Hexacosane-1-thiol | 66575-55-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: Hexacosane-1-thiol
• CAS: 66575-55-1
• 化学式: C₂₆H₅₄S
• 分子量: 398.8
• InChiKey: XPBKZLKKMZSNNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.7
• 重原子数：
  27
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Organic Semiconductor Material
  申请人：Miyata Yasuo

  公开号：US20110087034A1

  公开（公告）日：2011-04-14

  A dihydroindacene compound represented by the following formula (1): wherein R 1 is identical or different from each other, and each denotes a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, alkynyl which may be substituted, alkoxy which may be substituted, alkylthio which may be substituted, aryl which may be substituted, aryloxy which may be substituted, or the like; R 2 to R 5 are identical or different from each other, and each denote a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, or the like; p is 0, 1, or 2; and ring structures A and B are identical or different from each other, and each denote a benzene ring which may be substituted, a thiophene ring which may be substituted, or the like.

  一种二氢吲哚嗪化合物，其由以下式（1）表示：其中R1彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基、可被取代的炔基、可被取代的烷氧基、可被取代的烷硫基、可被取代的芳基、可被取代的芳氧基等；R2至R5彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基等；p为0、1或2；环结构A和B彼此相同或不同，各自表示可被取代的苯环、可被取代的噻吩环等。
• NOVEL COMPOUND AND ORGANIC SEMICONDUCTOR MATERIAL
  申请人：Miyata Yasuo

  公开号：US20110166362A1

  公开（公告）日：2011-07-07

  Discloses is a compound represented by the formula (1): wherein a ring structure A and a ring structure B independently represent an aromatic ring which may be substituted, or a heterocyclic ring which may be substituted; a ring structure C represents a benzene ring which may be substituted, a hetero[3,2-b]heterole ring, or a benzo[1,2-b:4,5-b′]diheterole ring which may be substituted; W, X, Y and Z independently represent a sulfur atom, an oxygen atom, a selenium atom, a tellurium atom, SO 2 , (R 1 )—C—(R 2 ), (R 2 )—Si—(R 4 ), or N—(R 5 ), and at least one of W, X, Y and Z is N—(R 5 ); R 1 , R 2 , R 3 , R 4 and R 5 independently represent a hydrogen atom, a substituent i, a substituent ii, an aryl group which may be substituted with halogen, or a heteroaryl group which may be substituted with halogen, the substituent i is a group selected from Group P shown below, the substituent ii is a group selected from Group P shown below which group is substituted, and Group P consists of an alkyl group, an alkoxy group, an alkyl-substituted aryl group, an alkoxy-substituted aryl group, and an alkyl-substituted heteroaryl group.

  Discloses是一种由公式（1）表示的化合物： 其中，环结构A和环结构B分别表示可以被取代的芳香环或杂环；环结构C表示可以被取代的苯环、杂[3,2-b]杂环或可以被取代的苯并[1,2-b:4,5-b′]二杂环；W，X，Y和Z分别表示硫原子、氧原子、硒原子、碲原子、SO2、(R1)-C-(R2)、(R2)-Si-(R4)或N-(R5)，并且W，X，Y和Z中至少有一个是N-(R5)；R1，R2，R3，R4和R5分别表示氢原子、取代基i、取代基ii、可以被卤素取代的芳基或可以被卤素取代的杂芳基，其中取代基i是从下面所示的P组中选择的一组取代基，取代基ii是从下面所示的P组中选择的一组取代基，该组取代基被取代，P组包括烷基、烷氧基、烷基取代的芳基、烷氧基取代的芳基和烷基取代的杂芳基。
• ORGANIC SEMICONDUCTOR MATERIAL
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2248818A1

  公开（公告）日：2010-11-10

  A dihydroindacene compound represented by the following formula (1): wherein R1 is identical or different from each other, and each denotes a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, alkynyl which may be substituted, alkoxy which may be substituted, alkylthio which may be substituted, aryl which may be substituted, aryloxy which may be substituted, or the like; R2 to R5 are identical or different from each other, and each denote a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, or the like; p is 0, 1, or 2; and ring structures A and B are identical or different from each other, and each denote a benzene ring which may be substituted, a thiophene ring which may be substituted, or the like.

