9,10-bis(4-cyanophenyl)anthracene | 99372-96-0

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9,10-bis(4-cyanophenyl)anthracene
• 英文别名: 4-[10-(4-cyanophenyl)anthracen-9-yl]benzonitrile
• CAS: 99372-96-0
• 化学式: C₂₈H₁₆N₂
• 分子量: 380.448
• InChiKey: DSPGMQPXTWKKKG-UHFFFAOYSA-N

物化性质

• 熔点：
  230 °C
• 沸点：
  571.4±50.0 °C(Predicted)
• 密度：
  1.28±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-bis(4-cyanophenyl)anthracene 在 氧气 、 亚甲兰 作用下， 以 二氯甲烷 为溶剂， 20.0 ℃ 、101.33 kPa 条件下， 生成 9,10-bis(4-cyanophenyl)-9,10-dihydro-9,10-epidioxidoanthracene
  参考文献：
  名称：

  Remote substituent effects on the photooxygenation of 9,10-diarylanthracenes: strong evidence for polar intermediates

  摘要：

  在 9,10-二芳基蒽的光氧合反应中发现了两种不同的反应途径，极性（前向，单线态氧加成）和自由基（后向，热分解）中间体的证据确凿。

  DOI：

  10.1039/b719637g
• 作为产物：
  描述：

  9,10-bis(4-cyanophenyl)-9,10-dihydro-9,10-epidioxidoanthracene 以 邻二甲苯 为溶剂， 生成 9,10-bis(4-cyanophenyl)anthracene
  参考文献：
  名称：

  Remote substituent effects on the photooxygenation of 9,10-diarylanthracenes: strong evidence for polar intermediates

  摘要：

  在 9,10-二芳基蒽的光氧合反应中发现了两种不同的反应途径，极性（前向，单线态氧加成）和自由基（后向，热分解）中间体的证据确凿。

  DOI：

  10.1039/b719637g

文献信息

• ORGANIC LIGHT EMITTING ELEMENT, DISPLAY DEVICE, IMAGE INFORMATION PROCESSING DEVICE, LIGHTING DEVICE, IMAGE FORMING DEVICE, EXPOSURE DEVICE, AND ORGANIC PHOTOELECTRIC CONVERSION ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170012215A1

  公开（公告）日：2017-01-12

  The present disclosure provides an organic light emitting element which has a pair of electrodes and an organic compound layer disposed therebetween and in which the organic compound layer contains an organic compound represented by the following general formula [1], wherein in the formula [1], Ar 1 and Ar 2 each independently represent an aromatic hydrocarbon group or a heteroaromatic ring group, R 1 to R 4 are each independently selected from a hydrogen atom or a substituent, R 1 and R 2 and R 3 and R 4 each may form a benzene ring, wherein the benzene ring may have at least one substituent.

  本公开提供了一种有一对电极和位于其之间的有机化合物层的有机发光元件，其中所述有机化合物层包含由下述通用式[1]表示的有机化合物， 在通用式[1]中，Ar1和Ar2分别独立表示芳香烃基或杂芳环基，R1至R4分别独立地选自氢原子或取代基，R1和R2以及R3和R4各自可以形成苯环，其中苯环可以具有至少一个取代基。
• Synthesis of Symmetrical and Unsymmetrical 9,10-Diarylanthracene Derivatives via Bis-Suzuki-Miyaura Cross-Coupling Reaction
  作者：Sambasivarao Kotha、Arun Kumar Ghosh、Kodand Dinkar Deodhar

  DOI：10.1055/s-2004-815981

  日期：——

  Synthesis of various 9,10-diarylanthracene derivatives via bis-Suzuki-Miyaura cross-coupling reaction as a key step is described. Availability of the 9,10-dithienylanthracenes derivatives where the thiophene unit is present in the molecule (e. g. 11, 12, 14) may provide an easy access to novel polymer and/or dendrimer preparation. In addition, we have synthesized unsymmetrical 9,10-diarylanthracene derivatives 20-25 by the Suzuki-Miyaura cross-coupling reaction, which are difficult to prepare by other transition metal-catalyzed cross-coupling reactions.

