1,3-bis(2,2-diphenylethenyl)-9-propyl-2-propoxycarbazole | 1219943-26-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,3-bis(2,2-diphenylethenyl)-9-propyl-2-propoxycarbazole
• 英文别名: 1,3-bis(2,2-diphenylethenyl)-9-propyl-2-propoxycarbazol；1,3-Bis(2,2-diphenylethenyl)-2-propoxy-9-propylcarbazole；1,3-bis(2,2-diphenylethenyl)-2-propoxy-9-propylcarbazole
• CAS: 1219943-26-6
• 化学式: C₄₆H₄₁NO
• 分子量: 623.838
• InChiKey: HKIQTEAVSDNYKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  48
• 可旋转键数：
  11
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  14.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,3-bis(2,2-diphenylethenyl)-9-propyl-2-propoxycarbazole 在 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 生成 1,3-bis(2,2-diphenylethenyl)-6-(1,1-diphenylhydrazon-2-yl)-9-propyl-2-propoxycarbazole
  参考文献：
  名称：

  1,3-Bisdiphenylethenyl-substituted Carbazolyl Derivatives as Charge Transporting Materials

  摘要：

  报告了基于1,3-二苯乙烯基咔唑的电荷传输材料的合成，这些材料涉及电子给体醛肟部分和一个电子受体的1,3-偶氮烷酮部分。所获得的材料通过各种技术进行了检测，包括差示扫描量热法（DSC）、紫外可见光谱法、静电喷墨时间飞行技术和空气中的电子光发射法。所研究化合物的非晶薄膜的光发射光谱显示出离子化势为5.54–5.90 eV。通过静电喷墨时间飞行技术测量了孔漂移迁移率。对于在聚合物基质双酚-Z聚碳酸酯（PC-Z）中分子掺杂N,N-二苯肼酮部分的1,3-二苯乙烯基咔唑衍生物，观察到在6.4 × 10^5 V/cm电场下，孔漂移迁移率超过10−5 cm^2/V·s的最高值。

  DOI：

  10.3390/molecules171214846
• 作为产物：
  描述：

  联苯乙醛 在 左旋樟脑磺酸 、 potassium hydroxide 作用下， 以 1,4-二氧六环 、 甲苯 为溶剂， 反应 2.33h， 生成 1,3-bis(2,2-diphenylethenyl)-9-propyl-2-propoxycarbazole
  参考文献：
  名称：

  1,3-Bisdiphenylethenyl-substituted Carbazolyl Derivatives as Charge Transporting Materials

  摘要：

  报告了基于1,3-二苯乙烯基咔唑的电荷传输材料的合成，这些材料涉及电子给体醛肟部分和一个电子受体的1,3-偶氮烷酮部分。所获得的材料通过各种技术进行了检测，包括差示扫描量热法（DSC）、紫外可见光谱法、静电喷墨时间飞行技术和空气中的电子光发射法。所研究化合物的非晶薄膜的光发射光谱显示出离子化势为5.54–5.90 eV。通过静电喷墨时间飞行技术测量了孔漂移迁移率。对于在聚合物基质双酚-Z聚碳酸酯（PC-Z）中分子掺杂N,N-二苯肼酮部分的1,3-二苯乙烯基咔唑衍生物，观察到在6.4 × 10^5 V/cm电场下，孔漂移迁移率超过10−5 cm^2/V·s的最高值。

  DOI：

  10.3390/molecules171214846

文献信息

• Easily functionalizable carbazole based building blocks with extended conjugated systems for optoelectronic applications
  作者：Giedre Bubniene、Tadas Malinauskas、Maryte Daskeviciene、Vygintas Jankauskas、Vytautas Getautis

  DOI：10.1016/j.tet.2010.02.086

  日期：2010.4

  Carbazole based building blocks, possessing diphenylethenyl fragments, have been synthesized. Condensation of the carbazol-2-ol with diphenylacetaldehyde yields 1,3-substituted derivatives. Change of the synthesis sequence, however, (i.e., substitution at the hydroxyl and NH groups, followed by the condensation reaction) results in the 3,6-substituted products. Thermal, optical, electro-chemical and photophysical properties of the synthesized derivatives have been investigated. Room temperature hole-drift mobilities, evaluated using xerographic time-of-flight technique, were found to exceed 10(-4) cm(2) V-1 s(-1) at strong electric fields. The obtained results indicate high charge mobility for molecularly doped polymers, especially considering the fact that these measurements were carried out under ambient conditions and not in high vacuum. Commercial availability and relative cheapness of the starting materials, simple synthetic method, number of sites available for easy functionalization and covalent linking to other molecules makes these precursors attractive building blocks for the construction of more complex low-molecular-weight or polymeric materials for optoelectronic applications. (C) 2010 Elsevier Ltd. All rights reserved.
• 1,3-Bisdiphenylethenyl-substituted Carbazolyl Derivatives as Charge Transporting Materials
  作者：Giedre Bubniene、Maryte Daskeviciene、Audrius Pukalskas、Vygintas Jankauskas、Vytautas Getautis

  DOI：10.3390/molecules171214846

  日期：——

  Synthesis of 1,3-diphenylethenylcarbazolyl-based charge transporting materials involving electron donating hydrazone moieties and an electron withdrawing 1,3-indandione moiety is reported. The obtained materials were examined by various techniques, including differential scanning calorimetry, UV-Vis spectroscopy, xerographic time of flight technique and the electron photoemission in air method. Photoemission spectra of the amorphous films of the investigated compounds showed ionization potentials of 5.54–5.90 eV. The hole drift mobility was measured by the xerographic time of flight technique. The highest hole drift mobility, exceeding 10−5 cm2/V·s at 6.4 × 105 V/cm electric field, was observed for the 1,3-diphenylethenylcarbazolyl derivative molecularly doped with a N,N-diphenylhydrazone moiety in the polymeric host bisphenol-Z polycarbonate (PC-Z).

  报告了基于1,3-二苯乙烯基咔唑的电荷传输材料的合成，这些材料涉及电子给体醛肟部分和一个电子受体的1,3-偶氮烷酮部分。所获得的材料通过各种技术进行了检测，包括差示扫描量热法（DSC）、紫外可见光谱法、静电喷墨时间飞行技术和空气中的电子光发射法。所研究化合物的非晶薄膜的光发射光谱显示出离子化势为5.54–5.90 eV。通过静电喷墨时间飞行技术测量了孔漂移迁移率。对于在聚合物基质双酚-Z聚碳酸酯（PC-Z）中分子掺杂N,N-二苯肼酮部分的1,3-二苯乙烯基咔唑衍生物，观察到在6.4 × 10^5 V/cm电场下，孔漂移迁移率超过10−5 cm^2/V·s的最高值。