2-(methacrylamido)ethyl-2-bromoisobutyrate | 869065-99-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(methacrylamido)ethyl-2-bromoisobutyrate
• 英文别名: 2-(2-Methylprop-2-enoylamino)ethyl 2-bromo-2-methylpropanoate
• CAS: 869065-99-6
• 化学式: C₁₀H₁₆BrNO₃
• 分子量: 278.146
• InChiKey: YSBINTLZFWUZAS-UHFFFAOYSA-N

物化性质

• 沸点：
  397.0±38.0 °C(Predicted)
• 密度：
  1.317±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-溴-2-甲基丙酰溴 、 N-(2-羟乙基)-2-甲基-2-丙烯酰胺 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 46.0h， 以85%的产率得到2-(methacrylamido)ethyl-2-bromoisobutyrate
  参考文献：
  名称：

  由于与环糊精发生超分子相互作用，导致聚甲基丙烯酰胺具有不寻常的溶解性。

  摘要：

  DOI：

  10.1002/anie.200501374

文献信息

• NOVEL COPOLYMER, NOVEL COPOLYMER-CONTAINING COMPOSITION, LAMINATE BODY, METHOD OF PRODUCING METAL FILM-COATED MATERIAL, METAL FILM-COATED MATERIAL, METHOD OF PRODUCING METALLIC PATTERN-BEARING MATERIAL AND METALLIC PATTERN-BEARING MATERIAL
  申请人：KANO Takeyoshi

  公开号：US20100247880A1

  公开（公告）日：2010-09-30

  There is provided a polymer containing a unit represented by the following Formula (1), and a unit represented by following Formula (2). In Formula (1) and Formula (2), R 1 to R 5 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group; R 6 represents an unsubstituted alkyl group, alkenyl group, alkynyl group or an aryl group; V and Z each independently represent a single bond, a substituted or unsubstituted divalent organic group, an ester group, an amide group or an ether group, and L 1 and L 2 each independently represent a substituted or unsubstituted divalent organic group.

  提供了一种聚合物，其中包含由以下公式（1）表示的单元和由以下公式（2）表示的单元。在公式（1）和公式（2）中，R1到R5分别独立表示氢原子，取代或未取代的烷基基团；R6表示未取代的烷基基团，烯基基团，炔基基团或芳基基团；V和Z分别独立表示单键，取代或未取代的二价有机基团，酯基团，酰胺基团或醚基团，并且L1和L2分别独立表示取代或未取代的二价有机基团。
• Nitrile group-containing polymer and method of synthesizing the same, composition containing nitrile group-containing polymer, and laminate
  申请人：FUJIFILM Corporation

  公开号：EP2105451B1

  公开（公告）日：2012-02-15
• Method of manufacturing surface metal film material, surface metal film material, method of manufacturing patterned metal material, patterned metal material, and polymer layer-forming composition
  申请人：Nagasaki Hideo

  公开号：US20090155553A1

  公开（公告）日：2009-06-18

  The present invention provides a method of manufacturing capable of readily obtaining a surface metal film material that has excellent adhesiveness of a metal film, reduced variability of adhesion due to humidity changes and excellent heat resistance and flexibility, and a method of manufacturing capable of readily obtaining a patterned metal material excellent in insulation reliability of a region where a patterned metal is not formed, and excellent in heat resistance and flexibility. A method of manufacturing a surface metal film material includes: forming a polymer layer including a polymer that has a cyano group and that chemically bonds directly with a polyimide film, on the polyimide film; imparting a plating catalyst or a precursor thereof to the polymer layer; and performing a plating process on the plating catalyst or the precursor thereof, and a method of manufacturing a patterned metal material including etching a pattern in a plating film of a surface metal film material obtained according to the method of manufacturing a surface metal film material.
• METAL-FILM-COATED MATERIAL AND PROCESS FOR PRODUCING THE SAME, METALLIC-PATTERN-BEARING MATERIAL AND PROCESS FOR PRODUCING THE SAME, COMPOSITION FOR POLYMER LAYER FORMATION, NITRILE GROUP-CONTAINING POLYMER AND METHOD OF SYNTHESIZING THE SAME, COMPOSITION CONTAINING NITRILE GROUP-CONTAINING POLYMER, AND LAMINATE
  申请人：Kano Takeyoshi

  公开号：US20090214876A1

  公开（公告）日：2009-08-27

  A process for producing a metal film-coated material, the process including: (a1) forming, on a substrate, a polymer layer formed from a polymer which has a functional group capable of interacting with a plating catalyst or a precursor thereof, and is directly chemically bonded to the substrate; (a2) providing a plating catalyst or a precursor thereof to the polymer layer; and (a3) performing plating with respect to the plating catalyst or a precursor thereof. The polymer layer satisfies all of the following requirements (1) to (4): (1) the saturated water absorption coefficient of the polymer layer as measured in an environment of temperature of 25° C. and relative humidity of 50% is 0.01 to 10% by mass; (2) the saturated water absorption coefficient of the polymer layer as measured in an environment of temperature of 25° C. and relative humidity of 95% is 0.05 to 20% by mass; (3) the water absorption coefficient of the polymer layer as measured after 1 hour of immersion in boiling water at 100° C. is 0.1 to 30% by mass; and (4) the surface contact angle of the polymer layer as measured after dropping 5 μL of distilled water thereonto and leaving to stand for 15 seconds in an environment of temperature of 25° C. and relative humidity of 50% is 50 to 150 degrees.
• COMPOSITION FOR FORMING LAYER TO BE PLATED, METHOD OF PRODUCING METAL PATTERN MATERIAL, METAL PATTERN MATERIAL
  申请人：KANO Takeyoshi

  公开号：US20100080964A1

  公开（公告）日：2010-04-01

  A composition including a polymer, the polymer having a non-dissociative functional group that interacts with a plating catalyst or a precursor thereof, a radical polymerizable group, and an ionic polar group; a method of producing a metal pattern material using the same: and a metal pattern material produced by the method.