2-己基癸烷-1-醇,甲磺酸 | 111360-16-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 中文名称: 2-己基癸烷-1-醇,甲磺酸
• 英文名称: 2-hexyldecyl methanesulfonate
• 英文别名: 2-Hexyldecyl mesylate
• CAS: 111360-16-8
• 化学式: C₁₇H₃₆O₃S
• 分子量: 320.537
• InChiKey: XZGFCPHKLRQESC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  21
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-己基癸烷-1-醇,甲磺酸 在 正丁基锂 、 四丁基溴化铵 、 sodium hydroxide 、 锌 作用下， 以 四氢呋喃 、 正己烷 、 水 为溶剂， 反应 2.5h， 生成 2,6-bis(trimethyltin)-4,8-di(2-hexyl)decyloxybenzo[1,2-b;3,4-b′]-dithiophene
  参考文献：
  名称：

  新型4,8-苯并双噻唑共聚物及其场效应晶体管和光伏应用

  摘要：

  一系列含有苯并[1,2- d：4,5- d的共聚物']双（噻唑）（BBT）单元已与联噻吩基-二酮吡咯并吡咯（DPP），二噻吩并吡咯（DTP），苯并噻二唑（BT），苯并二噻吩（BDT）或4,4'-二烷氧基比噻唑（BTz）共聚单体进行设计和合成。所得的聚合物具有与通过BBT单元的2，6-位的更常见的取代途径正交的共轭途径，从而促进相邻单体单元的策略性放置的杂原子之间的分子内非共价相互作用。这种相互作用使得能够通过改变平面度的数量和强度来控制平面度，进而允许调整带隙。所得的4,8-BBT材料在p型有机场效应晶体管中的迁移率高达2.16×10 -2 cm 2 V -1š -1为pDPP2ThBBT和最多为4.45％的功率转换效率的良好的太阳能电池的性能pBT2ThBBT。

  DOI：

  10.1039/c7tc03959j
• 作为产物：
  描述：

  2-己基癸醇 生成 2-己基癸烷-1-醇,甲磺酸
  参考文献：
  名称：

  ICHIJIMA, SEIJI;SHIMADA, YASUHIRO;ARAKAWA, JUN

  摘要：

  DOI：

文献信息

• COMPOSITIONS AND METHODS FOR DELIVERING MESSENGER RNA
  申请人：PROTIVA BIOTHERAPEUTICS, INC.

  公开号：US20160151284A1

  公开（公告）日：2016-06-02

  The present invention provides compositions comprising mRNA molecules encapsulated within lipid particles. The lipid particles comprise a cationic lipid, a non-cationic lipid, and an mRNA molecule that is encapsulated within the lipid particle. The compositions are useful, for example, to introduce the mRNA molecules into a human subject where they are translated to produce a polypeptide that functions to ameliorate one or more symptoms of a disease. The invention also provides cationic lipids that are useful for preparing the compositions of the invention.

  本发明提供了包含mRNA分子封装在脂质颗粒内的组合物。脂质颗粒包括一个阳离子脂质、一个非阳离子脂质和一个被封装在脂质颗粒内的mRNA分子。这些组合物可用于将mRNA分子引入人体受试者，从而产生一个多肽，其功能是改善一种或多种疾病症状。本发明还提供了用于制备上述组合物的阳离子脂质。
• Silver halide color photographic material containing a novel cyan
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US05094938A1

  公开（公告）日：1992-03-10

  There is disclosed a silver halide color photographic material having a silver halide emulsion layer on a base which comprises a novel cyan coupler. According to the disclosure, a silver halide color photographic material containing a cyan coupler that has high coupling reactivity and high color density, resulting color image being hardly susceptible to reduction fading and is excellent in heat fast can be obtained.

  本发明公开了一种银卤素彩色摄影材料，其在基材上具有银卤素乳剂层，其中包括一种新型的青色偶联剂。根据本发明，可以获得一种含有高偶联反应性和高色密度的青色偶联剂的银卤素彩色摄影材料，其生成的彩色图像不易受还原褪色影响，且在耐热性方面表现优异。
• Silver halide colour photographic material and cyan coupler of the 2-phenylureido-5-acylaminophenol type
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0423764A2

  公开（公告）日：1991-04-24

  There is disclosed a silver halide color photographic material having a silver halide emulsion layer on a base which comprises a novel cyan coupler. According to the disclosure, a silver halide color photographic material containing a cyan coupler that has high coupling reactivity and high color density, resulting color image being hardly susceptible to reduction fading and is excellent in heat fast can be obtained.

  本发明公开了一种卤化银彩色感光材料，该材料在包含新型青色耦合剂的基底上具有卤化银乳剂层。根据本发明，可以获得一种含有青色耦合剂的卤化银彩色感光材料，它具有高耦合反应活性和高色彩密度，所产生的彩色图像几乎不易还原褪色，而且耐热性能极佳。
• Synthesis of diketopyrrolopyrrole (DPP) derivatives comprising bithiophene moieties
  作者：Sara Stas、Sergey Sergeyev、Yves Geerts

  DOI：10.1016/j.tet.2010.01.027

  日期：2010.3

  Herein we disclose an easily applicable method for the synthesis of diketopyrrolopyrrole (DPP) derivatives comprising bithiophene moieties, with different substituents on the nitrogen atoms (Me, n-octyl, 3,5-di-tert-butylbenzyl, Boc) and on the thiophene rings (C6H13, C12H25), in good yields and purities. A comparison is made between the previously described method from literature and our more efficient approach regarding number of steps, overall yields and ease of synthesis and purification. (C) 2010 Elsevier Ltd. All rights reserved.
• Fluorinated Benzothiadiazole-Based Conjugated Polymers for High-Performance Polymer Solar Cells without Any Processing Additives or Post-treatments
  作者：Ning Wang、Zheng Chen、Wei Wei、Zhenhua Jiang

  DOI：10.1021/ja409881g

  日期：2013.11.13

  Thanks to their many favorable advantages, polymer solar cells exhibit great potential for next-generation clean energy sources. Herein, we have successfully designed and synthesized a series of new fluorinated benzothiadiazole-based conjugated copolymers PBDTTEH-DT(H)BTff (P1), PBDTTEH-DT(EH)BTff (P2), and PBDTHDO-DT(H)BTff (P3). The power conversion efficiencies of 4.46, 6.20, and 8.30% were achieved for P1-, P2-, and P3-based devices within similar to 100 nm thickness active layers under AM 1.5G illumination without any processing additives or post-treatments, respectively. The PCE of 8.30% for P3 is the highest value for the reported traditional single-junction polymer solar cells via a simple fabrication architecture without any additives or post-treatments. In addition, it is noteworthy that P3 also allows making high efficient polymer solar cells with high PCEs of 7.27 and 6.56% under the same condition for similar to 200 and similar to 300 nm thickness active layers, respectively. Excellent photoelectric properties and good solubility make polymer P3 become an alternative material for high-performance polymer solar cells.