  下式(1)代表的二氢茚化合物： 其中 R1 彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基、可被取代的炔基、可被取代的烷氧基、可被取代的烷硫基、可被取代的芳基、可被取代的芳氧基或类似物；R2 至 R5 彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基或类似物； p 为 0、1 或 2；以及 环结构 A 和 B 彼此相同或不同，各自表示可被取代的苯环、可被取代的噻吩环或类似环。
• Polymer parts
  申请人：Sony DADC Austria AG

  公开号：EP2792471A1

  公开（公告）日：2014-10-22

  A method of producing a polymer part comprising the following steps: (a) incorporating a hydrophobic small molecule into the polymer before, during or after manufacture of the polymer part, the hydrophobic small molecule and the polymer being essentially inert to one another; and (b) annealing the polymer part to induce migration of the hydrophobic small molecules to a surface of the polymer part to provide that surface with a specified degree of hydrophobicity defined by the combination of the polymer and the hydrophobic small molecule; is described. Polymer parts made according to the method are also described.

  一种生产聚合物部件的方法，包括以下步骤：(a) 在制造聚合物部件之前、期间或之后，将疏水性小分子掺入聚合物中，疏水性小分子和聚合物基本上互为惰性；以及 (b) 对聚合物部件进行退火处理，促使疏水性小分子迁移到聚合物部件的表面，使该表面具有由聚合物和疏水性小分子的组合确定的特定疏水性。还描述了根据该方法制造的聚合物部件。
• METAL COMPLEX DYE, PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, DYE SOLUTION, AND COMPOUND
  申请人：Fujifilm Corporation

  公开号：EP2793311A1

  公开（公告）日：2014-10-22

  A photoelectric conversion element, having: an electrically-conductive support; a photoconductor layer having a layer of semiconductor fine-particles that have adsorbed a dye; a charge transfer layer containing an electrolyte; and a counter electrode; which are provided on one side of the electrically-conductive support in this order, wherein the dye has at least one terdentate ligand having at least one acidic group; at least one ligand coordinating to a metal atom M has an sp2 carbon atom; a cyclic group binds to the sp2 carbon atom; in a circle position connecting through a carbon atom(s) from an atom of the cyclic group directly binding to the sp2 carbon atom, a substituent R is substituted at an atom of an α-position or β-position to the atom of the cyclic group directly binding to the sp2 carbon atom, with the substituent R being selected from a linear or branched alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an amino group, an alkylamino group, a cycloalkylamino group, an arylamino group, a heterocyclic amino group, a silyl group, or a silyloxy group; and when the atom of the α-position or β-position to which the substituent R binds is defined as G1 and an atom of the substituent R which directly binds to the atom G1 is defined as G2, an angle θ (∠MG1G2) formed by the metal atom M, the atom G1 and the atom G2, which is centered on the atom G1, is 150° or less, a dye-sensitized solar cell, a metal complex dye, a dye solution containing the dye and a compound useful as a ligand of the dye.

  一种光电转换元件，具有 导电支架 光电导体层，该层具有一层吸附了染料的半导体微粒； 含有电解质的电荷转移层；以及 一个对电极； 它们依次设置在导电支架的一侧、 其中，染料具有至少一个三齿配体，该配体具有至少一个酸性基团；至少一个配体与具有 sp2 碳原子的金属原子 M 配位；一个环状基团与 sp2 碳原子结合；在通过碳原子与直接结合到 sp2 碳原子的环状基团的原子相连的圆周位置上，在与直接结合到 sp2 碳原子的环状基团的原子处于 α 位或 β 位的原子上取代取代基 R，取代基 R 选自直链或支链烷基、环烷基、烷氧基、环烷氧基、芳氧基、烷硫基、环烷硫基、芳硫基、氨基、烷基氨基、环烷基氨基、芳基氨基、杂环氨基、硅烷基或硅烷氧基；当取代基 R 与之结合的 α 位或 β 位原子被定义为 G1，而取代基 R 直接与原子 G1 结合的原子被定义为 G2 时，金属原子 M 与原子 G1 形成的角度θ (∠MG1G2)、以原子 G1 为中心，由金属原子 M、原子 G1 和原子 G2 形成的角度θ (∠MG1G2)为 150°或更小。