trans-3-Methoxy-perfluor-2-penten | 1682-36-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: trans-3-Methoxy-perfluor-2-penten
• 英文别名: (E)-1,1,1,2,4,4,5,5,5-nonafluoro-3-methoxy-pent-2-ene；(E)-1,1,1,2,4,4,5,5,5-nonafluoro-3-methoxypent-2-ene
• CAS: 1682-36-6
• 化学式: C₆H₃F₉O
• 分子量: 262.075
• InChiKey: ZSIKUYDMQKKHLR-NSCUHMNNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  perfluoro-3-pentanone 、 三甲氧基磷 生成 cis-3-Methoxy-perfluor-2-penten 、 trans-3-Methoxy-perfluor-2-penten
  参考文献：
  名称：

  Fluoro Ketones. II. Reactions with Trialkyl Phosphites

  摘要：

  DOI：

  10.1021/jo01030a051

文献信息

• [EN] NOVEL ALKYL PERFLUOROALKENE ETHERS AND USES THEREOF<br/>[FR] NOUVEAUX ÉTHERS ALKYLIQUES DE PERFLUOROALCÈNE ET LEURS UTILISATIONS
  申请人：DU PONT

  公开号：WO2012006493A1

  公开（公告）日：2012-01-12

  Disclosed are methods of transferring heat comprising providing a device, using a heat-transfer fluid to transfer heat to or from the device, wherein the heat-transfer fluid compositions comprise at least one unsaturated fluoroether having the formula CF3(CF2)xCF=CFCF(OR)(CF2)yCF3, CF3(CF2)xC(OR)=CFCF2(CF2)yCF3, CF3CF=CFCF(OR)(CF2)x(CF2)yCF3, CF3(CF2)xCF=C(OR)CF2(CF2)yCF3, or mixtures thereof, wherein R can be either CH3, C2H5 or mixtures thereof, and wherein x and y are independently 0, 1, 2 or 3, and wherein x + y = 0, 1, 2 or 3.

  本发明涉及一种传热方法，包括提供一种装置，使用传热流体将热量传输到或从该装置中，其中传热流体组成物包括至少一种不饱和氟醚，其化学式为CF3(CF2)xCF=CFCF(OR)(CF2)yCF3、CF3(CF2)xC(OR)=CFCF2(CF2)yCF3、CF3CF=CFCF(OR)(CF2)x(CF2)yCF3、CF3(CF2)xCF=C(OR)CF2(CF2)yCF3或其混合物，其中R可以是CH3、C2H5或其混合物，x和y独立地为0、1、2或3，且x+y为0、1、2或3。
• Use of alkyl perfluoroalkene ethers and mixtures thereof in high temperature heat pumps
  申请人：THE CHEMOURS COMPANY FC, LLC

  公开号：US10287469B2

  公开（公告）日：2019-05-14

  Disclosed herein is a method for producing heating in a high temperature heat pump having a heat exchanger. The method comprises extracting heat from a working fluid, thereby producing a cooled working fluid wherein said working fluid comprises at least one alkyl perfluoroalkene ether. Also disclosed is a method of raising the maximum feasible condenser operating temperature in a high temperature heat pump apparatus. The method comprises charging the high temperature heat pump with a working fluid comprising at least one alkyl perfluoroalkene ether. Also disclosed is a high temperature heat pump apparatus. The apparatus contains a working fluid comprising at least one alkyl perfluoroalkene ether. Also disclosed is a composition comprising at least one alkyl perfluoroalkene ether, and specialized additives or lubricants for use in a high temperature heat pump.

  本文公开了一种在具有热交换器的高温热泵中产生热量的方法。该方法包括从工作流体中提取热量，从而产生冷却的工作流体，其中所述工作流体包括至少一种烷基全氟烯醚。还公开了一种提高高温热泵装置中冷凝器最高可行工作温度的方法。该方法包括向高温热泵充注包含至少一种烷基全氟烯醚的工作流体。还公开了一种高温热泵装置。该设备包含至少一种由烷基全氟烯醚组成的工作流体。还公开了一种包含至少一种烷基全氟烯醚和专用添加剂或润滑剂的组合物，用于高温热泵。
• NOVEL ALKYL PERFLUOROALKENE ETHERS AND USES THEREOF
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP2396294B1

  公开（公告）日：2015-07-22
• Method and apparatus for transferring heat with alkyl perfluoroalkene ethers
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP2590928B1

  公开（公告）日：2015-06-10
• PROCESSES FOR SEPARATING COMPONENTS IN ALKYL PERFLUOROALKENE ETHER PRODUCTION
  申请人：E. I. Du Pont de Nemours and Company

  公开号：EP2760814A1

  公开（公告）日：2014-08-06