9,10-C2B9H11 | 45839-61-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 9,10-C2B9H11
• 英文别名: 7,8-nido-C2B9H11
• CAS: 45839-61-0
• 化学式: C₂H₁₁B₉
• 分子量: 132.408
• InChiKey: HBKGEAOSLKEWSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  9,10-C2B9H11 在 水 作用下， 生成 、 硼酸
  参考文献：
  名称：

  Garrett, Philip M.; George, T. Adrian; Hawthorne, M. Fredrick, Inorganic Chemistry, 1969, vol. 8, # 9, p. 2008 - 2009

  摘要：

  DOI：
• 作为产物：
  描述：

  bis[π-(3)-1,2-dicarbollyl]nickel(IV) 以 neat (no solvent, gas phase) 为溶剂， 生成 9,10-C2B9H11
  参考文献：
  名称：

  Inner-shell excitation of boranes and carboranes

  摘要：

  Oscillator strengths for B 1s excitation of two borane cage compounds [nido-pentaborane(9) (B5H9) and nido-decaborane(14) (B10H14)] and for B 1s and C 1s excitation of three carborane cage compounds [closo-o-carborane (C2B10H12), nido-2,3-diethyl-2,3-dicarbahexaborane [(C2H5)2C2B4H6], and 1,2-dicarbaundecaborane(11) (C2B9H11)] have been derived from inner-shell electron energy loss spectra (ISEELS), recorded under electric dipole scattering conditions. The spectral features have been assigned on the basis of spectral comparisons and of the results of semiempirical (MNDO and extended Huckel) molecular orbital calculations. The 1,2-dicarbaundecaborane species was generated in situ by thermal decomposition of the bis(nido-1,2-dicarbaundecaborane)nickel species. The preservation of the nido form of the ligand after decomposition is deduced from the experimental B 1s and C 1s spectra.

  DOI：

  10.1021/j100133a010

文献信息

• Potential application of metallacarboranes as an internal reference: an electrochemical comparative study to ferrocene
  作者：Jewel Ann Maria Xavier、Clara Viñas、Encarnación Lorenzo、Tania García-Mendiola、Francesc Teixidor

  DOI：10.1039/d2cc00424k

  日期：——

  Ferrocene and its derivatives have been extensively used as an internal reference in electrochemical processes. Yet, they possess limitations such as solvent restrictions that require chemical modifications. In this regard, we have studied the use of metallacarboranes [3,3′-M(1,2-C2B9H11)2]− (M = Co, Fe) as general internal reference systems and have proven their suitability by thoroughly investigating

  二茂铁及其衍生物已被广泛用作电化学过程的内部参考。然而，它们具有限制，例如需要化学修饰的溶剂限制。在这方面，我们研究了金属碳硼烷 [3,3'-M(1,2-C 2 B 9 H 11 ) 2 ] - (M = Co, Fe) 作为一般内部参考系统的用途，并证明了它们的适用性通过彻底研究它们在水性和有机电解质中的电化学性质，无需任何衍生。
• Carbon Extrusion in 1,2-Dicarba-<i>closo</i>-dodecaboranes: Regioselective Boron Substitution in Ten-Vertex<i>closo</i>-Monocarbaborane Anions
  作者：Anna Laromaine、Francesc Teixidor、Clara Viñas

  DOI：10.1002/anie.200462209

  日期：2005.4.8
• Reactions involving the undecahydro-7,9-dicarba-nido-undecaborate(2-) ion. Insertion, oxidative closure, and addition
  作者：Vinay. Chowdry、W. R. Pretzer、D. N. Rai、R. W. Rudolph

  DOI：10.1021/ja00795a017

  日期：1973.7
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.6, 2.2.2.4, page 29 - 31
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.2, 4.2, page 162 - 164
  作者：

  DOI：——

  日期：——