tris(2,3,4,5,6-pentafluorophenyl) phosphite | 86341-40-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(2,3,4,5,6-pentafluorophenyl) phosphite
• 英文别名: tris(pentafluorophenoxy)phosphite；tris(pentafluorophenyl)phosphite
• CAS: 86341-40-4
• 化学式: C₁₈F₁₅O₃P
• 分子量: 580.146
• InChiKey: OACNPEDSVCMUDS-UHFFFAOYSA-N

物化性质

• 沸点：
  156-160 °C(Press: 0.5 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  37
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  tris(2,3,4,5,6-pentafluorophenyl) phosphite 在 溴 作用下， 以 二氯甲烷 为溶剂， 反应 52.0h， 生成 tris(pentafluorophenoxy)bis(1-bromo-2,2,2-trichloroethoxy)phosphorane
  参考文献：
  名称：

  Mironov, V. F.; Konovalova, I. V.; Pudovik, A. N., Journal of general chemistry of the USSR, 1991, vol. 61, # 1.2, p. 232 - 233

  摘要：

  DOI：
• 作为产物：
  描述：

  五氟苯酚 在 三氯化磷 作用下， 反应 4.0h， 以53%的产率得到tris(2,3,4,5,6-pentafluorophenyl) phosphite
  参考文献：
  名称：

  Chauzov, V. A.; Studnev, Yu. N.; Ragulin, L. I., Journal of general chemistry of the USSR, 1989, vol. 59, # 6.1, p. 1146 - 1148

  摘要：

  DOI：

文献信息

• Aromatic fluoroderivatives. XCV. The investigation of the behaviour of the polyfluoroaromatic compounds containing group VA elements in acid media
  作者：G.G. Furin、S.A. Krupoder、A.I. Rezvukhin、T.M. Kilina、G.G. Yakobson

  DOI：10.1016/s0022-1139(00)81148-3

  日期：1983.4

  The formation of the stable phosphonium ions from polyfluoroaromatic phosphines of C6F5PX2 type [X = H, CH3, C6H5, C6F5, Cl, F, NCS, CN, OCH3, N(C2H5)2] in HSO3FSbF5 (1:1) at −70 to −1O°C has been shown, as well as the transformation of the investigated phosphines in HSO3F at 20°C into the pentavalent phosphorus derivatives.The same processes take place also for the trivalent arsenic and antimony

  由C 6 F 5 PX 2型[X = H，CH 3，C 6 H 5，C 6 F 5，Cl，F，NCS，CN，OCH 3，N（C 2 ħ 5）2 ]中HSO 3 FSbF 5（1：1）在-70至-10℃的已被示出，以及在HSO的被调查膦的转化3F在20°C时生成五价磷衍生物，三价砷和锑衍生物也进行相同的过程。已经讨论了后者反应的可能途径以及决定因素。在HSO 3中由C 6 F 5 P（OCH 3）2和C 6 F 5 P（CN）2异常形成五氟苯膦酸二氟酸酐的质子化形式已找到F。已证明在-60°C下由强酸中的多氟亚硝基苯生成亚硝酸根阳离子。在相同的介质中于20°C，这些阳离子发生氧化，生成相应的硝基苯。研究了介质酸度对亚硝基苯反应的影响。
• ENAMINE COMPOUND AND USE THEREOF
  申请人：JAPAN SCIENCE AND TECHNOLOGY AGENCY

  公开号：US20200087245A1

  公开（公告）日：2020-03-19

  Provided are a donor-acceptor type compound having a novel structure and its use. An enamine compound represented by general formula (1) (in the formula: R 1 represents an electron-withdrawing group; A represents a divalent aromatic hydrocarbon group which may contain a substituent, a divalent aromatic heterocyclic group which may contain a substituent or a divalent unsaturated aliphatic hydrocarbon group which may contain a substituent; R 2 represents a hydrogen atom or a hydrocarbon group which may contain a substituent; R 3 and R 4 are the same or different from each other and represent an aromatic hydrocarbon group which may contain a substituent or an aromatic heterocyclic group which may contain a substituent, or R 3 and R 4 together form an optionally substituted bicyclic aromatic heterocyclic group containing two or more nitrogen atoms or a nitrogen atom and an oxygen atom or a sulfur atom, or a tricyclic aromatic heterocyclic group which may contain a substituent; and R 2 and A, or R 2 and R 3 may together form a cyclic structure).

  提供一种具有新颖结构的给受体型化合物及其用途。一种由通式（1）表示的恩胺化合物（在该式中：R1代表电子吸引基团；A代表可能含有取代基的二价芳香烃基团、可能含有取代基的二价芳香杂环基团或可能含有取代基的二价不饱和脂肪烃基团；R2代表氢原子或可能含有取代基的烃基团；R3和R4彼此相同或不同，代表可能含有取代基的芳香烃基团或可能含有取代基的芳香杂环基团，或R3和R4一起形成一个含有两个或更多个氮原子或一个氮原子和一个氧原子或一个硫原子的可选择取代的二环芳香杂环基团，或可能含有取代基的三环芳香杂环基团；以及R2和A，或R2和R3可能一起形成一个环状结构）。
• Chauzov, V. A.; Studnev, Yu. N.; Ragulin, L. I., Journal of general chemistry of the USSR, 1989, vol. 59, # 6.1, p. 1146 - 1148
  作者：Chauzov, V. A.、Studnev, Yu. N.、Ragulin, L. I.、Fokin, A. V.

  DOI：——

  日期：——
• Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of π-Conjugated Enamines
  作者：Atsushi Tahara、Yasumitsu Miyamoto、Ryuta Aoto、Keisuke Shigeta、Yuta Une、Yusuke Sunada、Yukihiro Motoyama、Hideo Nagashima

  DOI：10.1021/acs.organomet.5b00636

  日期：2015.10.26

  The appropriate design of a ligand (L) in IrCl(CO)(L)(2) (4) realized the efficient synthesis of pi-conjugated enamines possessing hole-transport properties. The iridium complex with electron-withdrawing phosphorus ligands catalyzed the hydrosilylation of amides to the corresponding silylhemiaminals, which were transformed to the enamines by heat or by treatment with acids. High catalytic efficiency (TON > 10,000) was achieved, which made it possible for the residual iridium in the enamine product to be below 20 ppb.
• Mironov, V.F.; Sinyashina, T.N.; Ofitserov, E.N., Russian Journal of General Chemistry, 1994, vol. 64, # 8.2, p. 1225 - 1227
  作者：Mironov, V.F.、Sinyashina, T.N.、Ofitserov, E.N.、Konovalova, I.V.

  DOI：——

  日期：——