N,N'-bis(3-aminopropyl)diethylenetriamine | 58214-71-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis(3-aminopropyl)diethylenetriamine
• 英文别名: 1,5,8,11,15-Pentaazapentadecane；N'-[2-[2-(3-aminopropylamino)ethylamino]ethyl]propane-1,3-diamine
• CAS: 58214-71-4
• 化学式: C₁₀H₂₇N₅
• 分子量: 217.358
• InChiKey: MLEFOTHMNWIYGG-UHFFFAOYSA-N

物化性质

• 沸点：
  348.9±10.0 °C(Predicted)
• 密度：
  0.955±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -2.2
• 重原子数：
  15
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  88.1
• 氢给体数：
  5
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  丙烯腈 、 二乙烯三胺 在 lithium hydroxide monohydrate 、 氢气 作用下， 以 水 、 异丙醇 为溶剂， 70.0~145.0 ℃ 、5.62 MPa 条件下， 反应 4.67h， 生成 N,N'-bis(3-aminopropyl)diethylenetriamine 、 N'-[2-(2-氨基乙胺基)乙基]丙烷-1,3-二胺 、 N,N',N''-tris(3-aminopropyl)diethylenetriamine 、 N,N-bis(3-aminopropyl)diethylenetriamine 、 N-3-aminopropyl-[N'-3-[N-3-aminopropyl]aminopropyl]diethylenetriamine 、 N,N,N'-tris(3-aminopropyl)diethylenetriamine
  参考文献：
  名称：

  [EN] AMIDOAMINE AND POLYAMIDE CURING AGENTS, COMPOSITIONS, AND METHODS
  [FR] AGENTS, COMPOSITIONS ET PROCÉDÉS DE DURCISSEMENT D'AMIDOAMINE ET DE POLYAMIDES

  摘要：

  本发明涉及一种包括肽胺固化剂组合物或聚酰胺固化剂组合物的组成物。该组合物包括以下反应产物：(1)胺组分，包括至少一种结构为(I)的多功能胺，其中每个R独立地为H或CH2CH2CH2NH2; R1为H、CH3CH2CH2N-、C1-C21烷基或C1-C21烯基; n为2; m为1或2；(2)脂肪酸或酯组分，选自二聚脂肪酸或酯组分、单功能脂肪酸或酯组分及其组合物。该肽胺固化剂组合物在常温下仍保持液态。

  公开号：

  WO2017136333A1

文献信息

• BENZYLATED MANNICH BASE CURING AGENTS, COMPOSITIONS, AND METHODS
  申请人：EVONIK DEGUSSA GMBH

  公开号：US20170240691A1

  公开（公告）日：2017-08-24

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R 1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R 2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein R A is substituted or unsubstituted benzyl; R B is each independently R A , or a hydrogen atom, or a group selected from C 1 -C 16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C 2 -C 10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

  含有苄基曼尼希碱基组分的组合物和固化剂。所述苄基曼尼希碱基组分包括以下反应产物：(a)至少具有一个取代基的取代酚化合物，所述取代基的公式为(I)：其中R1各自独立地是具有1到4个碳原子的线性或支链烷基，R2是氢、甲基、乙基或苯基；(b)苄基化的聚烯烃聚醚胺(II)：其中RA是取代或未取代的苄基，RB各自独立地是RA或氢原子，或选自C1-C16线性、环状和支链烷基、烯基和烷基芳基基团；X、Y和Z各自独立地选自C2-C10烷基和环状烷基基团；y是0到7的整数，z是0到4的整数；可选地，(c)多功能胺。还公开了胺-环氧组合物和由这些组合物制成的物品。
• Organosilane Coating Compositions and Use Thereof
  申请人：Colreavy John

  公开号：US20100330380A1

  公开（公告）日：2010-12-30

  A sol-gel coating composition comprising a hydrolysed organosilane, an organometallic precursor and a corrosion inhibitor, wherein the corrosion inhibitor is a chelator for the organometallic precursor. The corrosion inhibitor and the organometallic precursor may form a nanoparticulate complex. The coating composition may comprise one or more additive selected from: an antimicrobial additive, a hardener, a water repelling additive, a dye, a scratch resistant additive and a flexibility enhancing additive. A process for preparing a sol gel coating composition is also described, the process comprising the steps of: hydrolysing an organosilane in the presence of a catalyst; chelating an organometallic precursor; mixing the hydrolysed silane and the chelated organometallic precursor; and hydrolysing the organosilane-organometallic precursor mixture.

