申请人:ETHYL PETROLEUM ADDITIVES, INC.
公开号:EP0531000A1
公开(公告)日:1993-03-10
Additive concentrates and lubricant compositions containing a combination of additives which result in enhanced performance particularly as regards extreme pressure and antiwear performance. The combination of additives so utilized comprise
a-1) at least one oil-soluble additive composition formed by heating concurrently or in any sequence at least one ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group with (i) at least one inorganic phosphorus acid or anhydride, or at least one partial or total sulfur analog thereof, or any combination of the foregoing, and (ii) at least one boron compound; such that a liquid composition is formed; or
a-2) at least one oil-soluble boron-free additive composition formed by heating (i) at least one boron-free oil-soluble ashless dispersant containing basic nitrogen and/or at least one hydroxyl group, with (ii) at least one inorganic phosphorus acid such that a liquid boron-free phosphorus-containing composition is formed; or a-3) one or more oil-soluble additive compositions formed by heating concurrently or in any sequence at least one ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group with (i) at least one water-hydrolyzable organic phosphorus compound and water; and (ii) at least one boron compound; such that a liquid phosphorus- and boron-containing composition is formed; or a-4) one or more oil-soluble boron-free additive compositions formed by heating concurrently or in any sequence (i) at least one boron-free oil-soluble ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group, with (ii) -at least one water-hydrolyzable organic phosphorus compound and water; such that a liquid boron-free phosphorus-containing composition is formed; and
b) at least one oil-soluble metal-free sulfur-containing antiwear and/or extreme pressure agent having a sulfur content of at least 20% by weight; components a-1), a-2), a-3) or a-4) and b) being proportioned such that the mass ratio (wt:wt) of sulfur in component b) to phosphorus in component a-1), a-2), a-3) or a-4) is in the range of 8:1 to 30:1.
添加剂浓缩物和润滑剂组合物含有添加剂组合,可提高性能,特别是在极压和抗磨损性能方面。添加剂组合包括
a-1) 至少一种油溶性添加剂组合物,通过同时或任意顺序加热至少一种含碱式氮和/或至少一个羟基的无灰分散剂与(i) 至少一种无机磷酸或磷酸酐,或至少一种其部分或全部硫类似物,或上述物质的任意组合,以及(ii) 至少一种硼化合物,从而形成液体组合物;或
a-2) 至少一种油溶性无硼添加剂组合物,通过加热 (i) 至少一种含碱式氮和/或至少一个羟基的无硼油溶性无灰分散剂,与 (ii) 至少一种无机磷酸,从而形成液态无硼含磷组合物;或 a-3) 一种或多种油溶性添加剂组合物,通过同时或任意顺序加热至少一种含 碱式氮和/或至少一个羟基的无灰分散剂与(i)至少一种可水解的有机磷化 合物和水;和(ii) 至少一种硼化合物;从而形成一种液态含磷和硼的组合物;或 a-4) 一种或多种油溶性无硼添加剂组合物,通过同时或任意顺序加热(i) 至少一种含碱性氮和/或至少一种羟基的无硼油溶性无灰分散剂与(ii) 至少一种可水解的有机磷化合物和水;从而形成一种液态无硼含磷组合物;及
b) 至少一种油溶性无金属含硫抗磨剂和/或极压剂,其硫含量至少为 20%(重量比);组分 a-1)、a-2)、a-3)或 a-4) 和 b) 的比例为:组分 b) 中硫与组分 a-1)、a-2)、a-3)或 a-4) 中磷的质量比(重量比)在 8:1 至 30:1 之间。