  描述了通过双-Suzuki-Miyaura交叉偶联反应作为关键步骤合成各种9,10-二芳基蒽衍生物。分子中存在噻吩单元的9，10-二噻吩基蒽衍生物(例如11、12、14)的可用性可以提供一种容易获得新型聚合物和/或树枝状聚合物的制备方法。此外，我们还通过Suzuki-Miyaura交叉偶联反应合成了其他过渡金属催化交叉偶联反应难以制备的不对称9,10-二芳基蒽衍生物20-25。
• 2,2′-bibenzo[D]imidazolidene compound having heteromonocyclic groups at the 1-, 1′-, 3- and 3′- positions, and organic light-emitting element and display device containing the same
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10193084B2

  公开（公告）日：2019-01-29

  A 2,2′-bibenzo[d]imidazolidene compound expressed by the following general formula (1). In general formula (1), Ar1 to Ar4 each represent a substituted or unsubstituted heteromonocyclic group. R1 to R8 each represent a hydrogen atom or a substituent.

  由以下通式（1）表示的 2，2′-联苯并[d]咪唑烷化合物。在通式（1）中，Ar1 至 Ar4 各自代表一个取代或未取代的杂环基团。R1 至 R8 各自代表氢原子或取代基。
• 2,2′-bibenzo[D]imidazolidene compound having condensed rings at the 1-, 1′-, 3- and 3′-positions, and organic light-emitting element, display device, image information processing apparatus, lighting device, image forming apparatus and exposure unit, each containing the same
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10403827B2

  公开（公告）日：2019-09-03

  A stable 2,2′-bibenzo[d]imidazolidene compound is provided. The 2,2′-bibenzo[d]imidazolidene compound is expressed by the following General Formula (1). In General Formula (1), Ar1 to Ar8 each represent a substituted or unsubstituted condensed ring. R1 to R8 each represent a hydrogen atom or a substituent.

  提供了一种稳定的 2,2′-联苯并[d]咪唑烷化合物。2,2′-联苯并[d]咪唑烷化合物由以下通式（1）表示。在通式（1）中，Ar1 至 Ar8 各自代表一个取代或未取代的缩合环。R1 至 R8 各代表一个氢原子或一个取代基。
• Azoline ring-containing compound, electron transport/injection layer material containing the same, and organic electroluminescent element using the same
  申请人：JNC CORPORATION

  公开号：US11342511B2

  公开（公告）日：2022-05-24

  An object is to provide an azoline ring-containing compound which achieves characteristics required for an organic EL element, such as a driving voltage, a quantum efficiency, and element lifetime in a well-balanced manner, and particularly can obtain a high quantum efficiency, for example, in a case where the azoline ring-containing compound is used for the organic EL element. The above object is achieved by an azoline ring-containing compound represented by the following general formula (1). In formula (1), φ represents an m-valent group derived from an aromatic hydrocarbon having 6 to 40 carbon atoms or the like, Y represents —O—, —S—, or >N—Ar, R1 to R5 each represent a hydrogen atom or an alkyl having 1 to 4 carbon atoms, and L represents a phenylene group or the like.

  目的是提供一种含氮啉环的化合物，它能以平衡的方式实现有机电致发光元件所需的特性，如驱动电压、量子效率和元件寿命，尤其是在将含氮啉环的化合物用于有机电致发光元件的情况下，可以获得较高的量子效率。由以下通式（1）表示的含唑啉环化合物可实现上述目标。 在式 (1) 中，φ 代表衍生自具有 6 至 40 个碳原子的芳香烃或类似物的 m 价基团，Y 代表 -O-、-S- 或 >N-Ar，R1 至 R5 各代表氢原子或具有 1 至 4 个碳原子的烷基，L 代表亚苯基或类似物。