  一种溶胶-凝胶涂层组合物，包括水解的有机硅烷、有机金属前体和腐蚀抑制剂，其中腐蚀抑制剂是有机金属前体的螯合剂。腐蚀抑制剂和有机金属前体可以形成纳米颗粒复合物。涂层组合物可以包括以下一种或多种添加剂：抗菌添加剂、硬化剂、防水添加剂、染料、耐刮擦添加剂和增强柔韧性添加剂。还描述了一种制备溶胶-凝胶涂层组合物的方法，包括以下步骤：在催化剂存在下水解有机硅烷；螯合有机金属前体；混合水解硅烷和螯合有机金属前体；以及水解有机硅烷-有机金属前体混合物。
• Benzylated mannich base curing agents, compositions, and methods
  申请人：Evonik Operations GmbH

  公开号：US10669370B2

  公开（公告）日：2020-06-02

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein RA is substituted or unsubstituted benzyl; RB is each independently RA, or a hydrogen atom, or a group selected from C1-C16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C2-C10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

  包含苄化曼尼希基组合物的组合物和固化剂。苄化曼尼希基组合物包括以下物质的反应产物：(a) 具有至少一个式 (I) 取代基的取代酚化合物： 其中 R1 各自独立地为具有 1 至 4 个碳原子的直链或支链烷基，R2 为氢、甲基、乙基或苯基，与(b)苄化聚亚烷基多胺(II)的反应产物： 其中 RA 是取代或未取代的苄基；RB 各自独立地是 RA，或氢原子，或选自 C1-C16 直链、环链和支链烷基、烯基和芳烷基的基团；X、Y 和 Z 独立地选自 C2-C10 亚烷基和环亚烷基；y 是 0 至 7 的整数，z 是 0 至 4 的整数；以及，任选地，(c) 多官能胺。此外，还公开了胺环氧组合物和由这些组合物生产的物品。
• Aldehyde scavengers mixtures for polyurethane foams
  申请人：Evonik Operations GmbH

  公开号：US10696777B2

  公开（公告）日：2020-06-30

  A polyurethane composition comprising a mixture comprising at least two aldehyde scavengers, a polyurethane product, and a process for making polyurethane foam are disclosed. The mixture of scavenger compounds can reduce, if not eliminate, the emissions of aldehydes from polyurethane foams. The scavenger compounds comprise at least one member selected from the group consisting of: phenol or substituted phenol, a 1,3-dicarbonyl compound, a polyamine bearing a 1,3-propanediamino function, melamine, a 1,2-diaminocycloalkane, an ammonium salt, and aminosiloxane.

  本发明公开了一种由至少两种醛清除剂混合物组成的聚氨酯组合物、一种聚氨酯产品和一种制造聚氨酯泡沫塑料的工艺。清除剂化合物混合物可以减少甚至消除聚氨酯泡沫的醛排放。清除剂化合物包括至少一种选自以下组别的成员：苯酚或取代苯酚、1,3-二羰基化合物、具有 1,3-丙二氨基功能的多胺、三聚氰胺、1,2-二氨基环烷、铵盐和氨基硅氧烷。
• Amidoamine and polyamide curing agents, compositions, and methods
  申请人：Evonik Operations GmbH

  公开号：US10676564B2

  公开（公告）日：2020-06-09

  A composition including an amidoamine curing agent composition or a polyamide curing agent composition are disclosed. The composition includes the reaction products of (1) an amine component including at least one multifunctional amine of structure (I): wherein each R is independently H or CH2CH2CH2NH2; R1 is H, CH3CH2CH2N—, C1-C21 alkyl, or C1-C21 alkenyl; n is 2; and m is 1 or 2, with (2) a fatty acid or ester component selected from the group consisting of a dimer fatty acid or ester component, a monofunctional fatty acid or ester component, and combinations thereof. The amidoamine curing agent composition remains as liquid at ambient temperature.

  本发明公开了一种包括氨基胺固化剂组合物或聚酰胺固化剂组合物的组合物。该组合物包括以下物质的反应产物：(1) 包括至少一种结构(I)的多功能胺的胺组分： 其中每个 R 独立地为 H 或 CH2CH2CH2NH2；R1 为 H、CH3CH2CH2N-、C1-C21 烷基或 C1-C21 烯基；n 为 2；m 为 1 或 2，与(2)选自由二聚脂肪酸或酯类组分、单官能脂肪酸或酯类组分及其组合组成的组的脂肪酸或酯类组分。氨基胺固化剂组合物在环境温度下保持液态。