(1-alkenyl) isocyanate blocked with a CH--, OH-- or NH-acidic blocking agent, an adduct of an epoxy resin based on bisphenol A and epichlorohydrin, and having a molecular weight of from 380 to 3,500, with an olefinically unsaturated alcohol of 3 to 20 carbon atoms, and one or more other copolymerizable olefinically unsaturated compounds, and has a mean molecular weight of from 1,000 to 20,000. The novel surface-coating binder is used for the cathodic electrocoating of metallic articles.

  基于含有三级胺基、封闭异氰酸酯基、羟基和醚基的共聚物的表面涂层粘合剂，由于与酸的部分或完全盐化，该共聚物是水溶性或水分散性。该共聚物包含共聚单元，其中至少包含一种具有三级胺基的烯烃不饱和化合物，一种以CH--、OH--或NH-酸性阻滞剂阻滞的N-(1-烯基)异氰酸酯，一种基于双酚A和环氧氯丙烷的环氧树脂的加成物，其分子量为380至3,500，与3至20个碳原子的烯烃不饱和醇和一种或多种其他可共聚的烯烃不饱和化合物。该共聚物的平均分子量为1,000至20,000。这种新型的表面涂层粘合剂用于金属制品的阴极电泳涂装。
• Surface coating binder containing blocked isocyanate groups
  申请人：Basf Aktiengesellschaft

  公开号：US04530978A1

  公开（公告）日：1985-07-23

  Surface coating binders which contain tertiary amino groups, blocked isocyanate groups, hydroxyl groups and ether groups and are water-soluble or water-dispersible as a result of partial or complete salt formation with an acid are prepared by copolymerization of a mixture comprising (A) an olefinically unsaturated compound which contains a tertiary amino group, (B) an N-(1-alkenyl)-isocyanate which is blocked with a CH-, OH- or NH-acidic blocking agent and (C) an adduct of an epoxy resin based on bisphenol A and epichlorohydrin, and an olefinically unsaturated carboxylic acid of 3 to 20 carbon atoms, a secondary amine and, if required, a saturated monocarboxylic acid of 1 to 20 carbon atoms, with or without one or more copolymerizable, olefinically unsaturated compounds not mentioned under (A), (B) and (C). These surface coating binders are particularly useful as self-crosslinking or externally crosslinking binders for the cathodic electrocoating of metal articles.

  含有第三级胺基，被阻断的异氰酸酯基团，羟基和醚基的表面涂层粘合剂，由混合物共聚制备而成。该混合物包括（A）含有第三级胺基的烯丙基不饱和化合物，（B）被CH-，OH-或NH-酸性阻断剂阻断的N-（1-烯基）-异氰酸酯和（C）基于双酚A和环氧氯丙烷的环氧树脂的加成物，以及具有3至20个碳原子的烯丙基羧酸，二级胺和如有需要的1至20个碳原子的饱和一元羧酸的烯丙基不饱和羧酸，以及一个或多个未在（A），（B）和（C）下提到的共聚性烯丙基不饱和化合物，通过与酸部分或完全盐形成而成为水溶性或水分散性。这些表面涂层粘合剂特别适用于金属制品的阴极电泳自交联或外交联粘合剂。
• Surface-coating binders and their use for electrocoating finishes
  申请人：BASF Aktiengesellschaft

  公开号：US04310398A1

  公开（公告）日：1982-01-12

  Surface-coating binders based on a copolymer which contains tertiary amino groups and blocked isocyanate groups and is water-soluble or water-dispersible as a result of being at least partially salified with an acid. The copolymer contains, as copolymerized units, an olefinically unsaturated compound which possesses a tertiary amino group, an N-(1-alkenyl)-isocyanate which is blocked with a CH-, OH- or NH-acidic blocking agent, and another olefinically unsaturated compound, with or without one or more copolymerizable olefinically unsaturated compounds which possess hydrogen atoms which are reactive toward isocyanate groups, and has a mean molecular weight of from 1,000 to 20,000. The novel surface-coating binders are used for the cathodic electrocoating of metallic articles.

  基于共聚物的表面涂层粘合剂，其中包含三级胺基和阻塞异氰酸酯基团，并且由于至少部分与酸盐化而成为水溶性或水分散性。共聚物包含共聚单元，其中包括具有三级胺基的烯烃未饱和化合物，被CH-，OH-或NH-酸性阻断剂阻断的N-(1-烯丙基)-异氰酸酯以及另一个烯烃未饱和化合物，带或不带一个或多个共聚能与异氰酸酯基团反应的氢原子的未饱和化合物，其平均分子量为1,000至20,000。新型表面涂层粘合剂用于金属制品的阴极电泳涂装。
• Copolymers containing blocked isocyanate groups, and their use in anodic
  申请人：BASF Aktiengesellschaft

  公开号：US04336346A1

  公开（公告）日：1982-06-22

  Surface-coating binders based on a copolymer which contains carboxyl groups, blocked isocyanate groups, hydroxyl groups and ether groups, and which, due to partial or complete salification with ammonia or with an organic base, is water-soluble or water-dispersible. This copolymer contains, as copolymerized units, one or more .alpha.,.beta.-olefinically unsaturated carboxylic acids of 3 to 5 carbon atoms or one or more half-esters of an .alpha.,.beta.-olefinically unsaturated dicarboxylic acid of 3 to 5 carbon atoms, an N-(1-alkenyl) isocyanate blocked with a CH--, OH-- or NH-acidic blocking agent, an adduct of an epoxy resin, based on bisphenol A and epichlorohydrin and having a molecular weight of from 380 to 3,500, with an olefinically unsaturated alcohol of 3 to 20 carbon atoms, and one or more other copolymerizable olefinically unsaturated compounds, and has a mean molecular weight of from 1,000 to 20,000 and an acid number of from 35 to 150 mg of KOH/g. The novel surface-coating binder is useful for the anodic electrocoating of metallic articles.

  基于含有羧基、阻塞异氰酸酯基、羟基和醚基的共聚物的表面涂层粘合剂，由于与氨或有机碱部分或完全盐化，因此具有水溶性或水分散性。该共聚物包含作为共聚单元的1个或多个α，β-烯丙基不饱和羧酸，其碳原子数为3到5个，或1个或多个3到5个碳原子的α，β-烯丙基不饱和二羧酸的半酯，一种N-(1-烯基)异氰酸酯，其与CH-，OH-或NH-酸性阻断剂阻断，基于双酚A和环氧氯丙烷的环氧树脂加和物，分子量为380到3,500，与3到20个碳原子的烯丙基醇，以及1个或多个其他可共聚的烯丙基不饱和化合物。该共聚物的平均分子量为1,000到20,000，酸价为35到150mg KOH/g。该新型表面涂层粘合剂适用于金属制品的阳极电泳涂装。
• US4310398A
  申请人：——

  公开号：US4310398A

  公开（公告）日：1982-01-12